钢厂
氧硫交互作用对硅钢中非金属夹杂物生成的影响
结合工业化生产的无取向硅钢,探讨了氧硫交互作用对钢中夹杂物生成的影响。借助非水溶液电解+扫描电镜法,研究了不同O、S含量下钢中夹杂物的变化规律。结果表明,本实验条件下,提高O含量、降低S含量,会劣化热轧组织再结晶效果。在劣化效果上,O的作用大于S;低Si、无Al硅钢中,应尽可能降低O含量、适当提高S含量,以粗化钢中微细夹杂物,减少尺寸小于1.0μm的夹杂物的数量;O、S含量与钢中夹杂物数量不具有关联性。生产过程中,不仅要严格控制O、S含量,还要严格控制生产工艺,以免生成较多的有害夹杂物。 Based on the industrial production of non-oriented silicon steel,the effects of interaction between oxygen and sulfur on the formation of inclusions were discussed.The change of non-metallic inclusions in steel sheets was investigated by means of electrolysis with non-aqueous solution under different oxygen and sulfur content.Results show that the recrystallization microstructure of hot rolled sheets will be deteriorated with the increase of oxygen content and the decrease of sulfur content.The ...
Cr对含Nb高强无取向硅钢组织、织构及性能的影响
高强无取向硅钢主要应用于高速电机，要求其具备高强度和优异磁性能，但目前无取向硅钢的磁性能和强度难以兼顾。因此，设计并制备了添加微量Cr的含Nb高强无取向硅钢，通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明，添加质量分数为0.5%的Cr抑制了热轧组织的回复，使常化和退火组织再结晶减弱，常化和退火后有利织构面积分数增加，不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大，磁感略升高，但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用，另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强；而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成，使得织构因子增大；添加Cr使无取向硅钢的电阻率增加从而使铁损降低，同时Cr促进了Nb的析出，而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高，在两方面因素的综合作用下，添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此，... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren...
稀土处理无取向硅钢中夹杂物的控制
结合工业化生产的高效硅钢,进行了RH精炼稀土处理试验研究。针对不同的稀土处理条件,观察了夹杂物的形貌和尺寸分布,探讨了稀土处理后钢中的夹杂物形成、变化规律。结果表明:试验条件下,最佳的稀土合金添加数量为0.6～0.9 kg/t。经过合适的稀土处理后,可以有效抑制尺寸相对较小的、不规则的AlN、MnS复合夹杂生成,促进钢中微细夹杂物的聚合、上浮,钢质纯净度得到明显提高。此时,钢中全氧含量最低,脱硫效果最佳,钢中的夹杂物主要是尺寸相对较大的、近似球形或者椭球形的稀土类夹杂。 Based on the industrial production of non-oriented silicon steel,the experiment on RE treatment during the RH refining process was studied.The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions.Further more,the formation and change of inclusions of final steel sheets after RE treatment were discussed.The results show that the suitable RE added amount was 0.6～0.9 kg/t.After the suitable RE treatment,the formation of AlN and Mn...
高温退火气氛对硅钢表面硅酸镁底层形貌的影响
对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟，利用X射线衍射仪（XRD）分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成，采用场发射扫描电镜（SEM）观察了样品表面氧化层和底层在截面方向上的微观形貌特征，并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明：当退火气氛的露点温度保持一定时，较高的氢气含量有利于生成完整连续的底层；当退火气氛的水氢分压比保持一定时，在露点温度与氢气含量两者较低的条件下，底层附着性不佳易脱落，较高条件下，底层中夹杂着较多的铁单质；当氧化层中无FeO时，底层完整连续但易脱落，当FeO层较薄时，底层下方存在部分未反应的SiO2,当FeO层较厚时，底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer（XRD） was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy（SEM） was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ...
