论文

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

取向硅钢利用析出物作为抑制剂,抑制初次再结晶晶粒的长大,抑制剂是取向硅钢发生二次再结晶的基本条件之一。文中通过低温板坯加热技术制备取向硅钢,采用透射电镜(TEM)观察并研究了高温退火阶段抑制剂的演化过程。结果表明,渗氮后形成的非晶态Si3N4析出物不稳定,在700～750℃退火升温阶段转化为(Al,Si)N;(Al,Si)N颗粒在800℃发生团聚,随后长大并粗化;(Al,Si)N是低温取向硅钢主要抑制剂,随退火温度的升高,(Al,Si)N抑制力大幅下降。 Precipitates as inhibitor are used to inhibit the grain growth of primary recrystallization in grain-oriented silicon steel,and inhibitor is one of the basic conditions for occurring of secondary recrystallization.The grain-oriented silicon steel was produced by low temperature slab heating and nitriding technique.The evolution of inhibitor was observed by transmission electron microscopy.The results show that Si3N4 particles are precipitated after nitriding,and Si3N4 particles are amorphous and... 

双辊连铸技术是冶金及材料领域内的一项前沿技术,对于生产高品质硅钢具有独特优势.本实验研究了一种双辊铸轧w[Si]=4.5%的无取向硅钢,考察其铸态和常化处理后样品的组织、织构及析出相尺寸特征.结果表明:铸带组织以与铸带法向成5~20(°)倾角的柱状晶为主,晶内存在少量0.3~0.4μm的AlN析出相,铸带织构以λ(<001>//ND)织构为主,表层织构漫散.950℃/10 min常化处理后,析出相尺寸增大,表层λ织构增强. As an advanced technique of metallurgy and material science,twin- roll strip casting has unique advantages for producing high quality silicon steel. The present study was aimed at a 4. 5% Si non- oriented electrical steel for analyzing the structure,texture and the size of precipitates at the initial and normalized state. The results revealed that the initial structure mainly consisted of columnar grains with 5 ~ 20( °) angle to the normal of cast strip,and some AlN precipitates of 0. 3 ~ 0. 4 μ... 

采用扫描电镜、场发射扫描电镜、能谱仪等对50SW1300冷轧无取向硅钢中的夹杂物分不同尺寸区间进行数量统计,利用主成分回归分析法,即数据的标准化处理—主成分分析—回归分析—标准化的变量还原成原始变量—确定显著影响因素,综合分析夹杂物总量及各尺寸区间的夹杂物数量对无取向硅钢磁性能的影响。结果表明:主成分回归分析能够从夹杂物尺寸区间及数量的多个影响因素中提取主要的因素,定量研究其对磁性能的影响。分析表明,显著影响无取向硅钢铁损的夹杂物为100~500nm的AlN、AlN+MnS、MnS、Al2O3、AlN+Al2O3,而劣化磁感最明显的夹杂物尺寸区间为100~200nm。 Different size intervals of inclusions in cold rolled non-oriented silicon steel 50SW1300 were counted by scanning electron microscope(SEM),field emission scanning electron microscope(FESEM)and energy disperse spectroscopy(EDS).With principal component regression method:standardization for experimental data,principal component analysis,regression analysis,transform standardized variables into original variables,determination of significant factor,effects of the total number of inclusions and the... 

基于BOF→RH→CSP生产工艺,研究了RH精炼过程钢中夹杂物类型演变及MgO·Al2O3夹杂物形成规律,同时对MgO·Al2O3夹杂物的形成条件进行了热力学计算,借助CFD数值模拟软件研究了RH精炼过程卷渣行为。研究发现,RH精炼过程20和30 min时,w([MgO])/w([Al2O3])为0.005~0.020,未发现MgO·Al2O3夹杂物;RH出站后夹杂物w([MgO])/w([Al2O3])为0.3~0.5,且RH精炼结束后MgO·Al2O3夹杂物占夹杂物总量的58.4%;另外,RH精炼过程钢液表面速度CFD模拟结果为0.57 m/s,大于临界卷渣速度0.45 m/s,且顶渣成分与夹杂物成分相近,存在卷渣现象。热力学计算表明,钢液与炉渣平衡时钢中w([Al])为0.31%~0.37%,w([Mg])为0.00024%~0.00028%,在MgO·Al2O3生成区域之内。减少RH处理过程卷渣,浇铸过程下渣及控制顶渣和包衬相中MgO质量分数可抑制MgO·Al2O3夹杂物形成。 Based on the practical production of non-oriented silicon steel, the evolution of inclusion type and the formation of MgO·Al2O3inclusion were analyzed in the process of BOF→RH→CSP. The thermodynamic conditions for forming MgO·Al2O3inclusion were discussed and the behavior of slag entrapment of molten steel was also simulated by CFD software during RH refining. The results showed that the value of w([MgO])/w([Al2O3]) was in the range of 0.005-0.020 and no MgO · Al2O3 inclusion was observed at 20 ... 

