钢厂
电感耦合等离子体质谱法测定硅钢中痕量铝钼钒钛铌
研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c...
无取向硅钢用磷酸盐涂层材料制备及其防腐性能
系统研究了无取向硅钢用磷酸盐系涂层性能的影响因素。以氢氧化铝和磷酸为原料制备磷酸二氢铝,再添加适量的添加剂酒石酸铵、二氧化硅、环氧树脂,得到的涂液涂布于硅钢表面,并控制合适的烘干温度,通过耐盐雾实验考察各因素对涂液耐腐蚀性能的影响。实验结果表明,在磷酸与氢氧化铝物质的量比为3.4∶1、酒石酸铵用量为2%、二氧化硅用量为1%、环氧树脂用量为5%、烘干温度为300℃条件下,所得涂层材料的防(耐)腐蚀效果最佳。 The factors influencing the performance of phosphate anticorrosive coating for non-oriented silicon were systematically studied.Aluminum dihydrogen phosphate was prepared with aluminum hydroxide and phosphoric acid as raw materials.Then added the right amount of additives,such as ammonium tartrate,silicon dioxide,and epoxy resin to prepare the liquid coating,which was coated on the surface of the silicon steel,and finally controlled a suitable drying temperature.The influences of various factors...
普通取向硅钢轧制过程中组织和织构的演变
借助电子背散射衍射(EBSD)及ZEISS-200MAT金相显微镜对某钢厂普通取向硅钢(CGO)进行研究,研究结果表明:热轧板组织、织构沿板厚方向存在明显的不均匀性,在热轧板表层及次表层发生再结晶,同时存在强度较高的Goss织构,中心层存在较强的{001}<110>变形织构。冷轧组织均呈纤维状条带组织,一次冷轧后,热轧板中的Goss织构消失,织构主要为α、γ织构,经中间脱碳退火后,α、γ织构强度减弱,并出现一定强度的Goss织构和利于Goss织构发展的{554}<225>、{332}<113>等织构,经二次冷轧后,二次冷轧织构类型与一次冷轧织构一致,但织构强度不同。 The grain-oriented silicon steel produced by a steel factory was investigated by EBSD and ZEISS-200 MAT metallographic microscope.The results show that the textures and microstructures along thickness of hot rolled slab are inhomogeneous.The surface layer and the layer near that are recrystallized structure which has a high Goss texture,but there is deformation texture{001}<110>in the central layer.The structure after cold rolling is a structure like fiber strip.After the first cold rollin...
球刻痕法对高磁感取向硅钢磁性的影响
试验研究了球刻痕法对高磁感取向硅钢的铁损、矫顽力、相对磁导率、巴克豪森噪声等磁学性能的影响.研究结果表明:经过球刻痕处理后,高磁感取向硅钢的铁损明显降低,矫顽力下降,8 mm球刻痕过后铁损值与矫顽力分别下降16.2%和14.7%,且铁损和矫顽力均随刻痕间距降低而减少.刻痕后的高磁感取向硅钢磁导率在高磁感应强度下明显上升,刻痕后巴克豪森噪声值明显降低,经过对比分析确定8 mm为球刻痕的最佳刻痕间距.从磁畴观察、细化磁畴的原理等方面解释了细化磁畴对高磁感取向硅钢性能的影响原因. The effects of the ball scribing on magnetic properties of high permeability grain-oriented silicon steels,including the iron loss,coercive force,relative permeability,and Barkhausen noise were investigated. The results showed that the iron loss and coercive force of the high permeability grain-oriented silicon steels apparently decreased 16. 2% and 14. 7% respectively after 8 mm ball scribing and they both decreased with the decrease of the scribing spacing at the same magnetic flux density. At...
铸坯热装温度对无取向硅钢中AlN和MnS析出行为的影响
通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo...
