硅钢资料

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

一种含Bi高磁感取向硅钢热轧带钢边部质量控制方法：炼钢；连铸；铸坯加热；粗轧，粗轧道次不低于4道次，各道次压下率控制在20~33%；规精轧及进行后工序。本发明通过对热轧工序的控制，能使热轧带钢边部开裂的尺寸降低至不超过5mm，且边部开裂≤2mm比率能达到95%以上，后工序切边量很少甚至无需切边即可进行冷轧，使产品成材率能比现有技术提高2~4%；且由于铸坯加热温度的降低使能耗也随之降低。

一种提高有效氮和底层质量的高磁感取向硅钢制造方法：冶炼后连铸成坯；对铸坯加热；热轧、常化及酸洗后时效冷轧；在湿式气氛下脱碳退火；在湿式混合气氛下均热；在湿式混合气氛下渗氮退火；进行后工序。本发明与现有技术相比，通过合理控制渗氮过程，提高渗氮后钢板基体内氮含量与总氮量之间的比例达到80%以上，使无点状露晶产生，最终获得产品的底层质量优异。

利用X-射线衍射织构分析和线形分析技术测定了交叉轧制双取向硅钢在制备工艺各阶段的织构及微结构,进而探讨了立方织构({100}<001>)的形成过程。通过对实验结果的分析可知,二次冷轧和交叉轧制工艺为立方织构提供了内能优势和有利的形变织构,而低温预退火工艺既强化了立方织构的内能优势,又为立方织构的异常长大提供了有利的组织保证,最终在抑制剂(AlN和MnS)的协同作用下,硅钢在二次再结晶退火后形成了强烈的立方织构。 The texture and substructure of the double oriented electrical steels produced by the cross rolling technology during the difference process has been measured by means of the X-ray texture and diffraction peak profile analysis technology,and research the formation mechanism of cube texture,{100}<001>.The results show that the dominances of inner energy and deformation texture were supplied by secondary cold rolling and the cross rolling technology and strengthened by pre-annealing at a low... 

本发明公开了一种精确控制高磁感取向硅钢板坯Als含量的方法，转炉出钢20～40秒时，定量加入金属铝，加入量按0.15～0.35kg/吨钢；转炉出钢及合金加入后，底吹搅拌均匀3～5min后，加入一定量金属铝后再底吹搅拌均匀3～5min后将钢水吊运至RH开始精炼处理，铝加入量按[WAls目标+(0.009～0.0120％)]范围控制；钢水在RH精炼过程经过2～3次酸溶铝的成分微调后结束精炼，精炼结束Als按[WAls目标+(0.0030～0.0045％)]目标范围控制；RH精炼结束样酸溶铝检测结果出来后，在连铸开浇前，在钢包内补加铝线使钢液中Als在[WAls目标+Δ浇注Als损]目标范围内；连铸进行氩气环流保护浇注，其中氩气环流流量控制在6～12m3/h；浇注成合格板坯后按正常工艺进行热轧及后工序生产。

本发明提供了一种提高无取向硅钢铁损均匀性的方法，所述方法包括，对无取向硅钢板坯进行加热和粗轧，获得中间坯；将所述中间坯精轧后以620‑750℃的温度进行卷取，获得热轧卷；将所述热轧卷进行酸洗和冷轧，获得冷轧卷；对所述冷轧卷升温至900‑960℃的温度保温50‑90s的时间，进行退火，获得铁损均匀性良好的无取向硅钢。本发明提供的方法，其铁损P1.0/50为1.379‑2.721W/kg，P1.5/50为2.751‑5.438W/kg，B5000为1.706‑1.741T，在线P1.0/50极差为0.062‑0.188W/kg，无取向硅钢的铁损更均匀。

【机构】 武钢研究院； ...