【作者】 陶永根； ...

冷轧无取向硅钢是高技术含量、高附加值产品,工艺复杂,生产周期长,过程控制难度大,被誉为钢铁产品中的\"工艺品\"。热轧生产工艺又是无取向硅钢生产的重中之重,直接决定了硅钢的铁损和电磁性等多项指标。 Cold rolled non-oriented silicon steel is high technology content 、high added value product. Its process is complex, its production cycle is of length, and its process control is difficult, which is known as the iron and steel products \" Arts and crafts\". Hot rolling production process is the top priority of non-oriented silicon steel, which directly determines iron loss of the silicon steel and electromagnetic property,as well as other many index. 

【作者】 欧阳帆； 肖侃； ...

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

用Gleeble1500D模拟试验机在变形温度为950～1 200℃、应变速率为0.01～8s-1、最大变形程度为60%的条件下,对硅钢50A1300做单道次压缩试验,首先分析了不同参数对流变应力的影响,然后用回归法确定了应力模型中的变形激活能及材料常数,得到硅钢50A1300在峰值应力条件和稳态应力条件下的变形激活能分别为270.360和91.557kJ/mol,同时得到了流变峰值应力模型,模型的相关系数为0.997。最后通过作lnθ-ε图的方法找到了硅钢50A1300发生动态再结晶的临界应变量,并回归得到峰值应变量、临界应变量与参数Z/C的关系式。 To analyze the effects of different parameters on the flow stress and critical strain of the dynamic recrystallization,single-pass compression experiments were carried out with silicon steel 50A1300 specimens using a Gleeble1500D thermal simulator at a temperature range of 950-1 200 ℃ and strain rate range of 0.01-8 s-1 under the condition of maximum deformation of 60%.The average deformation activation energy is respectively 270.360 and 91.557 kJ/mol under the peak stress and steady-state stres... 

电工钢反复弯曲次数是电工钢性能检验的重要指标之一,直接影响到用户在使用电工钢过程的机加工性能。主要分析了试样宽度、试样张力、晶粒取向、反复弯曲设备等因素对电工钢反复弯曲试验的影响,并对各个因素的影响程度进行量化以及原因探讨,从而归纳形成各影响因素的基本规律,以便为电工钢实际生产、用户使用提供科学指导。结果表明:试样宽度增加,反复弯曲次数也会不断增加,晶粒位向对取向电工钢的反复弯曲次数影响较大,当支座顶部到拨杆底部的距离减小或拉紧力增加时,反复弯曲次数会不断减小,但当拉紧力达到60N以上时,对反复弯曲次数影响不大,试样经退火后,反复弯曲次数略有上升。 The reverse bend number is an important performance of electrical steels′capabilities,affecting the machining performance directly when the customers used.It investigated some factors,such as sample′s width,sample′s tension load,grain orientation and equipment,how to effect the reverse bend test for electrical steel,measured the influence degree,and discussed the reason,in order to form basic rules which could be guided the manufacturing and using for electrical steel.Results showed that the rev... 

本文介绍了无取向硅钢C6涂液的性能,研究了配水量、固化程度和涂层厚度等因素对无取向硅钢C6涂层性能的影响。结果表明,随着配水量的增加,完全固化所需的时间增加,涂液固体含量降低,涂层厚度减小;随着固化程度的提高,涂层硬度先增大然后趋于恒定,而柔韧性逐渐变差,在过固化后急剧恶化;涂层厚度对涂层的表面外观、附着性和绝缘层间电阻均有显著影响。 Based on the introduction about the performance of C6 varnish for non-oriented silicon steel sheets,effects of water amount,curing degree and coating thickness are discussed. Results show that with the increase of water amount,the time required to cure completely extends,and both the solid content of C6 varnish and the coating thickness decrease. As the curing degree increases,the hardness of the coating increases first and then tends to be constant,however the flexibility degenerates,especially...