钢厂
硅钢水溶性极厚绝缘涂层的热老化行为研究
对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed...
CN202123334411.9一种变压器铁芯硅钢片的收片装置
本实用新型公开了一种变压器铁芯硅钢片的收片装置,包括固定平台、硅钢片出料机构、压片机构、支撑平台和升降调节机构,所述固定平台设置在硅钢片出料机构的出料端下方,所述压片机构对应于硅钢片出料机构的出料口设置在硅钢片出料机构的上方,从所述硅钢片出料机构传送出的硅钢片通过压片机构压覆在固定平台上;所述固定平台上设置有升降调节机构,所述升降调节机构的升降端设置有支撑平台,所述支撑平台相对于固定平台在竖向方向上位移调节设置,能够对硅钢片叠放平面进行高度调节,保证出料高度的一致性,使得出料规整性较好。
CN202122836410.8一种成品取向硅钢片加工用的卷绕装置
本实用新型公开了一种成品取向硅钢片加工用的卷绕装置,包括机箱和卷绕机,所述机箱的下表面固定安装有底座,所述机箱的一侧表面靠近上方固定安装有控制箱,所述机箱的两侧表面靠近前方固定安装有伸缩机,所述机箱的前端面固定安装有挡板,所述挡板的前端设有卷绕机,所述底座的上表面且位于卷绕机的下方固定安装有定位筒,所述定位筒的内部活动安装有托杆。本实用新型所述的一种成品取向硅钢片加工用的卷绕装置,可以有效的控制卷绕机卷绕取向硅钢片的厚度,从而保证每次卷绕取向硅钢片的厚度都相同,利用伸缩机可以对不同宽度的取向硅钢片进行边缘位置的夹紧,并且可以控制卷绕板与卷绕机之间的间距,从而控制卷绕后取向硅钢片的内径大小。
电工钢显微结构和疲劳性能的研究
研究了电工钢SXRC的显微结构和疲劳性能,并与DP钢进行了比较。结果表明,退火温度低温化能够有效的抑制电工钢的再结晶。该钢在固溶铌的作用下,能够在保证电机磁性的同时具有一定的强度。与DP钢相比,SXRC钢的抗疲劳性能更好。 The microstructures and fatigue properties of the electrical steel SXRC we re investigated, and the properties were also compared with the steel DP. The results show that the recrystallization of the electrical steel can be suppressed at lower annealing temperature. The steel presents favorable motor magnetic and also a compatible strength with the help of solid-solution Nb. Compared with the steel DP, the fatigue resistance of the steel SXRC is preferable.
CN202110203335.3硅钢含铬涂层废液处理过程中六价铬浓度在线监控方法
本发明公开了一种硅钢含铬涂层废液处理过程中六价铬浓度在线监控方法,提出一种准确检测废液中六价铬含量的方法和检测时间的确定,实现了含铬废水原液中六价铬含量预测和焦亚硫酸溶液添加量的确定及六价铬在线检测预处理系统的启动时间的确定,确保处理装置安全高效运行。在酸化还原罐上安装氧化还原电位检测仪,实时检测含铬废液在整个处理过程中ORP的变化,推测含铬涂层废液中六价铬还原情况,初步判断还原过程的终点,为在线六价铬自动检测仪的启动提供依据,最终实现解毒后废液六价铬的含量低于0.05mg/L,达到六价铬含量超低处理的要求。
取向硅钢连续退火的工艺与设计
分析了影响脱碳效果和结晶行为的各种要素及其相互制约关系,提出了Hi-B连续退火工艺曲线,总结得出快速加热及合理稳态气氛是实现工艺制度的关键。结合实际工程,介绍了在连续退火炉设计中快速加热和气氛设计的考虑方法,并指出随着Hi-B产品的发展,如何改进这些方法将是连退工程研发的方向之一。 The factors which affect decarbonization and crystallization and the mutual restriction between them were analyzed.A complete continuous annealing process for Hi-B was put forward.As a result,the rapid heating and the proper steady atmosphere were two important factors.According to an actual project,the consider methods for designing rapid heating and proper steady atmosphere were introduced,and it is pointed that with the development of Hi-B technique,how to improve these techniques would be on...
