硅钢资料

对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in... 

【机构】 商务部进出口公平贸易局； ...

本发明涉及涂层液技术领域，且公开了取向硅钢绝缘涂层液，其配比为：二氧化硅10‑15%、硼酸5‑8%、磷酸二氢盐2‑5%、金属溶胶20‑25%、氢氧化铝占5‑6%、有机酸处理的复合盐溶液20‑30%、分散剂0.5‑1%，其余为水，采用硅溶胶作为辅助成膜物，粘结力较强，对附着性影响很大。硅溶胶能够很均匀地包裹在被胶结物质的表面，通过自干成膜，保持了很高的常温结合强度；而磷酸盐涂层的固化是通过受热分解，脱水聚合完成的，低温强度差，中温强度高，充分利用了硅溶胶低温的结合强度和磷酸盐中、高温时的结合性能，消除了常规涂层烘烤时容易出现的收缩、起泡现象，阻止了微气孔的形成，提高了涂层的表面光滑度，粘结强度和稳定性同时保持绝缘涂层的光泽、光滑和稳定性。

本发明提供一种提高硅锰镇静硅钢浇注性的生产方法，属于钢铁冶炼技术领域。其生产流程包括：转炉冶炼→RH真空精炼→连铸。转炉出钢严格控制下渣量，加石灰、渣面脱氧剂调渣；RH真空精炼脱碳结束后，先加入低碳低硫硅铁脱氧，再加入金属锰、磷铁等进行合金化，同时向钢包渣面加入低碳钢渣面脱氧剂对炉渣进行改质，待钢水成分全部命中后加入钙镁铁合金，循环3‑5min后净循环处理6‑10min，破空出钢；连铸采取保护浇注，浇注过程选用塞棒头中Al2O3≥80％、C≤10％、SiC含量8‑15％、气孔率≤12％，质量密度≥2.9g/cm3的塞棒进行控流，连浇炉数≥15炉/中包。本发明可以显著改善浇注过程塞棒头侵蚀问题，提高连浇炉数，降低生产成本。

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

用Gleeble1500D模拟试验机在变形温度为950～1 200℃、应变速率为0.01～8s-1、最大变形程度为60%的条件下,对硅钢50A1300做单道次压缩试验,首先分析了不同参数对流变应力的影响,然后用回归法确定了应力模型中的变形激活能及材料常数,得到硅钢50A1300在峰值应力条件和稳态应力条件下的变形激活能分别为270.360和91.557kJ/mol,同时得到了流变峰值应力模型,模型的相关系数为0.997。最后通过作lnθ-ε图的方法找到了硅钢50A1300发生动态再结晶的临界应变量,并回归得到峰值应变量、临界应变量与参数Z/C的关系式。 To analyze the effects of different parameters on the flow stress and critical strain of the dynamic recrystallization,single-pass compression experiments were carried out with silicon steel 50A1300 specimens using a Gleeble1500D thermal simulator at a temperature range of 950-1 200 ℃ and strain rate range of 0.01-8 s-1 under the condition of maximum deformation of 60%.The average deformation activation energy is respectively 270.360 and 91.557 kJ/mol under the peak stress and steady-state stres... 

在现普通冷轧无取向硅钢的基础上,降低Si含量,复合添加少量辅助元素,组合热轧板处理和成品退火加热技术,研制出了免常化处理的高磁感、低铁损并具有良好耐酸腐蚀性能的新系列无取向电工钢。 Based on existing common cold rolled non-oriented silicon steel,a new series of non-orientedelectrical steel with high induction,low core loss and excellent anti-corrosion property has been developed by reducing Si element,adding complexly a small amount of supplementary elements,and employing combined treatment of hot rolled sheet and finished product annealed heated technology. 

本发明公开了一种超薄取向硅钢用的半有机绝缘涂料。该半有机绝缘涂料，按质量百分比计，包括以下组分：10～25％磷酸盐，1～10％含有环氧基的硅烷耦合剂，0.2～2.0％有机硅烷，1～10％铬酐，1.5～6％二氧化硅粒子，0.3～5％碱，余量为水；其中二氧化硅粒子的粒径为100～300nm。该半有机绝缘涂料应用于超薄取向硅钢表面时，既提高了涂层与基体的附着性，又保证了涂层的绝缘性和耐热性，涂层附着性为A级，叠片系数大于0.96，可耐900℃高温，并且涂层较薄(小于1μm)时，钢板的绝缘电阻大于30Ω·cm2/片，绝缘性能优异，可满足超薄取向硅钢的应用需求。

研究了激光加热辅助圆盘剪高速切割技术,以解决现有冷轧生产线硅钢切边技术存在的微裂纹、应力、毛刺和边浪等问题。建立了激光加热温度场有限元分析模型,根据生产线上圆盘剪加工的实际过程,探讨了数值模拟中热源的加载形式,研究了激光对板材进行辅助加热时各个工艺参数如激光功率、光斑尺寸以及激光入射角度对切割工艺的影响,并通过实验对工艺参数进行了优化。最后,进了验证实验。实验结果显示:当激光加热点运动至圆盘剪刃口位置时,温度为100℃左右,此时材料硬度降低到原有硬度的70%~80%,降低了切削力,减少了圆盘剪的磨损,可有效提高圆盘剪的寿命。 Laser assisted trimmer side cutting technology was studied to overcome the problems such as micro cracks,stress,burrs and edge waves existing in a cold rolling production line of silicon steel side cutting.A finite element analysis model for the laser hearting temperature field was established, the loading form of a heating source was determined and influences of various processing parameters like laser powers,spot sizes,and laser incident angles on laser assisted heating sheet materials were di... 

以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in... 

针对攀钢高硫铁水冶炼现状,结合不同生产工艺路线,论述了攀钢近年来为实现低硫电工钢的生产,在铁水预处理、转炉冶炼、钢水精炼过程中硫控制技术的开发与应用,形成了低硫洁净钢生产工艺技术,实现了低硫电工钢的生产。低硫电工钢RH脱硫率可达到20%左右,成品[S]控制在0.006%左右。 According to the smelting situations of hot metal with high sulphur content at Panzhihua Steel,combined with different produce processes,technologies for controlling the sulfur content during hot metal pretreatment,converter smelting,and second refining are developed. Technologies in low-sulfur clean steelmaking are formed. Low-sulfur electric steel are produced. As for the desulfurization rate of lowsulfur electric steel can reach about 20%,and the content of [S] in products is controlled to ab... 

本发明涉及硅钢技术领域，尤其涉及一种硅钢连退炉辊除瘤方法及装置。包括连杆、手柄、磨削片、密封盖、端盖与套筒；磨削片垂直固接在连杆一端的外壁上，手柄固接在连杆的另一端，手柄与磨削片处于同一平面上；连杆套接在套筒内，连杆能沿套筒轴向移动，套筒固接在端盖上；硅钢连退炉辊下方的炉墙设有与连杆及磨削片相应的磨辊孔，端盖或密封盖固接在磨辊孔处。1)确定结瘤炉辊；2)确定结瘤在碳套辊上的位置；3)插入除瘤装置；4)磨削；5)抽出。本发明降低废品量，提高成材率；减少停炉处理结瘤时间，降低能耗，提高生产率；提高难磨瘤辊的修复率，降低炉辊成本。