硅钢资料

研究了铝和铬元素在无取向电工钢晶粒长大过程中对织构及晶界变化的影响规律。试验结果表明:电工钢在晶粒长大过程中的主要织构组分均为{111}<112>。在晶粒生长期间,不加铝的1号试样中,{111}<112>、{111}<110>织构组分强化,而{100}<001>织构组分弱化;与1号试样相比,在加入0.2%的铝(质量分数,下同)的2号试样中,{111}<112>、{111}<110>织构组分强化(增加)的速率下降,{100}<001>织构组分变化不明显,甚至稍有增加。在含铝的试样中再加入0.3 5%的铬之后(3号试样),{111}<112>{、111}<110>和{100}<001>织构组分的变化规律与1号试样相似,但当电工钢中加入0.72%的铬之后(4号试样),上述3种织构组分的变化规律与2号试样相似。对于在晶粒生长期间持续变化的3种织构组分而言,1号试样的{1 1 1}<112>和{111}<110>织构组分的高(低)取向差角度晶界频率下降(... The effect rule of Aluminm and Chromium on texture and grain boundary transformation in the nonoriented electrical steel during grain growth was investigated.The experimental result shows that the main texture component is {111}<112> in the electrical steel.The {111}<112> and {111}<110> components in specimen 1 without Alumium were strengthened during grain growth whereas {100}<001> component was weakened.But the growth rate of {111}<112> and {111}<110> compon... 

通过后天抑制剂获得法制备了取向硅钢,对渗氮前后和高温退火升温阶段析出物的析出和转化规律进行了研究。研究结果表明,渗氮前脱碳退火态基体中存在少量的粗大AlN颗粒和细小AlN颗粒,渗氮处理后新析出大量的Si3N4析出物,高温退火升温阶段Si3N4将转化为(Al,Si)N,随着温度的继续升高(Al,Si)N颗粒将发生粗化,(Al,Si)N是后天抑制剂获得法制备取向硅钢的主要抑制剂。 Grain-oriented silicon steels were produced by acquired inhibitor method.The rule of precipitate transformation was studied after nitriding treatment and high-temperature finishing annealing.The results show that a small amount of large AlN and fine AlN are found in matrix before nitriding treatment,and a large amount of Si3N4 is precipitated in matrix after nitriding treatment.During the temperature rising period of high-temperature finishing annealing,Si3N4 would transform into(Al,Si)N,and(Al,... 

对高牌号无取向电工钢国内生产情况、工艺技术、产品性能及应用领域等进行了阐述,并探讨了高牌号无取向电工钢产品的发展趋势。 This paper introduces basic facts on the production status,process technology and products’ properties and their applications of non-oriented electrical steel with high grade at home,and then discusses the development trend on technology for producing the non-oriented electrical steel with high grade. 

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 

本实用新型提出一种EI型硅钢片，所述EI型硅钢片呈长方形，其包括两个E形片和两个I形片，所述两个E形片开口相对且对称设置，所述两个I形片分别连接于两个E形片相接形成的两个空挡内，所述长方形的长度A为120mm，宽度B为88mm；其中，E形片的高度C为60mm，中间舌部宽度D为29.5mm，舌部高度E为44mm，其上两侧边柱宽度F为13.25mm；I形片宽度G为16mm，长度H为88mm。本实用新型采用两个E形片和两个I形片对称设置，在冲压时充分利用材料，不会造成多余废料，且其与现有EI90型硅钢片相比，其面积为EI90型硅钢片面积的97.78％，即硅钢材料重量也为EI90的97.78％，减少了硅钢用量。

介绍了一种适用于超大晶粒取向硅钢的高斯晶粒取向偏离角的X射线衍射测量方法，提出了将试探法和探测器扫描法相结合的方式进行测量。结果表明：该方法可以同时获得准确的实际衍射角度和取向偏离角度，试样制备方式简单，对设备的要求低且测量结果准确。 This paper introduces a X-ray diffraction measurement method of Gaussian grain orientation deviation angle for ultra-large grain oriented silicon steel, and puts forward a method of combining the test method with the detector scanning. The results show that this method can obtain accurate actual diffraction angle and orientation deviation angle at the same time. The sample preparation method is simple, the requirements for equipment are low, and the measurement results are accurate. 