CN202121319771.9一种硅钢板冲裁余料处理工装
本实用新型涉及电机生产设备技术领域,特别涉及一种硅钢板冲裁余料处理工装,出料带通过支撑架平放在地面上,出料带的上方平行设置有安装在支撑架上的支撑砧板;支撑砧板的上方平行设置有上下滑动安装在支撑架上的刀架,刀架上设有切刀;支撑砧板的一端邻接有上料带,上料带将硅钢板冲裁余料送入到支撑砧板上。本实用新型的有益效果是:本实用新型可将成条的硅钢板冲裁余料进行自动裁切处理,裁切后的三角形的边角料会掉落到出料带中送出,此设备节省了大量的人力成本,提高了车间生产的安全性。
我国硅钢发展现状及发展趋势
硅钢是钢铁产品中的\"工艺品\",是高附加值产品,通过对我国主要硅钢生产厂家的工艺设备,市场情况分析,简要介绍了我国硅钢生产消费现状,未来生产能力预测及硅钢未来发展趋势。 Silicon steel is the \"crafts\" of steel products,also is high value-added product.By analyzing process equipment and market condition of major silicon steel-making plant of China,it briefly introduces our current production consumption status,future production capacity prediction and future development trend of silicon steel.
热变形温度对3%SiCGO硅钢组织和织构的影响
通过对3%Si CGO硅钢进行恒变形速率、不同变形温度下的单道次压缩实验,结合Thermal-Calc软件,金相分析,SEM及EBSD技术,研究了取向硅钢热变形过程中组织和微观织构的变化规律。结果表明:实验钢是在双相区变形,变形后组织主要是铁素体和少量的珠光体。随变形温度的升高,晶粒由长条状变为等轴状,尺寸逐渐变大;CGO硅钢在热变形过程中立方{100}<001>取向是较为稳定存在的。随着变形温度的提高,{111}<110>等取向逐渐转向{110}<1 10>取向,且{110}<1 10>取向逐渐变得锋锐。 3% Si CGO silicon steel was studied at constant strain rate and different deformation temperatures by single-pass compression deformation experiments to reveal the evolution of microstructure and texture during thermal deformation in oriented silicon steel,and the Thermal-Calc software,metallurgical,SEM and EBSD technique was used in the experiment. The results show that experimental steel is deformed at the temperatures of two-phase zone. The microstructure of the deformed steel consists of fer...
CN202111121416.5一种低铝无取向硅钢结晶器液面波动的控制方法
本申请公开了一种低铝无取向硅钢结晶器液面波动的控制方法,包括:步骤1:KR脱硫,脱硫后铁水硫含量≤0.0015%;步骤2:转炉吹炼,转炉出钢后钢包顶渣厚度≤30mm;步骤3:RH真空处理,RH脱碳结束后,加入铝粒脱氧后钢液循环3‑5min,提升气体流量至0.8‑1.0m3/(h·t);随后加入合金进行脱氧合金化,提升气体流量至0.5‑0.7m3/(h·t);步骤4:连续浇注,长水口氩气流量150‑200L/min,连铸塞棒氩气流量5‑10L/min,背压≥0.05bar。本申请的控制方法控制结晶器液面波动≤±1.5mm的比例稳定在90%以上。
不同尺寸电工钢样品磁性能检测对比分析
对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ...
CN202123158104.X一种变压器铁芯加工用硅钢片裁剪装置
本实用新型涉及变压器铁芯加工的技术领域,特别是涉及一种变压器铁芯加工用硅钢片裁剪装置,其可提高下料的便利性,同时提升工作效率;包括操作台、集料板、气缸、底架、两组立板、电机、从动轴、传送带、缓冲座、两组高弹簧和两组低弹簧,操作台底端设有四组支腿,操作台顶端设有送料组件和裁剪机,操作台上设有下料口,集料板转动安装在下料口内,气缸顶端和操作台底端固定连接,集料板底端滑动设有铰接座,气缸的输出端和铰接座铰接,立板通过两组立板固定安装在操作台底端,电机固定安装在底架前端,电机的输出端设有主动轴,主动轴转动安装在底架内,从动轴转动安装在底架内,主动轴和从动轴之间通过传送带传动连接。
CN202110760894.4一种显示取向硅钢高温退火试样显微组织的方法
本发明公开了一种显示取向硅钢高温退火试样显微组织的方法,其主要流程为:取样→制样→腐蚀→金相观察;本发明提供的方法显示的试样晶界清晰完整,达到人工和金相分析软件的评级要求,对于精确测量取向硅钢显微组织和磁性能分析提供了更加可靠的条件。