硅钢资料

以试验室模拟CSP工艺生产的Fe-3Si热轧钢带为研究对象,采用正交试验及方差分析的方法,研究了取向硅钢初次再结晶退火工艺对高温退火后获得锋锐的高斯织构的影响。结果表明:取向硅钢两段式初次再结晶脱碳退火工艺参数加热段保温时间及加热温度是高温退火后获得锋锐高斯织构的主要影响因素,其可信度分别在90%和85%以上;在本试验条件下,通过正交试验获得的最佳退火工艺为:冷硬板经600℃保温3 min和850℃保温6 min。 Fe-3Si hot rolled strip was produced by simulating CSP technology in the laboratory.Orthogonal experiment and analysis of variance were carried out to investigate the influence of primary recrystallization on the sharp Goss texture of the oriented silicon steel.The results show that holding time of the heating section and the heating temperature for a sharp Goss texture of the samples annealed has important implications in this experiment conditions,the two-step decarburization annealing process... 

试验了通过NaCl-KCl-NaF-SiO₂熔盐在电流密度50 mA/cm²、电沉积脉冲电流正反向比9:1和750⁸50℃60min电沉积下阴极（/mm）20×20×0.5的1.6Si无取向冷轧硅钢片断面层硅的分布,并通过计算得出Si的扩散系数。结果表明,电沉积温度由750℃提高至850℃时,试样中Si含量增加,扩散的深度由18μm提高到40μm;电沉积温度与Si在钢中的扩散系数近似符合Arrhenius指数关系。 The distribution of silicon at cross section of cathode（/mm） 20 × 20 × 0.5 sheet of 1.6Si non-oriented cold rolled silicon steel after electro-deposit treatment by NaCl-KCl-NaF-SiO₂ molten salt with current intensity 50 mA/cm²,electro-deposit pulse current positive-negative ratio 9:1 at 750 850 ℃ for 60 min has been tested and the diffusion coefficient of Si is obtained by calculation.Results show that with increasing electro-deposit temperature from 750 ℃ to 85... 

分析总结退火工艺各参数对冷轧无取向硅钢磁性能的影响,结合设计和生产实践经验介绍退火工艺中各参数的实际生产取值,并针对现生产工艺过程中出现的典型问题提出解决办法。 It is analyzed and summarized the great influences on magnetism of cold rolled non-oriented silicon steel affected by various annealing process data in this article.The relevant settled ways is raised.According to the actual value presetting ways for various annealing process data based on design and production,as well as typical problems occurred during production. 

薄带连铸流程下取向硅钢粗大λ晶粒(〈100〉//ND,normal direction)的“遗传”会导致磁性能恶化.为解决这一问题，针对取向硅钢的热轧孪生行为开展研究，结果表明：凝固组织粗大的取向硅钢在650℃热轧时可产生大量{112}〈111〉形变孪晶，这与具有高层错能的硅钢在较高温度下难以孪生变形的传统认知不同.热轧过程中复杂的应力状态降低了变形孪晶的取向依赖性，由于具有更高的储存能，孪晶界/孪晶界及孪晶界/晶界交叉点成为再结晶形核的优先位置，大大提高了常化过程中的再结晶率，受沿孪晶界应变分布及孪晶间距离的限制，沿孪晶界形核的再结晶晶粒通常呈“饼状”,最终形成以细小且取向漫散的再结晶晶粒为主的常化组织，消除了初始凝固组织中有害的粗大λ晶粒. In strip casting grain-oriented silicon steels, the inheritance of coarse λ grains(〈100〉//ND, normal direction) can deteriorate their magnetic properties. To solve the problem, twinning behaviors in strip casting grain-oriented silicon steels during hot rolling were investigated in this work. It is found that after rolling at 650 ℃, a number of {112}〈111〉deformation twins are formed in the coarse solidification microstructure of the steels, in contrast to the well-accepted view that it is diffic... 

对无取向硅钢炼钢全流程钢液增钛的原因进行了分析,认为铁水钛含量、转炉出钢温度、转炉下渣量、精炼渣TiO₂含量、钢水罐及RH浸入管混钢种生产是影响钢液增钛的主要原因。通过采取低钛铁水冶炼,减少转炉下渣量,提高出钢温度,添加白灰改质精炼渣等措施,均能够降低钢液中的钛含量。 After analyzing the causes leading to increased content of titanium in molten nonoriented silicon steel during whole steelmaking process, it was concluded that such factors as content of titanium in hot metal, tapping temperature from converter, quantity of roughing slag entered into the ladle from converter, content of TiO₂ in refining slag, molten steel ladle car,carrying out the steelmaking of different steel grades by the same ladle and same RH immersion tube were the main causes ... 

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d... 

通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination... 

以不断增长的薄板坯流程为背景,与传统流程对比分析了薄板坯流程无取向电工钢热轧晶粒组织特征;以50W800和50W1300钢为典型实例,探讨了两种流程下成品板晶粒组织、织构、磁性能及其磁时效行为的基体差异和相关原理。研究表明,薄板坯流程热轧板组织较粗大,有利于在成品板中获得粗大的晶粒和有利的织构,从而得到较低的铁损和较高的磁感。然而,薄板坯流程会造成第二相粒子的细小弥散分布与不充分析出,容易因磁时效而使磁性能恶化。 Based on the rapid development of compact strip production(CSP) processing,the characteristics of hot band grain structure produced by CSP processing were analyzed in comparison with those of conventional technology.The basic differences in grain size,texture,magnetic properties and the magnetic aging behaviors of the final sheet products produced by the two processing technologies and the corresponding principles were discussed,while steel 50W800 and 50W1300 were taken as examples.It is indicat... 

【摘要】 <正>含6.5%Si的电工钢是软磁特性最佳的电...

就冷轧硅钢废水处理生产中面临的主要问题进行分析,从技术角度及运行管理角度提出工艺优化升级改进措施及应对策略;同时从后续深度处理,逐步实现零排放目标的角度进行探讨,为冷轧硅钢废水减量化、出路乃至废水零排放提供一些思路。 The main problems in the wastewater treatment process of cold-rolled silicon steel lines are analyzed and process upgrading measures and optimization strategy are put forward from both technical and management views.At the same time,downstream deep treatment to gradually achieve the target of zero discharge is discussed,to provide some ideas for reduction or even zero discharge of wastewater from cold-rolled silicon steel lines. 

利用OM、TEM与EDS技术,对Fe-3.2%Si低温取向硅钢热轧板进行不同常化冷却工艺处理后的显微组织、析出相及最终产品的磁性能进行分析,并与热轧板的组织和析出相进行对比。结果表明,常化板较热轧板的表层组织均匀,基体中再结晶比例增加,带状组织变窄;常化板中析出物的数量明显比热轧板的多,析出物主要有AlN、MnS及复合析出的(Cu,Mn)S等。在常化温度1120℃、保温3 min的条件下,采用二段式冷却较空冷、淬沸水、淬常温水的冷却工艺,常化板表层显微组织更均匀,沿板厚方向的显微组织的不均匀性显著,取向硅钢的磁性能最高;常化后采用二段式冷却工艺析出的细小析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利。 Microstructure, precipitate and magnetic characteristic of final products with different normalizing cooling processes for Fe-3.2%Si low-temperature hot-rolled grain-oriented silicon steel were analyzed and compared with the hot-rolled plate by optical microscopy(OM), transmission electron microscopy(TEM), and energy dispersive spectrometry(EDS). The results show that, the surface microstructure is uniform, the proportion of recrystallization in matrix increases, and the banding textures are nar...