硅钢资料

本发明公开了一种半无机硅钢片漆及其制备方法和应用，其包括：聚酰胺酰亚胺清乳液、二氧化钛、二氧化硅、硫酸钡和氨基树脂，聚酰胺酰亚胺清乳液的制备：在保护气体保护下和回流状态下，使偏苯三酸酐与特定的复合双端氨基化合物在第一有机溶剂中反应，加入磷酸三丁酯、三乙胺，反应；向外蒸出第一有机溶剂，加入第二有机溶剂，加入直链烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠和脂肪醇聚氧乙烯醚，混合，在搅拌条件下滴加水，滴加完之后，加入双马来酰亚胺进行封端，制成；该半无机硅钢片漆通过将各组分混合超声分散而制成，可在硅钢片中作为覆盖漆应用，且不仅可以采用水作为主体溶剂，环保型好，而且还兼具耐高温、高粘结强度、电气性能强等优点。

本发明公开了一种取向硅钢实验室常化工艺方法，采用两段式常化工艺，可以模拟现场常化生产，为现场批量生产提供有效的工艺参考，缩短现场调试工艺次数和废品率、次品率，降低制造成本。

通过热力学计算,分析了实验钢中主要析出物析出的可能性。结果表明:在液相和固液两相区中,AlN和MnS均不能析出;在奥氏体区,AlN和MnS具备热力学析出条件,平衡析出温度分别为1547、1582 K。成品退火板中的析出物主要为AlN和MnS。扫描电镜下观察到的AlN形貌多为长条状,MnS形貌多为棒状或近似球形。这两种析出物占了析出物总量的85%以上,尺寸集中分布在400~800nm;复合析出物主要是(Al2O3+MnS)和(AlN+MnS),形貌不规则,尺寸集中在0.7~1.5μm;透射电镜下观察到了少量100nm以下独立的AlN析出。 According to thermodynamic calculation, the precipitation probability of precipitates was analyzed, AlN and MnS can not precipitate in liquid phase area and solid-liquid two-phase area. In austenite area, both the AlN and MnS have precipitation condition in thermodynamics and precipitates at 1547 K and 1582 K, respectively. The precipitates in annealing plate are mainly AlN and MnS. The shape of AlN is mostly strip, and MnS is stick or near sphericity. They accounted for over 85% of the total qu... 

介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including... 

【摘要】 <正>据武钢股份公司提供的消息,武钢将与...

本文介绍了无取向硅钢C6涂液的性能,研究了配水量、固化程度和涂层厚度等因素对无取向硅钢C6涂层性能的影响。结果表明,随着配水量的增加,完全固化所需的时间增加,涂液固体含量降低,涂层厚度减小;随着固化程度的提高,涂层硬度先增大然后趋于恒定,而柔韧性逐渐变差,在过固化后急剧恶化;涂层厚度对涂层的表面外观、附着性和绝缘层间电阻均有显著影响。 Based on the introduction about the performance of C6 varnish for non-oriented silicon steel sheets,effects of water amount,curing degree and coating thickness are discussed. Results show that with the increase of water amount,the time required to cure completely extends,and both the solid content of C6 varnish and the coating thickness decrease. As the curing degree increases,the hardness of the coating increases first and then tends to be constant,however the flexibility degenerates,especially... 

目前高磁感冷轧硅钢生产过程中，采用经验方法确定的乳化液流量设定值往往会造成硅钢产品的磁感性能达不到预期目标，针对此情况，基于轧机轧制机理研究了的乳化液流量数学模型，确定了乳化液流量设定值。实践表明，使用该数学模型输出的乳化液流量设定值，可提高轧制过程中乳化液流量控制精度，从而提高高磁感冷轧硅钢的轧制性能。 In view of the current production process of high magnetically inductive cold-rolled silicon steel, the mathematical model of emulsified fluid flow based on mill rolling mechanism is studied in view of the situation in which the magnetic sensing performance of silicon steel products is often not up to the expected target by using empirical method to determine the emulsified liquid flow setting. Practice shows that the emulsified fluid flow setting value output from this mathematical model improv... 

