硅钢资料

研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0～2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w... 

针对新日铁公开的相关专利,总结日本高强度无取向电工钢的研究进展,分析了各专利化学成分、生产工艺及产品性能的特点,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度。在高强度无取向电工钢的研发过程中,需要根据其具体用途确定目标性能,再采用合适的强化手段,从而实现力学性能、磁性能和生产性能之间的平衡。 Authors summarize the research progress of high strength non-oriented electrical steel in Japan by learning related patents brought into the public by Nippon Steel. Authors also analyze the characteristics of the chemical composition, production technology and properties of products in the patents and point out that any ones of solution strengthening method, fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method may be used to improve the strengt... 

为满足用户对无取向电工钢中硫含量的要求,采用CaO-CaF2复合渣系为脱硫剂,利用RH投入法对无取向电工钢进行深脱硫试验。试验结果表明,RH精炼渣成分控制在w CaO43%~51%、w Al2O325%~31%、w MgO4%~6%、w SiO29%~12%、w(FeO+MnO)3%~6%,在脱硫剂加入量为6~8 kg/t时,钢中平均硫含量从32×10-6降低到18×10-6,RH平均脱硫率为43.3%,最高达47.1%。利用KTH模型计算精炼终渣平均硫容量为0.003 1,RH精炼结束时渣-钢间实际平均硫分配比从14增加到52。 In order to satisfy the requirements of consumers on sulfur content in non-oriented electrical steel,taking( CaO-CaF 2) based flux as desulfurizer,industrial experiments on deep desulphurization of non-oriented electrical steel were carried out during RH process. The results show that as the compositions of refining slag are appropriately controlled with w CaO of 43% ~ 51%,w Al2O3 of 25% ~ 31%,w MgO of 4% ~ 6%,w SiO2 of 9% ~ 12%,and w( FeO + MnO) of 3% ~ 6%,and the desulfurizer added are at 6 ~ ... 

本发明属于冶金技术领域，具体涉及一种基于纳米析出强化制备高强度无取向硅钢的方法。该无取向硅钢包括如下重量百分比的化学成分：Si2.5～4.5wt.％，Ni2.5～6.5wt.％，Al1.0～3.0wt.％，Mn0.1～1.0wt.％，Cu0～1.0wt.％，(C+N+O+S)≤100ppm，其余为Fe；该无取向硅钢的制造方法包括：真空冶炼、浇铸锻造及热轧加工(或者薄带连铸)、常化热处理、酸洗与冷轧加工、再结晶退火、时效热处理。本发明制备的新能源汽车驱动电机转子用高强无取向硅钢厚度为0.20～0.50mm，磁感应强度B50为1.60～1.70T，P10/400为10～31W/kg，屈服强度Rp0.2为700～1000MPa，抗拉强度Rm为740～1150MPa，延伸率A为8～20％，可以满足用户对新能源汽车驱动电机用无取向硅钢性能要求。

根据本发明的一个实施例的双取向电工钢板，以重量％计，所述钢板包含Si：2.0至4.0％、Al：0.01至0.04％、S：0.0004至0.02％、Mn：0.05至0.3％、N：0.01％以下且0％除外、C：0.005％以下且0％除外、P：0.005至0.15％、Ti：0.001至0.005％、Ca：0.0001至0.005％和Mg：0.0001至0.005％，余量包含Fe和其他不可避免的杂质，具有从{100}＆lt;001＆gt;起15°以内的取向的晶粒的面积分数为60至99％，具有从{100}＆lt;025＆gt;起15°以内的取向的晶粒的面积分数为1至30％。

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

采用取向分布函数和取向线分析方法对低温板坯加热取向硅钢从热轧到初次再结晶工艺阶段的织构进行了研究。研究表明:一次冷轧后各层的织构组分与热轧板各层面的织构组分存在着继承关系,次表层存在很强的{001}<110>织构,中心层的织构和热轧板的中心层相似,存在强的{001}<110>和{112}<110>织构;中间退火后发生再结晶,各织构组分的强度有所减弱,Goss织构组分再次出现;二次冷轧后沿厚度方向上的织构不均匀性不明显,{111}<112>织构强度最高,几乎是其他织构组分的1倍,{001}<110>织构大幅降低;初次再结晶后织构沿厚度方向没有明显的不均匀性,{111}<110>为最强的织构组分,并且具有一定强度的Goss位向。 The texture from the first cold rolling to the primary recrystallization of low temperature slab reheating grain-oriented electrical steel were researched by orientation distribution function and orientation distribution intensity technique.The results show that after the first stage of cold rolling,there is a strong {001}<110> texture in the subsurface and the texture in center layer is very similar to the center layer of hot band which has strong {001}<110> and {112}<110> tex... 

