论文

对冷轧无取向硅钢在冶炼过程中各个工序的顶渣进行了检测,分析了顶渣变化原因,并得出结论:硅钢生产宜采用复吹转炉,以降低吹炼终点渣中TFe含量,进而减轻对精炼的压力;使用低S、低Al2O3含量中间包覆盖剂;RH脱氧及合金化顺序采用先加硅铁后加铝;首罐宜经LF提温并降低渣中TFe。 The top-surface slag used for the various production processes in smelting coldrolled non-oriented electrical steel is tested and based on tested results the cause of the top surface slag change is analyzed.So it is concluded that the combined blown converter is more suitable to be used for smelting electrical steel in order to reduce the content of TFe in slag at blow end point and then much better results can be achieved during the period of refining.Secondly the tundish flux contenting low co... 

利用EBSD技术对CGO硅钢热轧、中间退火、脱碳退火及二次再结晶退火组织及织构进行分析,研究了CGO硅钢各阶段加工制备过程中高斯{110}<001>晶粒的形状、尺寸及分布特点,分析了高斯取向晶粒在各工序过程中的遗传继承性特点。结果表明,CGO硅钢热轧板的次表层存在Goss取向晶粒,历经一次冷轧及中间退火后Goss取向晶粒基本消失,一次再结晶之后Goss织构仍不是主要织构,主要织构为{111}<110>和{111}<112>,说明Goss取向晶粒在二次再结晶退火前数量及尺寸上并不占优势,二次再结晶过程中Goss取向晶粒异常长大形成锋锐Goss织构。{111}<110>和{111}<112>织构组分的强度在一次冷轧中不断增加,{111}<112>织构组分的强度在二次冷轧后达到最大而{111}<110>织构组分是在初次再结晶后变强。 Grain shape,size and distribution of { 110} < 001 > Goss grains in CGO steel and the hereditary characteristics of Goss orientated grains during each processing period were investigated,based on the analysis of the microstructure and texture of the CGO silicon steel during hot rolling,intermediate annealing,decarburizing annealing and secondary recrystallization annealing by means of EBSD. The results show that Goss orientated grains exist in the subsurface of the hot rolled plate,and Goss... 

通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows... 

结合工业化生产的无取向硅钢,探讨了氧硫交互作用对钢中夹杂物生成的影响。借助非水溶液电解+扫描电镜法,研究了不同O、S含量下钢中夹杂物的变化规律。结果表明,本实验条件下,提高O含量、降低S含量,会劣化热轧组织再结晶效果。在劣化效果上,O的作用大于S;低Si、无Al硅钢中,应尽可能降低O含量、适当提高S含量,以粗化钢中微细夹杂物,减少尺寸小于1.0μm的夹杂物的数量;O、S含量与钢中夹杂物数量不具有关联性。生产过程中,不仅要严格控制O、S含量,还要严格控制生产工艺,以免生成较多的有害夹杂物。 Based on the industrial production of non-oriented silicon steel,the effects of interaction between oxygen and sulfur on the formation of inclusions were discussed.The change of non-metallic inclusions in steel sheets was investigated by means of electrolysis with non-aqueous solution under different oxygen and sulfur content.Results show that the recrystallization microstructure of hot rolled sheets will be deteriorated with the increase of oxygen content and the decrease of sulfur content.The ... 

介绍了硅钢CSP工程辊底式均热炉的技术特性,详细阐述了辊底式均热炉工艺特点。根据硅钢均热要求,通过采取不同烧嘴布置方法和燃烧控制技术,选用耐火纤维模块和绝热材料等相关技术措施,满足了出钢温度要求。 The technical specialty for roller hearth furnace of silicon steel CSP Plant was introduced,and the technology characteristics of the roller hearth furnace were illuminated in detail.According to the reheating require of the silicon steel,different burner arrangement and combustion control methods were applied,and technology measures such as selecting refractory fiber module and insulation material and so on were taken,the temperature requirement of silicon steel was met. 

高强无取向硅钢主要应用于高速电机，要求其具备高强度和优异磁性能，但目前无取向硅钢的磁性能和强度难以兼顾。因此，设计并制备了添加微量Cr的含Nb高强无取向硅钢，通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明，添加质量分数为0.5%的Cr抑制了热轧组织的回复，使常化和退火组织再结晶减弱，常化和退火后有利织构面积分数增加，不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大，磁感略升高，但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用，另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强；而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成，使得织构因子增大；添加Cr使无取向硅钢的电阻率增加从而使铁损降低，同时Cr促进了Nb的析出，而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高，在两方面因素的综合作用下，添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此，... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren... 