取向硅钢用特种氧化镁的应用研究
采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar...
压下率对6.5%Si电工钢温轧板织构的影响规律
6.5%Si电工钢是一种优异的软磁材料,织构对其磁性能影响很大。利用温轧工艺对6.5%Si电工钢热轧板进行不同压下率轧制,研究了温轧板织构随压下率的变化规律。实验结果显示,随着压下率的增大,{100}〈110〉、{110}〈100〉和γ纤维织构在薄板表层中的强度先增强后减弱,当压下率达到75%时,沿板厚方向形成3个组织区域:表层细晶粒区({110}〈100〉取向为主)、过渡层({111}〈110〉和{111}〈112〉变形晶粒区)和中心层(以拉长的γ纤维织构和{100}〈110〉取向晶粒为主),这种组织和织构不均性对后期织构的发展有重大影响。 6.5wt% Si electric steel has excellent soft magnetic properties,on which texture play important role.In this experiment,warm rolling technique was employed to investigate the effect of rolling reduction on texture.It was found that the density of {100}〈110〉,{110}〈100〉 and γ-fiber textures first increased and then decreased with increasing of the rolling reduction.At 75% reduction,the microstructure along the thickness of the sheet formed three zones,containing surface layer with {110}〈100〉 orien...
抑制剂成分对取向硅钢夹杂物析出及磁性能的影响
利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O...
基于GTN损伤模型对含边部缺陷硅钢薄板冷轧时边裂的预测
采用拉伸试验和显微组织观测的方法确定了GTN损伤模型中的9个损伤参数,运用GTN损伤模型对冷轧硅钢薄板边部缺陷的扩展及边裂的产生进行了有限元模拟,并与预置缺口的钢板轧制试验进行对比。结果表明:轧制过程中边部缺陷是造成钢板边部裂纹萌生和扩展的一个重要原因,GTN损伤模型可用来预测含边部缺陷硅钢薄板在冷轧过程中边裂的产生;预测结果与试验结果基本一致。 The crack initiation and propagation of silicon steel strip with edge defect during cold rolling process was studied by using GTN damage model in this paper.Nine damage parameters in GTN model were identified by tensile testing and microstructure observing,and then the FE simulation of edge defect evolution of silicon steel strip during rolling process was conducted on the base of GTN damage model,and then the results were compared with rolling experimental results.The results show that the edge...
无取向电工钢退火工艺研究现状
综述了退火温度、时间对无取向电工钢磁性的影响。退火温度主要影响无取向电工钢不同织构的占有率,退火时间主要影响晶粒尺寸的大小,晶粒尺寸的变化对织构的形成也有一定的影响。磁感最高点出现在纤维组织完全消失,(111)面织构组分较弱的组织状态。铁损的降低主要依赖于磁滞损耗的降低,织构的影响不大。 The effects of annealing temperature and time on the non-oriented electrical steel magnetic properties were reviewed.Annealing temperature and time mainly affects the different textures share and the grain sizes of non-oriented electrical steel respectively.Changes of the grain sizes also have a certain effect on textures formation.The highest point of the magnetic induction value in the fibrous tissue completely disappears and{111} plane texture has a lower state of the component content.Iron l...
CN202011605469.X一种不含铬取向电磁钢板用涂料、其制备方法及带涂层的不含铬取向电磁钢板的制备方法
一种不含铬取向电磁钢板用涂料、其制备方法及带涂层的不含铬取向电磁钢板的制备方法,属于取向电磁钢板技术领域。所述涂料按质量份配比组成如下:100份磷酸盐、60~120份二氧化硅溶胶、5~50份氧化锡溶胶、2~40份硼酸和0.5~10份二氧化硅粉体。本发明所述制备方法环境友好、能够满足规模化生产要求,制备的涂料不含铬、具有良好的稳定性和涂敷性,并且本发明所述涂料能够使取向电磁钢板表面涂层具有良好的耐吸湿性、耐腐蚀性、耐热性、张力效果和抗粘片性。