本实用新型公开了一种成品取向硅钢片加工用的卷绕装置，包括机箱和卷绕机，所述机箱的下表面固定安装有底座，所述机箱的一侧表面靠近上方固定安装有控制箱，所述机箱的两侧表面靠近前方固定安装有伸缩机，所述机箱的前端面固定安装有挡板，所述挡板的前端设有卷绕机，所述底座的上表面且位于卷绕机的下方固定安装有定位筒，所述定位筒的内部活动安装有托杆。本实用新型所述的一种成品取向硅钢片加工用的卷绕装置，可以有效的控制卷绕机卷绕取向硅钢片的厚度，从而保证每次卷绕取向硅钢片的厚度都相同，利用伸缩机可以对不同宽度的取向硅钢片进行边缘位置的夹紧，并且可以控制卷绕板与卷绕机之间的间距，从而控制卷绕后取向硅钢片的内径大小。

采用取向分布函数分析了无取向电工钢不同再结晶退火温度下的织构变化及织构对磁感应强度和铁损的影响,并计算了无取向电工钢的磁晶各向异性能。结果表明,随着实验钢的再结晶退火温度升高,Goss织构和立方织构组分显著增强,而{111}面织构强度却减弱。较高的退火温度有利于减小织构因子,提高磁感应强度。磁晶各向异性能计算结果显示,随着再结晶退火温度升高,无取向电工钢板的磁晶各向异性能降低。 The recrystallization texture and the relationship of texture to magnetic induction intensity and core loss of a non-oriented electrical steel were investigated by orientation distribution function analysis. The magnetic anisotropy energy of the steel was calculated also. The results show that,the intensity of Goss texture and cubic texture increases,but the intensity of { 111} texture decreases with increasing recrystallization annealing temperatures of the steel. The higher annealing temperatu... 

利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O... 

通过后天抑制剂获得法制备了取向硅钢,对渗氮前后和高温退火升温阶段析出物的析出和转化规律进行了研究。研究结果表明,渗氮前脱碳退火态基体中存在少量的粗大AlN颗粒和细小AlN颗粒,渗氮处理后新析出大量的Si3N4析出物,高温退火升温阶段Si3N4将转化为(Al,Si)N,随着温度的继续升高(Al,Si)N颗粒将发生粗化,(Al,Si)N是后天抑制剂获得法制备取向硅钢的主要抑制剂。 Grain-oriented silicon steels were produced by acquired inhibitor method.The rule of precipitate transformation was studied after nitriding treatment and high-temperature finishing annealing.The results show that a small amount of large AlN and fine AlN are found in matrix before nitriding treatment,and a large amount of Si3N4 is precipitated in matrix after nitriding treatment.During the temperature rising period of high-temperature finishing annealing,Si3N4 would transform into(Al,Si)N,and(Al,... 

本发明提供一种以热轧卷为单元观察时具有在长边方向整个长度上均匀的织构，磁特性的变动小的取向性电磁钢板的制造方法。上述取向性电磁钢板的制造方法，包括如下步骤：将具有规定的成分组成的钢坯热轧而制成热轧板，将上述热轧板退火而制成热轧板退火板，对上述热轧板退火板实施1次或者隔着中间退火的2次以上的冷轧而制成最终板厚的冷轧板，对上述冷轧板实施一次再结晶退火和二次再结晶退火；至少1次冷轧的总压下率为80％以上，并且利用连轧机进行，利用上述连轧机的至少一个机架进行的轧制在压下率为30％以上且上述机架的工作辊的咬入温度T0℃的条件下进行，其中，将上述热轧板退火板的前端和尾端中的一方或两方的上述工作辊的咬入温度设为70℃以上且比上述钢板的温度T0℃高10℃以上的温度。