【作者】 严伟明； ...

采用经验设计法初步确定了取向硅钢铸坯感应加热线圈设计参数,应用Ansoft仿真软件分别对36组不同线圈高度、线圈内径的感应加热炉在不同频率下的三维整体磁场和铸坯的温度场进行了数值仿真。通过对比仿真结果,确定电磁场分布最佳的一组感应加热炉设计参数为线圈高度h=1.50 m、线圈内径D1=0.575 m、电流频率f=110 Hz。在该参数下应用Ansoft仿真软件对取向硅钢铸坯感应加热炉的温度场进行了仿真,结果发现温度场分布均匀,可满足取向硅钢铸坯加热要求。 The induction heating coil design parameters for the oriented silicon steel casting blank were determined preliminary by experience design method,and 36 groups three-dimensional electromagnetic field with different height and inside diameter of coil under different frequencies of the induction heating furnace and the temperature field of the casting blank were investigated by numerical simulation using Ansoft simulation software. By comparing the simulation results of electromagnetic field distr... 

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

【机构】 宝山钢铁股份有限公司规划与科技部； ...

采用轧制法制备出具有低铁损高磁感0.23mm厚6.4%(质量分数)Si高硅钢。沿轧制方向的最终磁性能为B8=1.474 T,B50=1.714 T;P10/50=0.30W/kg,P15/50=0.88W/kg。利用X射线衍射及背散射电子衍射(EBSD)技术分析了高硅钢在轧制及退火过程中的织构演变过程。结果表明,通过采用大压下率热轧,确保热轧板次表层中产生更多的高斯织构,随后进行遗传;温轧板中粗大的晶粒有利于冷轧剪切带的形成;冷轧板经脱碳退火后生成强{210}〈001〉织构及次表层较强的高斯织构是在轧向上获得高磁感的原因,归因于其在{111}〈112〉冷轧形变晶粒内的剪切带优先形核并长大;最终退火后虽出现了随机取向,但以{310}〈001〉织构为代表的η织构得以保留并且增强,进一步提高了磁感。随着退火温度的升高及保温时间的延长,高硅钢薄板晶粒尺寸不断增大,铁损明显降低。 6.4wt%Si high silicon steel sheets(0.23mm thick)with low iron loss and high magnetic induction were successfully produced by rolling process.The final magnetic properties along the rolling direction(RD) were:B8=1.474T,B50=1.714T;P10/50=0.30 W/kg,P15/50=0.88 W/kg.The texture evolution during rolling and annealing was investigated by means of X-ray diffraction and electron backscatter diffraction(EBSD).It was found that more Goss textures formed in the subsurface of hot rolled plates by using larg... 

试验的铸态取向硅钢（/%:0.044⁰.056C,3.12³.32Si,0.08⁰.11Mn,0.002⁰.008S,0.002 9⁰.029 1Als,0.006 2⁰.010 9N）由30 kg高频真空感应炉熔炼。通过场发射扫描电子显微镜/能谱仪（FE-SEM/EDS）研究结果表明,0.002 9%Als钢中氧化物主要为SiO₂,存在片状、棒状及近似球状的独立MnS,未发现含铝的氧化物或氮化物;0.0090%Als钢中出现以Al₂O₃为主的复合氧化夹杂物,存在MnS与AlN的复合析出物。钢中Als增加,复合析出物多呈簇状发展。氧化物容易成为MnS-AlN复合析出的核心,钢中Als含量越低,夹杂物中的MnS含量越高;作为核心的氧化物夹杂的尺寸越小,形成的复合夹杂物的形状越规则,尺寸也越小。热力学计算结果表明,钢中Als含量主要影响了钢中氧化物夹杂的组成和AlN的析出温度及析出量。 Test as-cast grain-oriented silicon steel（/%:0.044 ⁰.056C,3.12 3.32Si,0.08 0.11Mn,0.002⁰.008S,0.002 9⁰.029 1 Als,0.006 2⁰.010 9N） is melted by a 30 kg high frequency vacuum induction furnace.The research results by using field emission-scanning electron microscope/energy dispersive spectrometer（FE-SEM/EDS） show that in 0.002 9%Als steel the main oxide is SiO₂,and there is independent laminable,rod-like and approximate ...