本发明提供了一种可修饰取向硅钢表面的无机绝缘涂料及其制备和使用方法，该涂料按照重量份计，包括：大颗粒硅溶胶5‑35份、磷酸二氢铝10‑30份、小颗粒硅溶胶5‑35份、铬酐0.5‑5份、增稠剂1‑10份、钛白粉0.01‑0.5份及去离子水0‑78.49份；该涂料的固含量为20‑40％。该涂料制备方法为：将增稠剂、去离子水、磷酸二氢铝、大颗粒硅溶胶、小颗粒硅溶胶，铬酐和钛白粉依次加入反应器中搅拌均匀，室温静置0.5‑1h。该涂料在使用时，需先将取向硅钢片进行清洁干燥预处理后，再将涂料辊涂在取向硅钢片上固化烧结并控制膜厚。本发明所提供的涂料制成的涂层表面平整均匀、颜色光亮，具有优良的附着性、耐蚀性、热稳定性和绝缘性，并且能修饰因硅酸镁底层质量不良引起的露晶亮点缺陷。

本发明公开了一种低铁损高磁导率无取向电工钢及其生产方法，所述生产方法包括以下步骤：钢水连续浇铸成板坯，板坯经加热炉加热，再经热轧得到热轧板，然后经空冷和水冷后在500～650℃进行卷取；热轧板经常化处理、盐酸酸洗；酸洗后在可逆轧机上进行冷轧；最后经成品退火，退火温度为840～900℃，加热时间为240～500s；然后以不超过3℃/s的冷却速度冷却至500℃以下；涂覆绝缘涂层、固化，后经二次退火，即可得到低铁损高磁导率无取向电工钢，其磁性能满足P1.5/50≤3.50W/kg，μ1.5≥3800Gs/Oe，B5000≥1.76T的要求。

利用电子背散射衍射(EBSD)技术和场发射电子扫描显微镜(FESEM)研究了电工钢中柱状晶不同初始取向50%热压缩变形后的演变规律及其对粒子析出行为的影响。结果表明:〈100〉晶粒形变后仍为〈100〉取向,只发生绕ND∥〈100〉方向的转动,具有遗传性,粒子析出数量少。柱状晶长轴与压缩轴的偏转度增加,取向的稳定性变差,超过40°,可形成〈111〉取向,期间发生复杂的滑移系交互作用,产生较高的缺陷密度,促进粒子析出。MnS粒子主要在晶内析出,变形温度高、形变量低,粒子均无法充分析出。回复时,形变晶粒内高的储能和缺陷密度是促进粒子进一步析出的必要条件。 The evolution of initial orientations and their influence on precipitation of columnar-grained electrical steel after 50% hot compression deformation were investigated by electron backscatter diffraction technique and field emission scanning electron microscopy.The results indicate that the〈100〉orientated columnar grains remain still〈100〉after hot compression deformation,with only rotation around ND parallel to〈100〉direction,with heredity,and less precipitation.As the deviation angle between the... 

研究二次冷轧压下率对于硅的质量分数为3.0%的无取向硅钢组织结构和磁性能的影响。结果表明:当第二次冷轧压下率从0变化至16.7%时,铁损逐渐增加,磁感逐渐降低。当第二次冷轧压下率大于16.7%时,随压下率的增加,铁损逐渐减小,磁感逐渐增加。当第二次冷轧压下率大于38%时,二次冷轧法所能获得的磁性能明显优于一次冷轧法。 Effect of double cold reduction on magnetic,microstructure and texture of 3.0% Si non-oriented silicon steel sheets was investigated.The results show that the iron loss increases and magnetic induction reduces as the percentage redcution in secondary cold rolling changes from 0 to 16.7%.The core loss can be reduced remarkably,and magnetic induction can get a little benefit if the percentage redcution in double cold reduction is higher 16.7%.In case of higher than 38% of the percentage redcution ... 

该电磁钢板包括母材钢板、第1绝缘被膜及第2绝缘被膜，该第1绝缘被膜被形成于所述母材钢板的第1面，并具有粘结能量，该第2绝缘被膜被形成于作为所述母材钢板的所述第1面的背面的第2面，并具有粘结能量，所述第1绝缘被膜的平均铅笔硬度为HB以上3H以下，所述第2绝缘被膜的平均铅笔硬度比所述第1绝缘被膜的平均铅笔硬度更高。

简述了无取向硅钢环保涂层发展背景,分析了硅钢环保涂层的特点及国内、外研究进展,提出了硅钢保涂层下一步的发展方向。 The back ground of environmental protection coating of non-oriented silicon steel was described in this paper.The characteristics and study progress in domestic and foreign of environmental protection coating of non-oriented silicon steel were analysised.The next development direction of environmental protection coating of non-oriented silicon steel was put forward.