硅钢资料

本发明涉及一种取向硅钢热轧钢带的板形控制方法，所述取向硅钢热轧钢带的工艺流程包括铸坯加热过程、轧制过程及层流冷却过程；其中轧制过程中采取取向硅钢与普钢交叉轧制的方式；粗轧过程采取R1轧制1道次、R2轧制5道次的1+5轧制工艺，并控制轧制工艺参数；精轧过程中控制F1～F7轧制工艺参数。本发明通过设定合理的交叉轧制工艺及取向硅钢热轧工艺，使取向硅钢的轧制稳定性大幅提高，取向硅钢带形控制良好，凸度控制在30～50μm之内，楔形控制在30μm之内，板形平坦度控制在25iu之内；从而为冷轧工序提供了优质原料。

本发明公开了一种新能源汽车驱动电机用低铁损高强度无取向电工钢及其制造方法，所述无取向电工钢的化学成分及重量百分比包括C：0.001‑0.005％、Si：2.4‑3.0％、Mn：0.25‑0.5％、Al：0.70‑1.10％、P：≤0.02％、S：≤0.005％、0.015％≤Ce+Sn≤0.035％，余量为铁和不可避免的杂质，本发明通过加入Ce和Sn，净化钢质、微合金化提高无取向电工钢强度和磁性能，不需要添加固溶金属元素，且避免了高Si体系下的轧制困难问题，且不需要高温退火，解决了退火温度过高使晶粒异常长大，晶粒尺寸均匀性降低的问题，生产出的无取向电工钢具有较高强度的同时，还具有优良的磁性能。

研究了CSP工艺生产≤0.005%C-1.1%Si的2.2mm无取向电工钢热轧板在800～1000℃常化对0.5mm冷轧板840℃退火后组织和磁性能的影响。结果表明,热轧板常化温度升高,冷轧板退火后的再结晶晶粒增大,铁损降低,磁感增加;热轧板常化温度超过900℃,因第二相固溶而后弥散析出,退火后冷轧晶粒细化,铁损增加,因此该无取向电工钢热轧板最佳常化温度为900℃。 The effect of normalizing at 800-1000℃ of CSP produced plate(≤0.005%C-1.1%Si) on the microstructure and magnetic properties of downstream cold-rolled non-oriented electrical steel annealed at 840℃ was studied.Results show that with increasing normalizing temperature of hot-rolled material the recrystallized grain size of annealed sheet increases,iron loss reduced and magnetic induction increases.As normalizing temperature excesses 900℃,grain is refined and iron loss increases after annealing due... 

一种增大压下率的电工钢冷轧装置及冷轧方法，属于电工钢冷轧技术领域，该电工钢冷轧装置，包括单机架可逆轧机，单机架可逆轧机的两侧均设置有电磁感应加热装置和氮气风冷装置，氮气风冷装置靠近单机架可逆轧机的轧制进口或入口设置，本发明的有益效果是，本发明通过在单机架可逆轧机两侧增设电磁感应加热装置和氮气风冷装置，对每道次轧制过程中可在线调节电磁感应加热温度，实现了边去应力退火边轧制，保证了正常的轧制工作，达到了高效轧制更薄规格电工钢产品的目的和消化生产CSP热轧超厚过渡坯的目的。

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

通过对辉光放电发射光谱法分析电工钢样品光谱行为的研究,分析其工作参数如:电压、电流、预溅射时间和积分时间对光谱强度和稳定性的影响,并以铁为内标元素,优化了工作参数。确定了直流辉光放电光谱法测定电工钢中碳、硅、锰、磷、硫、铬、镍、铜共8种元素的定量分析方法,并对该方法分析的精密度和准确度进行验证,结果表明,各元素的测定结果与认定值和其他方法测定值一致,测量元素结果RSD值小于2%。 Based on research on analyzing the spectrum behavior of the sample taken from the electrical steel by glow discharge optical emission spectrometry,the effect of its operational parameters such as current,voltage,pre-sputtering time and integrating time on the spectral intensity and spectral stability is analyzed.Taking the Fe as an element applied by internal standard method,these operational parameters are optimized,and therefore the quantitative analysis method for testing eight kinds of eleme... 

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the... 

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali... 

本发明公开了一种适应高频率工况下低铁损无取向电工钢及其生产方法，所述生产方法包括以下步骤：钢水连续浇铸成板坯—热轧—正火—酸洗—冷轧—连续退火—涂绝缘涂层并固化；所述冷轧步骤中，采用六辊单机架往复式轧机经5道次一次冷轧至目标厚度，冷轧过程中前三道次采用变速异步轧制方法，使钢板表层在剪应力作用下位错密度增加，这样在退火后表层晶粒尺寸细化而心部晶粒粗大，通过本发明的方法可生产得到心部为粗大等轴晶粒，表层为纳米级细等轴晶粒的电工钢产品，该产品的铁损P1.5/50≤2.35W/kg，P1.0/400≤14.0W/kg。

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

本发明一种解决取向硅钢热轧板晶粒粗大的方法，在取向硅钢的成分设计中减少固溶温度较高的MnS的含量，降低铸坯加热温度，同时计算实际取向硅钢成分中γ‑相含量与温度之间的关系，依据计算结果设计取向硅钢的热轧工艺，可以保证20％～30％的γ‑相数量，成功解决取向硅钢热轧板晶粒粗大的问题。

本发明涉及一种含磷无铝高效无取向硅钢生产方法，生产方法取消常化工艺，具体步骤如下：1)将钢水冶炼至目标成分后，浇铸成坯；2)板坯热装，热装温度≥500℃，热轧板坯加热炉均热段板坯温度1150～1200℃；终轧温度控制在860～930℃，卷取温度700～800℃3)酸洗后冷轧，控制冷轧整体压下率80％以内，至成品厚度；4)连续退火炉快速加热段温度设定1050～1180℃，增加有利织构组织形核，均热段温度设定830～950℃，全氮气干气氛保护，退火工艺速度120～150m/min，满足晶粒度8～4级。本发明不需进行热轧卷常化处理，降低了制造成本。