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对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 
2011-04-28 64 5.8

本发明揭示了一种无取向硅钢及其生产方法。该无取向硅钢的化学成分:Si:2.95%~3.15%,Al:0.75%~0.95%,Si+2Al:4.6%~4.9%,Mn:0.5%~0.7%,Sn:0.03%~0.04%,Cu≤0.03%,Cr≤0.03%,Ni≤0.03%,Nb≤0.004%,V≤0.004%,Ti≤0.004%,C≤0.0025%,P≤0.015%,S≤0.0015%,N≤0.004%,余量铁;Mn/S≥380,Al/N≥200;无取向硅钢的再结晶晶粒尺寸50~80μm。本发明在保证磁性能的同时,提高了强度,解决了现有技术所存在的磁性能和强度的兼顾问题。
2021-10-26 64 6.8

采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e... 
2011-03-28 64 5.8

采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0~2μm向2~4μm、4~6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1~5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5~10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2~4 μm and 4~6 μm,from 0~2 μm.Under different calcium treatments,there e... 
2013-02-28 64 5.8

分析总结退火工艺各参数对冷轧无取向硅钢磁性能的影响,结合设计和生产实践经验介绍退火工艺中各参数的实际生产取值,并针对现生产工艺过程中出现的典型问题提出解决办法。 It is analyzed and summarized the great influences on magnetism of cold rolled non-oriented silicon steel affected by various annealing process data in this article.The relevant settled ways is raised.According to the actual value presetting ways for various annealing process data based on design and production,as well as typical problems occurred during production. 
2012-05-28 64 5.8

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 
2014-09-28 64 5.8

本实用新型涉及一种具有在线测量功能的电工钢片横剪线,包括床身,床身上沿其长度方向安装有导轨,电工钢片在外部驱动辊带动下以导轨为导向移动;位于导轨一端端头外部的床身上安装有测量辊组件,位于导轨另一端处的床身上安装有影像测量组件;测量辊组件、导轨和影像测量组件的中心位于同一直线上,影像测量组件横跨设置于导轨上方;位于测量辊组件和影像测量组件之间的床身上依次安装有冲孔组件、V冲组件和斜剪组件;本实用新型通过测量辊组件对电工钢片行进长度进行检测,通过影像测量组件对电工钢片成型尺寸进行检测,从而便利于及时调整横剪线整体的运行状态,有效助力于保证合格率,并降低了人工负担。
2021-02-08 64 6.8

本实用新型公开了一种用于硅钢片的焊接工装夹具,它包括底座,所述底座包括底板(1)、固设于底板(1)顶表面上的左挡板(2)和右挡板(3),左挡板(2)与右挡板(3)之间固设有位于底板(1)上的挡条(4),挡条(4)的前端面上设置有止口(5),左挡板(2)的前端部铰接有压杆(6),所述底板(1)的顶表面上且位于其左侧放置有压条(7),底板(1)的顶表面上且位于其右侧固设有限位条(8),压条(7)与限位条(8)之间设置有多个紧靠于一起的定位块(9),每个定位块(9)均放置于底板(1)的顶表面上。本实用新型的有益效果是:结构紧凑、提高硅钢片组件焊接质量、提高硅钢片组件生产效率、操作简单。
2021-11-19 64 6.8

含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10~50 nm Cu2S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;(Cu,Mn)1.8S、Cu1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30~50 nm(或大于50 nm),主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10~50 nm Cu2S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30~50 nm or more than 50 nm... 
2013-03-28 64 5.8

测试了高强无取向电工钢的S-N曲线,并借助光学显微镜、扫描电子显微镜、透射电子显微镜分析了实验钢组织,疲劳断口形貌和位错结构。结果表明:室温条件下,频率为20Hz,应力比R为0.1,循环10~7周次时,实验钢的疲劳强度为360MPa,疲劳裂纹萌生于实验钢的次表面,裂纹萌生点附近有沿晶开裂现象,疲劳裂纹扩展区域有解理台阶与疲劳条纹,瞬间断裂区是韧性断裂,有大量韧窝。实验钢在循环应力作用下基体中产生了大量位错,并有驻留滑移带终止在晶界位置。 The S-N curve of a high strength non-oriented electrical steel was tested.The microstructure and fatigue fracture morphology and dislocation were analyzed by optical microscope,scanning electron microscope,transmission electron microscope.The results showed that:at room temperature and the frequency of 20 Hz and the stress ratio Rof 0.1,the fatigue strength of the experimental steel was 360 MPa when the cycle was 10~7 cycles.The fatigue crack initiation at the surface of the steel and the interg... 
2022-01-28 64 5.8

本发明公开了一种精确控制高磁感取向硅钢板坯Als含量的方法,转炉出钢20~40秒时,定量加入金属铝,加入量按0.15~0.35kg/吨钢;转炉出钢及合金加入后,底吹搅拌均匀3~5min后,加入一定量金属铝后再底吹搅拌均匀3~5min后将钢水吊运至RH开始精炼处理,铝加入量按[WAls目标+(0.009~0.0120%)]范围控制;钢水在RH精炼过程经过2~3次酸溶铝的成分微调后结束精炼,精炼结束Als按[WAls目标+(0.0030~0.0045%)]目标范围控制;RH精炼结束样酸溶铝检测结果出来后,在连铸开浇前,在钢包内补加铝线使钢液中Als在[WAls目标+Δ浇注Als损]目标范围内;连铸进行氩气环流保护浇注,其中氩气环流流量控制在6~12m3/h;浇注成合格板坯后按正常工艺进行热轧及后工序生产。
2021-12-08 64 6.8

本实用新型公开了一种无取向硅钢绝缘涂层粘结性检测装置,涉及涂层粘结性检测技术领域,为解决现有的无取向硅钢绝缘涂层,在对绝缘涂层粘结性检测过程中,其检测结构单一,容易导致检测不准的问题。所述基座的上方设置有存料罐,所述存料罐的内壁设置有防腐涂层,所述存料罐的底部设置有声波感应器,所述声波感应器的一侧设置有液位感应器,所述液位感应器的一侧设置有自控温度调整器,所述存料罐的上方设置有控制盘,所述控制盘的表面设置有PLC操控器,所述控制盘的上方设置有电机,所述电机的一侧设置有带轮结构,所述带轮结构的一侧设置有伸缩气缸,所述伸缩气缸的一侧设置有联动结构,所述伸缩气缸的一端设置有收缩棒。
2021-09-06 64 6.8

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