钢厂
温度及扩散时间对CVD法制备高硅钢的影响
采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r...
退火温度和时间对用电沉积法制备的高硅钢性能的影响
研究了退火温度和退火时间对电沉积硅钢试样中的断面层组织、硅在试样中的分布情况、织构分布和磁性能的影响。结果表明:退火温度为1000℃、退火时间为210 min时得到的试样晶粒分布均匀、硅在试样中分布均匀、硅平均浓度为6.3715%(接近6.5%)。试样的织构分析及磁性能检测的结果表明,在较高温度下延长退火时间可增加{100}和{110}面织构,降低铁损,所得试样的磁性能较为良好。 The effect of annealing temperature and time on the microstructure, distribution of silicon,texture and magnetism of the high silicon steel prepared by electrodeposition was investigated. The results showed that after annealing at 1000℃ for 210 min, the mean grain size of steel was about 190 μm with a uniform grain size distribution, and the silicon is also uniformly distributed on the entire cross section with an average Si concentration 6.3715%(close to 6.5%); With the increasing annealing tim...
退火温度对2%Si无取向电工钢磁性能的影响
研究了传统工艺流程生产的2%Si无取向电工钢在不同退火温度下的磁性能。研究结果表明,随着退火温度的升高,显微组织均匀性提高且晶粒尺寸增大;有利织构组分{100}<0vw>、α、η增强,不利织构组分减弱;成品的铁损P1.5/50先下降后略有上升,磁感B50上升平缓;在890℃×2 min的退火工艺条件下,成品电工钢的磁性能最佳,对应的铁损P1.5/50小于3.2 W/kg,磁感B50高于1.74 T。 In this paper,the effect of annealing temperature on magnetic properties of non-oriented electrical steel with 2% silicon was studied.Results show that the uniformity of microstructure and the average grain size increase with the rise of annealing temperature.The texture components of annealing can be improved by enhancing {100} <0vw>,α,η fiber textures and weakening {111} <112> fiber texture.The tendency of core loss P1.5/50 shows that it decreases first and then increases,while the...
TSCR热轧工艺对3.2%Si无取向硅钢组织性能的影响
研究了薄板坯连铸连轧流程(TSCR)条件下热轧工艺对3.2%Si-0.7%Al无取向硅钢组织、织构演变及磁性能的影响规律。结果表明,提高均热温度和热轧温度有助于获得粗大的变形组织和强烈的{001}〈110〉织构,进而对后续的组织、织构演变进程及磁性能产生有利的遗传影响。与低温均热和低温热轧相比,高温均热和高温热轧得到的最终成品板的再结晶晶粒较粗大,λ纤维再结晶织构较强而γ纤维再结晶织构较弱,磁感应强度较高。 It was investigated that the effects of thin slab cast rolling(TSCR) hot rolling processes on microstructural,textural evolution and magnetic properties of 3.2%Si-0.7%Al non-oriented silicon steel.The results show that much larger hot rolling deformed microstructure and much stronger {001}〈110〉 texture could be obtained by increasing the soaking and hot rolling temperatures,which had good heritable effects on subsequent microstructural,textural evolution and magnetic properties.The final sheets ...
国内外中低牌号无取向硅钢夹杂物控制效果解析
选用国内外无取向硅钢标杆企业A、B、C的产品,采用非水溶液电解提取+SEM(EDS)方法,分析了其典型牌号对应成品试样中的夹杂物。结果表明,从磁性能控制角度而言,受钢的化学成分及生产工艺影响,A、B、C企业成品试样的夹杂物尺寸、种类、数量存在差异,这些差异对其磁性能产生显著影响;从夹杂物控制角度而言,A、B、C企业对应成品试样的夹杂物,以MnS、CuxS复合或者AlN、MnS、CuxS复合为主,其中1.0μm以下的夹杂物数量分别为2.34×107个/mm3、2.98×107个/mm3和11.98×107个/mm3,1.0μm以上夹杂物数量均很少,夹杂物的平均尺寸从大到小依次为A企业、B企业、C企业。 According to the production of three benchmarking manufacture enterprises A,B and C of non-oriented silicon steel at home and abroad,the inclusions in finished steel samples with typical grades were investigated by electrolytic extraction from non-aqueous solution and SEM(EDS).Results show that,from the viewpoint of improving the magnetic properties,affected by chemical composition and production technique,the size,type and amount of inclusions in finished steel samples are various,which will af...
