论文

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

【机构】 宝山钢铁股份有限公司规划与科技部； ...

电工钢试样加工产生的剪切应力会恶化钢板的磁性,对不同牌号硅钢片的横向、纵向试样退火前后磁性能的变化进行研究,结果表明:无取向硅钢片在剪切过程中横向、纵向的磁性受到剪切应力影响是不一样的。 The electrical steel sample processing magnetic of electrical steel will worsen due to the shear stress of sample. In this paper,the magnetic change of transverse,longitudinal specimens of different type of silicon steel sheet before and after annealing are studied. The results show that the magnetic of non- oriented silicon steel sheet affected in the process of shear is not the same in horizontal and vertical direction. 

对无取向硅钢炼钢全流程钢液增钛的原因进行了分析,认为铁水钛含量、转炉出钢温度、转炉下渣量、精炼渣TiO₂含量、钢水罐及RH浸入管混钢种生产是影响钢液增钛的主要原因。通过采取低钛铁水冶炼,减少转炉下渣量,提高出钢温度,添加白灰改质精炼渣等措施,均能够降低钢液中的钛含量。 After analyzing the causes leading to increased content of titanium in molten nonoriented silicon steel during whole steelmaking process, it was concluded that such factors as content of titanium in hot metal, tapping temperature from converter, quantity of roughing slag entered into the ladle from converter, content of TiO₂ in refining slag, molten steel ladle car,carrying out the steelmaking of different steel grades by the same ladle and same RH immersion tube were the main causes ... 

利用OM、TEM与EDS技术,对Fe-3.2%Si低温取向硅钢热轧板进行不同常化冷却工艺处理后的显微组织、析出相及最终产品的磁性能进行分析,并与热轧板的组织和析出相进行对比。结果表明,常化板较热轧板的表层组织均匀,基体中再结晶比例增加,带状组织变窄;常化板中析出物的数量明显比热轧板的多,析出物主要有AlN、MnS及复合析出的(Cu,Mn)S等。在常化温度1120℃、保温3 min的条件下,采用二段式冷却较空冷、淬沸水、淬常温水的冷却工艺,常化板表层显微组织更均匀,沿板厚方向的显微组织的不均匀性显著,取向硅钢的磁性能最高;常化后采用二段式冷却工艺析出的细小析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利。 Microstructure, precipitate and magnetic characteristic of final products with different normalizing cooling processes for Fe-3.2%Si low-temperature hot-rolled grain-oriented silicon steel were analyzed and compared with the hot-rolled plate by optical microscopy(OM), transmission electron microscopy(TEM), and energy dispersive spectrometry(EDS). The results show that, the surface microstructure is uniform, the proportion of recrystallization in matrix increases, and the banding textures are nar... 

观察了取向硅钢极薄带经冷轧至不同厚度,并经过不同工艺热处理后的显微组织及亚结构。结果表明:冷轧压下量越大,显微组织中位错密度越高,冷变形组织越多,等轴晶粒越少;增加冷轧压下量可以使试样的再结晶温度降低,当钢带厚度为0.08 mm时,在650℃退火时就能发生明显的再结晶。 Microstructure and substructure of the grain oriented ultra-thin silicon steel sheets is analyzed,which are rolled down to different thickness and treated with different heat treatment process.The result shows that there are higher dislocation density,more cold deformation structure and less equiaxed crystal grain in microstructure of the steel sheets with more cold rolled reduction.Increase of cold rolled reduction will decrease recrystallization temperature,and when thickness of the steel shee... 