退火温度对无取向电工钢磁晶各向异性能的影响
采用取向分布函数分析了无取向电工钢不同再结晶退火温度下的织构变化及织构对磁感应强度和铁损的影响,并计算了无取向电工钢的磁晶各向异性能。结果表明,随着实验钢的再结晶退火温度升高,Goss织构和立方织构组分显著增强,而{111}面织构强度却减弱。较高的退火温度有利于减小织构因子,提高磁感应强度。磁晶各向异性能计算结果显示,随着再结晶退火温度升高,无取向电工钢板的磁晶各向异性能降低。 The recrystallization texture and the relationship of texture to magnetic induction intensity and core loss of a non-oriented electrical steel were investigated by orientation distribution function analysis. The magnetic anisotropy energy of the steel was calculated also. The results show that,the intensity of Goss texture and cubic texture increases,but the intensity of { 111} texture decreases with increasing recrystallization annealing temperatures of the steel. The higher annealing temperatu...
无取向硅钢铬酸镁绝缘涂层结构与耐蚀性能研究
采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e...
微合金元素对冷轧取向电工钢再结晶行为的影响
以取向电工钢成分为基础,制备了含C或Mn和S的4种实验钢。观察了接近平衡析出状态实验钢经60%冷轧后在600～1000℃范围再结晶退火过程中微观组织演变,统计分析了再结晶体积分数随退火时间的变化规律,进而计算了各实验钢静态再结晶的激活能。观察了高含C实验钢退火初期再结晶晶粒优先出现的部位。结果表明900～1000℃范围内各实验钢铁素体的化学成分相似,因而其再结晶激活能基本一致。在600～800℃范围内铁素体内会有阻碍再结晶进程的三次渗碳体析出,从而使再结晶激活能明显提高。高C含量实验钢中还会有从奥氏体转变而来的粗大珠光体或渗碳体,轧制过程中其附近形成的变形区会促进600～800℃加热时该区域附近率先发生再结晶形核、降低再结晶激活能。固溶的Mn、S元素可微弱提高再结晶激活能,但高Mn、S含量会改变粗渗碳体从奥氏体析出时的形态。 Four experimental steels based on grain oriented electrical steel containing C,or Mn and S were prepared.Microstructure evolution of the steels close to a state of equilibrium precipitation were observed during annealing processes at 600-1000 ℃after 60% cold rolling,the changes of recrystallization volume fraction were analyzed statistically as the annealing was prolonged,and the activation energy for static recrystallization of the steels were calculated.The locations,where the recrystallizatio...
稀土铈含量对1.2%Si无取向电工钢组织、织构及磁性能的影响
在实验室模拟CSP流程制备了不同含量稀土铈(质量分数0~0.018%)的1.2%Si无取向电工钢,并对其进行1 000℃×5min的再结晶退火处理,研究了铈质量分数对无取向电工钢夹杂物、显微组织、再结晶织构和磁性能的影响。结果表明:随着铈质量分数的增加,微细夹杂物数量、再结晶晶粒尺寸、{100}和{110}织构组分、磁感应强度先增后减,{111}织构组分、铁损先减后增;铈的质量分数为0.005 1%时,钢中的夹杂物数量最少,再结晶晶粒尺寸最大,有利织构最多,磁性能最优,铁损P15/50为3.253W·kg-1,磁感应强度B50为1.751T。 Non-oriented electrical steels containing different contents rare earth Ce element(0-0.018wt%) were prepared in the laboratory by simulated CSP(compact strip production)process,and then recrystallization annealing at 1 000 ℃ for 5 min were performed,the effects of Ce content on inclusion,microstructure, recrystallization texture and magnetic properties of non-oriented electrical steels were studied.The results show that with the increase of Ce content,the amounts of fine inclusion,the size of re...
冷轧硅钢废水处理现状、问题及对策浅析
就冷轧硅钢废水处理生产中面临的主要问题进行分析,从技术角度及运行管理角度提出工艺优化升级改进措施及应对策略;同时从后续深度处理,逐步实现零排放目标的角度进行探讨,为冷轧硅钢废水减量化、出路乃至废水零排放提供一些思路。 The main problems in the wastewater treatment process of cold-rolled silicon steel lines are analyzed and process upgrading measures and optimization strategy are put forward from both technical and management views.At the same time,downstream deep treatment to gradually achieve the target of zero discharge is discussed,to provide some ideas for reduction or even zero discharge of wastewater from cold-rolled silicon steel lines.