低温取向硅钢热轧态组织及织构的研究
利用热模拟试验机、光学显微镜和X射线衍射仪对Fe-3.2%Si低温取向硅钢热轧工艺参数对组织及织构的影响进行了研究。结果表明,Fe-3.2%Si硅钢在1110℃粗轧、880℃终轧,轧后以10℃/s的速度冷却到550℃卷取,然后空冷到室温,热轧硅钢板沿板厚方向的显微组织不均匀性显著,对后续发展完善的二次再结晶有重要作用。无论是热轧板,常化板还是冷轧板,它们的织构集中分布在γ取向线上,γ取向线的织构除取向密度不同外,织构种类是一致的,这说明γ取向线上织构是有继承性的。从热轧到常化,织构取向密度显著减小,经二次冷轧后,织构密度又显著升高,可见,轧制变形有助于织构的形成并使织构强度升高。 The influence of hot-rolled process parameters on the microstructure and texture of Fe-3.2%Si low temperature hot rolled grain-oriented silicon steel were researched by hot simulation experiment machine,light microscope and X-ray diffractometer.The results show that,Fe-3.2%Si silicon steel is rolled by the technology with a temperature of rough rolling of1110℃,finish rolling of 880℃,coiling with the speed of 10℃ /s,and then cooled to room temperature with air.The microstructure of hot-rolled sil...
RH精炼添加钙合金去除硅钢夹杂物研究
采用RH精炼添加钙合金方式对硅钢进行钙处理。结果表明,钙合金添加量为0.67、1.00、1.67kg/t钢时,钢中钙含量分别为0、2×10-6、4×10-6;随着钙合金添加量增大,钢中夹杂物粒度逐渐由0～2μm向2～4、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或同AlN、CaS夹杂复合;粒径为5～10μm区间,钢中的夹杂物基本以钙的氧、硫化物为主。与钙处理前相比,钙合金添加量为0.67、1.00、1.67kg/t钢时,粒径小于1.0μm的微细夹杂物减少幅度分别为68.06%、87.50%、94.94%。钙合金添加量为1.67kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 Ca alloy was added into the liquid steel during RH refining,and the results show that Ca concentration in final Si steel sheets is insignificant,about 0,2×10-6 and 4×10-6 when the added amount of Ca is 0.67,1.00 and 1.67 kg/t steel,respectively.With the increase in the added Ca alloy amount,the inclusions in the steel gradually change from those of 0～2 μm to those of 2～4 and 4～6 μm.Under different Ca treatments,there exist MnS and CuxS inclusions whose size is below 1 μm as well as MnS and CuxS ...
热变形温度对3%SiCGO硅钢组织和织构的影响
通过对3%Si CGO硅钢进行恒变形速率、不同变形温度下的单道次压缩实验,结合Thermal-Calc软件,金相分析,SEM及EBSD技术,研究了取向硅钢热变形过程中组织和微观织构的变化规律。结果表明:实验钢是在双相区变形,变形后组织主要是铁素体和少量的珠光体。随变形温度的升高,晶粒由长条状变为等轴状,尺寸逐渐变大;CGO硅钢在热变形过程中立方{100}<001>取向是较为稳定存在的。随着变形温度的提高,{111}<110>等取向逐渐转向{110}<1 10>取向,且{110}<1 10>取向逐渐变得锋锐。 3% Si CGO silicon steel was studied at constant strain rate and different deformation temperatures by single-pass compression deformation experiments to reveal the evolution of microstructure and texture during thermal deformation in oriented silicon steel,and the Thermal-Calc software,metallurgical,SEM and EBSD technique was used in the experiment. The results show that experimental steel is deformed at the temperatures of two-phase zone. The microstructure of the deformed steel consists of fer...