本实用新型公开了E字型硅钢片的级进模冲压装置，属于冲压模具设备领域，所述下模具包括与冲孔凸模、冲方孔凸模、切断凸模分别对应且相适配的冲孔凹模、冲方孔凹模、切断凹模，所述上模具上设有对条料板进行输送的导料板，所述冲孔凸模、冲孔凹模均设有两对并且并排设置，且每对冲孔凸模、冲孔凹模均设有两个，每个所述冲孔凸模、冲方孔凸模、切断凸模的顶端均用微米级间隙固定安装于上模具上，所述冲孔凹模、冲方孔凹模、切断凹模的底端均用微米级间隙固定安装在下模具上。本实用新型中各个凸、凹模分别采用硬质合金拼块、镶块式的结构并用微米级间隙固定安装在上、下模具上，这样不仅可节省材料的费用，同时还便于人们后期对模具的维修和使用。

本发明属于金属材料加工技术领域，具体涉及取向硅钢罩式炉高温退火低保温阶段节能工艺，包括：1)将涂镁取向硅钢卷装入密闭的罩式炉中，并向罩式炉内通入氮气将炉内氧气充分排出，使炉内氧含量浓度≤300PPm；2)通电升温并将氮气转换为10m3/h氮气与氨分解气的混合气体，升温2h将温度升温至500‑600℃后，恒温13h；3)将温度氮气与氨分解气的混合气体转换为12m3/h氨分解气，并升温2h将温度升至650℃恒温15h，使内部气体露点小于‑10℃；本发明提供退火工艺，钢卷在高温下不被水蒸汽氧化，消除钢带表面露金、发红、发黑、水印、色泽不均、导通缺陷，降低钢带铁损、提高磁感、降低生产成本。此外，本发明进一步减少退火过程中氨分解气的用量，具有极高的工业应用价值。

研究表明,硅钢中的夹杂物对成品带钢的磁性能有显著影响。为研究冶炼过程硅钢中的夹杂物遗传变化,进而提出更有效的控制措施加以去除,本文结合典型的无取向硅钢生产炉次,采用非水溶液电解提取+扫描电镜观察方法分析冶炼过程中上述炉次典型试样的夹杂物。结果表明:转炉冶炼结束、RH精炼开始时,钢的氧化物夹杂总量最大,约为0.23%;RH精炼过程中,氧化物夹杂总量不断降低,并在脱碳结束时达到最低,约为0.02%;连铸过程中,氧化物夹杂总量仍有不断降低趋势,但夹杂物的平均尺寸变化不大。本试验条件下,中间包试样的夹杂物数量约为1.59×104个/mm3。 As we all know, the non-metallic inclusion effects magnetic properties of silicon steel sheets obviously. The article aims to study the heredity of non-metallic inclusion in non-oriented silicon steels during the steel making process, and then provides a more effective controlling measure to remove the inclusions. Based on the typical non-oriented silicon steel charges, the non-aqueous solution extraction and SEM observation were adopted to analyze the non-metallic inclusions. Results show that,... 

本实用新型公开了一种硅钢片生产用冲压模具，包括承重板，所述承重板的上表面分别设置有缓冲机构和安装架，缓冲机构包括固定连接在承重板上表面的缓冲座，缓冲座的上表面开设有升降腔，升降腔的内部竖向滑动连接有冲压母模，冲压母模上边沿的下表面固定连接有缓冲弹簧，缓冲弹簧的底端与升降腔的内底壁固定连接，冲压母模的内底壁设置有气压顶出机构。该硅钢片生产用冲压模具，在合模过程中，冲压母模能够在缓冲弹簧的作用下沿升降腔缓慢下降，对合模的冲击力进行缓冲，从而达到对整体结构进行保护的目的，在冲压母模停止下降后，合模操作完成，随后液压杆带动冲压公模上升，冲压母模在缓冲弹簧的弹力作用下复位，便于下次冲压加工操作的进行。

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re...