硅钢资料

分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained. 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

【作者】 姚昌国； ...

【机构】 武钢研究院； ...

本发明涉及无取向硅钢生产技术领域，公开了一种改善含Cu高强度无取向硅钢冷轧质量的方法，包括如下步骤：A)含Cu高强度无取向硅钢热轧卷化学成分(wt,％)：Si：2.0～3.5％，Als≤1.5％，Cu：1～3％，其他为Fe,Als,Mn以及不可避免的杂质元素，对热轧卷进行常化酸洗处理，常化温度T常满足：T常≤1620‑(0.5Als+1.5Si+Cu)％×104，单位℃；B)将常化后的热轧卷在电磁感应加热炉内进行加热；C)在冷轧机组开卷机进行开卷，冷轧第一道次开卷温度T冷轧满足：1.5×(Si+Cu)％×103‑T室温≤T冷轧≤40+2×(Si+Cu)％×103，单位℃，式中，T室温为室温；D)按照4‑6道次冷轧到目标厚度。本发明改善含Cu高强度无取向硅钢冷轧质量的方法，在采用传统常化工艺路线，保证较高的强度和磁性水平前提下，改善冷轧质量，提高成品成材率。

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

采用X-射线衍射分析技术测定了取向硅钢热轧板在不同压下率下不同厚度处的织构。结果表明,在压下率低于80%的情况下,几乎所有试样的不同厚度处的织构均为旋转立方织构类型{100}<011>,但不同压下率、不同厚度处的织构强度存在很大差异;在压下率大于80%的情况下,不同试样的不同厚度处的织构类型发生了变化,其织构类型为旋转立方织构或高斯织构{011}<100>,且当织构类型为旋转立方织构时,织构强度存在很大差异,而当织构类型为高斯织构时,织构强度差异相对较小。 The texture of the grain oriented silicon steel hot rolled plate at different compressibility has been measured.The experimental results have shown that the texture of all samples at different thickness is {100}<011> when the compressibility is below 80%,and its intensity at different compressibility and thickness is difference.The texture of all samples at different thickness is variable when the compressibility is above 80%,it is {100}<011> or {011}<100>,and the intensity of ... 

介绍了国内、外电工钢极薄带的生产现状及市场应用的情况,以及典型生产企业的生产规模、产品性能和应用领域,指出扩大高牌号无取向电工钢生产、提高产品质量是目前电工钢发展的迫切要求。 The production situation and market application of ultra thin electrical steel strip at home and abroad were described.The production capability,product property and application area of typical corporation were introduced.The results indicate that the urgency needed of electrical steel development is expanding high-grade non-oriented electrical steel production and improving products quality at present. 

对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550～650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550～650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin... 

本发明实施例公开了一种硅钢稀酸废水零排放处理方法和系统，所述方法包括：获得稀酸废水；对所述稀酸废水中的含硅固体杂质进行分离与回收，以获得稀酸废水净化液和含硅脱水泥饼；将所述稀酸废水净化液进行两级电吸附分盐处理，利用直流电场将稀酸废水中氯化亚铁组份浓缩分离，以获得分盐浓水和分盐淡水；将所述分盐浓水与酸再生工艺耦合，以获得再生盐酸；将所述分盐淡水调质再生处理，以获得铁系絮凝剂和再生工业净化水。所述硅钢稀酸废水零排放处理方法和系统，可以较低成本和能耗实现硅钢稀酸性废水全回用，真正实现废水零排放；可回收稀酸废水中的铁素和稀盐酸，不产生固体废物，可彻底实现废弃物资源化利用。

一种低温高磁感取向硅钢的热轧方法：经转炉冶炼并浇注成坯；对铸坯加热后进行粗轧：首先确定粗轧减宽量；根据所确定的粗轧减宽量进行粗轧；进行精轧；常规进行下工序。本发明采用低温板坯加热技术，降低了板坯烧损和修炉负担，且边裂发生率比现有技术的不低于18%的基础上能降低5%以上，由此节约资源及降低能耗。