研究的两种取向硅钢（%:No1-0.042C、3.16Si、0.009Al、0.07Mn、0.50Cu、0.015S、0.0084N和No2-0.040C、3.20Si、0.014Al、0.22Mn、0.49Cu、0.016S、0.008 2N）由50 kg真空感应炉冶炼,锻成（mm）350×120×35板坯,经1 250℃30 min加热,开轧温度1 100℃,5道次热轧成2.3 mm板,终轧温度950～1 000℃。实验结果表明,两热轧板沿板厚方向存在组织和织构的不均匀性,热轧板次表层为再结晶组织,有较强的Goss织构组分;中心层为形变组织,具有典型的形变织构。含0.22%Mn的No2钢次表层{110}〈001〉织构组分比含0.07%Mn的No1钢弱,中心层{001}〈110〉织构组分大大强于0.07%Mn No1钢,导致两者磁性能差异,0.22%Mn No2钢磁感应强度(B₈₀₀)和铁损(P_1.7/50)分别为1.87 T和1.24 W/kg,0.07%Mn No1钢分别为1.88 T和1.18 W/kg。 Studied both grain-oriented silicon steels（%:No1- 0.042C,3.16Si,0.009Al,0.07Mn,0.50Cu, 0.015S,0.0084N and No2-0.040C,3.20Si,0.014Al,0.22Mn,0.49Cu,0.016S,0.0082N） are melted by a 50 kg vacuum induction furnace,forged to（mm） 350×120×35 slab,heated at 1 250℃for 30 min,with beginning rolling temperature 1 100℃hot-rolled to 2.3 mm plate by 5 passes,finishing-rolled at 950～1000℃.Test results show that the structure and texture along thickness of both hot-rolled plates are inhomogeneous:the subsurface ... 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

利用场发射扫描电镜观察了以MnS为主要抑制剂的普通取向电工钢加工过程中第二相粒子的分布状态,统计了粒子面密度、平均尺寸以及相应的尺寸分布.结果显示,热轧加工造成了大量第二相粒子弥散、细小地析出,同时基体仍保持过饱和状态.冷轧变形会造成第二相粒子的回溶行为,而基体的过饱和状态会减弱回溶现象.中间退火与脱碳退火过程中会同时存在新粒子的形核及已析出粒子的粗化两个过程,而在最终二次再结晶升温阶段则以第二相粒子明显粗化为主. The distribution of second phase particles in conventional grain-oriented electrical steels during manufacturing processes with MnS as inhibitors was observed by field emission scanning electron microscopy,while the areal particle density,the average particle size and the corresponding size distribution were statistically determined.It is indicated that hot rolling leads to dispersive precipitation of a large amount of fine second phase particles and the matrix keeps a supersaturated state furth... 

目前高磁感冷轧硅钢生产过程中，采用经验方法确定的乳化液流量设定值往往会造成硅钢产品的磁感性能达不到预期目标，针对此情况，基于轧机轧制机理研究了的乳化液流量数学模型，确定了乳化液流量设定值。实践表明，使用该数学模型输出的乳化液流量设定值，可提高轧制过程中乳化液流量控制精度，从而提高高磁感冷轧硅钢的轧制性能。 In view of the current production process of high magnetically inductive cold-rolled silicon steel, the mathematical model of emulsified fluid flow based on mill rolling mechanism is studied in view of the situation in which the magnetic sensing performance of silicon steel products is often not up to the expected target by using empirical method to determine the emulsified liquid flow setting. Practice shows that the emulsified fluid flow setting value output from this mathematical model improv... 

介绍了普通取向硅钢(CGO)和高磁感取向硅钢(Hi-B)铸坯高温加热两次冷轧、一次冷轧和铸坯低温加热两次冷轧、一次冷轧法4种成熟生产工艺的主要技术参数,取向硅钢理论研究(Goss晶核和抑制剂)和生产技术现状。取向钢的发展趋势为:提高(110)[001]晶粒取向度,降低取向硅钢铁损,发展铸坯低温加热(≤1 300℃)和薄板坯连铸连轧流程生产取向硅钢工艺。 Main technology parameters of four developed process:cast bloom higher temperature heating-double cold rolling or single cold rolling,lower temperature heating-double cold rolling or single rolling process for production of common grain oriented silicon steel(CGO) and high magnetic induction grain oriented silicon steel(Hi-B),theory research on grain oriented steel(Goss nucleus and inhibitor) and present situation of process are summarized in this paper.The development trend of grain oriented si... 

介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including...