硅钢资料

【作者】 陶永根； ...

概述了高磁感取向硅钢生产工艺的研究现状及发展趋势。介绍了国内外薄板坯连铸连轧流程生产高磁感取向硅钢的研究现状。从流程工序特点、热履历、组织与抑制剂控制方面进行对比,分析了薄板坯连铸连轧流程相对传统板坯流程生产高磁感取向硅钢的技术优势,在此基础上提出了利用该流程生产高磁感取向硅钢需要解决的主要技术难点。 The current status and development trend of production process for high magnetic induction grain-oriented silicon steel are summarized.The research status of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process at home and abroad is introduced.The potential technical advantages of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process are obtained by analyzing in terms of process characteristics,t... 

对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in... 

层叠铁芯使用的电磁钢板是在母材钢板(2)的表面具有涂布电磁钢板用涂布组合物而形成的绝缘被膜(3)的电磁钢板，所述电磁钢板用涂布组合物以特定的比率配合有环氧树脂、由烷基酚构成的第一固化剂、由苯酚甲阶酚醛树脂和苯酚酚醛清漆树脂中的任意一方或双方构成的第二固化剂。

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

用还原分离-原子荧光光谱法分析了硅钢中的痕量汞.分析方法的不确定度主要来自测量重复性,样品溶液浓度,工作曲线变动性,标准溶液,移取、配制标准溶液,仪器变动性等.文章分别对上述构成合成不确定度大小的分量进行了计算讨论. Trace mercury in silicon steel and galvanized sheet was analyzed by adopting reduced separation-atomic fluorescence spectrometry.The uncertainty of the analysis method mainly comes from measurement repeatability,sample concentration,working curve volatility,standard solution,pipetting and preparation of standard solution,and instrument variability,etc.The essay conducted all calculations and discussions on the above components that determine uncertainty. 

本发明提供一种改善表面麻点缺陷的薄规格中低牌号无取向硅钢及其生产方法，成分C≤0.0025％，1.2≤Si≤1.65％，0.25％≤Mn≤0.35％，0.06％≤P≤0.11％，0.1％≤Als≤0.2％，S≤0.0025％、N≤0.0025％，Ti≤0.0025％，其余为Fe及不可避免的杂质。与现有技术相比，本发明采用较低氢气浓度，防止炉内氧化铁皮还原，减轻碳套辊的腐蚀程度，减少碳套辊结瘤率，改善带钢表面质量；采用合理合金成分设计，提高带钢的力学强度，降低碳套辊结瘤对带钢表面的影响程度，改善带钢表面质量。产品厚度为0.35mm，板面麻点发生率降低，无手感，且辊身周长周期范围内麻点个数≤5个。

介绍了EB5325涂层液的主要性能和中冶新材生产冷轧无取向电工钢所用的涂层设备,通过多次试验摸索出使用EB5325涂层液的工艺,对涂层出现的缺陷进行分析研究,并提出解决方法,使中冶新材生产的冷轧无取向电工钢的涂层质量满足了用户的要求。 This article introduces the main properties of EB5325 and the coating equipments for cold-rolled non-oriented electrical steel. A process using EB5325 coating liquid is made through many time experiments and exploration. The appeared defects in the coating are studied and analyzed,and the solutions are proposed. The coating quality meets clients’ requirements of cold rolled non-oriented electrical steel. 

对取向硅钢熔融态钢液进行处理,对比研究了不同脉冲参数的作用效果。结果表明,电脉冲对钢锭晶粒组织具有明显的细化作用,凝固组织等轴晶比例大幅上升。在脉冲电容、频率、处理时间和电压中,影响等轴晶比例的最显著性因素为脉冲频率;最优正交实验参数为:电容1 200μF,脉冲频率1 Hz,处理时间5 s,脉冲电压800 V;随着输入能量的增大,等轴晶率先增大后减小,脉冲输入能量为某值时,等轴晶率最大,通过经典形核理论和热力学对这一现象进行了解释。 Research on the influence of the electric pulse on the solidification structure of oriented silicon steel was preformed.Electric pulses in different parameters were applied to molten steel and results were compared.The result shows that solidification structure of oriented silicon steel can be improved by the electric pulse,and the equiaxed crystal ratio increases obviously.Among the four parameter factors of electric capacity,frequency,applied time and voltage,the most effective factor is frequ... 

本实用新型属于冷轧硅钢技术领域的一种冷轧硅钢无压回水自动控制设备，包括底座，底座外表面的上端固定连接有工作台，工作台外表面上端的两侧分别固定连接有固定柱和压辊主体，工作台外表面上端的中部滑动连接有移动架，压辊主体的下端设置有集水槽，集水槽的内表面设置有浮球液位传感器。液压杆工作推动移动架位移到合适的位置，再通过气缸使伸缩管发生位移，使出水口接近钢板，设置的水箱高于出水口所以水可以在重力的作用下流淌，流出的水流到集水槽内，水流在集水槽内聚集，水流使浮球液位传感器的浮球上升，上升到合适的位置时，浮球液位传感器通过电缆发生电信号至控制器，此设置可以实现设备的自动控制，省去人工进行操作。

本发明公开了一种高硅钢的冷轧生产工艺。该生产工艺属于机械制造技术领域，其中的处理工序的加热工序通过电磁感应加热装置加热，待处理钢经过加热工序的速度为30‑200mpm，加热工序的加热温度为70‑120℃。本发明具有生产效率高和生产质量高的特点，特别是在加热工序中对待处理钢采用电磁感应加热装置进行加热，使其可以快速有效地提升温度，以满足高硅钢的冷轧生产工艺要求，减少断带事故，具有很好的实用性和创新性。

通过在实验室条件下模拟薄板坯连铸连轧流程,并在以Cu2S为主抑制剂制造普通取向硅钢(CGO)的基础上,加入适量钒钛,研究了钒钛对取向硅钢组织与磁性能的影响。结果表明,适量钒钛使热轧板和脱碳退火板组织更好,尤其使脱碳退火板的晶粒更加细小和均匀;加入适量钒钛不但使热轧板表面高斯织构强度更高,更使脱碳退火板中有利于高斯织构发展的γ织构强度更高;适量钒钛能形成Cu2S+(V,Ti)N等复合析出物,起到辅助抑制剂作用,加强抑制能力。细小均匀的晶粒、强度更高的有利织构和更强的抑制能力使CGO钢磁性能更佳。 Effect of V and Ti on microstructure and magnetic properties of conventional grain-oriented silicon steel(CGO) were investigated under simulated thin slab continuous casting and rolling process in laboratory with Cu2 S as the dominant inhibitor. The results show that appropriate amount V and Ti make the microstructures of the hot rolled sheet and the decarburizing annealed sheet better,especially make the grains of the decarburizing annealed sheet more tiny and uniform. Adding appropriate V and ...