介绍了国内、外电工钢极薄带的生产现状及市场应用的情况,以及典型生产企业的生产规模、产品性能和应用领域,指出扩大高牌号无取向电工钢生产、提高产品质量是目前电工钢发展的迫切要求。 The production situation and market application of ultra thin electrical steel strip at home and abroad were described.The production capability,product property and application area of typical corporation were introduced.The results indicate that the urgency needed of electrical steel development is expanding high-grade non-oriented electrical steel production and improving products quality at present. 

本发明公开了一种可替代高磁感取向硅钢常化退火的热处理方法。该方法包括对所述取向硅钢的铸坯依次进行热轧、酸洗和冷轧，省去了常化酸洗工序中的常化退火工艺。所述热轧工序包括加热、粗轧和精轧过程，所述精轧过程中，热轧板离开精轧机最后一个机架时的温度达到1000～1050℃；或者，所述酸洗工序后，对热轧板进行通电加热至1000～1050℃；然后，对热轧板采用短时通电加热控制冷却速度，通电加热2‑5s使热轧板的温度降至940～960℃。采用该热处理方法得到高磁感取向硅钢常化板等效织构，满足生产高磁感取向硅钢的织构组分条件，其简化了高磁感取向硅钢的制造工艺，降低了生产成本和能耗，提高了生产效率。

分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained. 

本文中简要介绍了武汉钢铁有限公司采用薄板坯连铸连轧CSP(compact strip production, CSP)工艺生产中低牌号无取向硅钢的实践情况.CSP工艺生产的硅钢具有成品磁性均匀、板形好的优势，但是在利用该技术生产中低牌号无取向硅钢时，常存在成品板表面瓦楞状缺陷严重、连铸生产效率低等问题.通过优化炼钢成分、热轧等相关工艺，可消除热轧板厚度方向中心的粗大形变组织，从源头上避免了粗大{100}<011>纤维组织的出现，消除了瓦楞状缺陷；通过提升冶炼效率和控制钢中夹杂物总量，可优化隧道炉的加热温度与在炉时间，大幅度提升了连铸生产效率，实现了中低牌号无取向硅钢的批量稳定制造，使CSP产线成为中低牌号无取向硅钢热轧板原料的主要供给生产线.如何进一步提升钢水纯洁度、提高连铸生产效率、降低生产成本，以及挖掘该产线生产薄带钢的技术优点，是未来工作的重点. This paper briefly introduces the practice of producing medium and low grade non oriented silicon steel(NGO) with CSP(compact strip production, CSP)technology in Wuhan Iron and Steel Co., Ltd.. This technology has the inherent advantages of uniform magnetic properties and good shape for silicon steel finished strip. However, in the actual production process, there are serious corrugated defects on the surface of silicon steel finished strip, and production efficiency of continuous casting is low... 

目的提高硅钢的磁性能。方法采用多弧离子镀技术,在普通取向硅钢薄板两面沉积高硅FeSi合金层制得高硅梯度硅钢,并进行热处理,观察其显微组织,测量磁性能。结果退火态高硅梯度硅钢表面的高硅FeSi合金层与基底结合紧密,均匀致密。高硅梯度硅钢中硅含量呈梯度分布,最表层硅质量分数为11.0%,随着深度增加,硅含量逐渐降低,在距表面20μm处硅质量分数仍能达到6.5%。沉积态高硅梯度硅钢的电阻率ρ、低频铁损P10/50、高频铁损P10/1k及磁感应强度B8分别为68.6μΩ·cm,0.82W/kg,83.3 W/kg和1.73 T,退火后分别为63.1μΩ·cm,0.44 W/kg,54.38 W/kg和1.89 T。结论由于表层高硅FeSi合金层的存在,梯度高硅钢的低频磁学性能良好,但高频损耗需进一步改善。 Objective To improve the magnetic properties of silicon steel. Methods FeSi alloy coatings with high-silicon content were deposited on the surface of common grain-oriented silicon steel by cathodic arc plasma evaporation,and then a kind of high silicon gradient steel was prepared. The morphologies,content and magnetic properties of the samples were tested. Results FeSi alloy coatings were featured with compact microstructures and excellent adhesive quality with the substrates. The silicon conten...