钢厂
冷轧工艺对取向硅钢初次再结晶织构的影响
研究了取向硅钢制备过程中常见的两种冷轧工艺,主要研究了一阶段冷轧与两阶段冷轧+中间退火工艺对初次再结晶组织及织构的影响.结果表明:采用两阶段冷轧+中间退火工艺制备以Cu2S为主抑制剂的取向硅钢,其初次再结晶平均晶粒尺寸为18.1μm,高斯晶粒的体积分数为0.6%,迁移性强的重位点阵晶界(Σ5+Σ9)和高能晶界(20°~45°取向偏差角)所占比例分别为1.8%和50.4%.与一阶段冷轧工艺相比,其初次再结晶晶粒较细,且高斯晶核与特征晶界所占的比例较高,有利于高斯晶粒发生二次再结晶. Two common cold-rolling processes of grain oriented silicon steel and the effects of the single stage cold rolling and tw o-stage cold rolling w ith intermediate annealing processes on the primary recrystallization microstructure and texture w ere investigated. The results revealed that for the grain oriented silicon steel prepared under the tw o-stage cold rolling process w ith intermediate annealing w ith Cu 2 S as the main inhibitor,the average grain size of the primary recrystallization micr...
普通冷轧取向硅钢中间完全脱碳退火工艺的确定
为了确定普通冷轧取向硅钢最优的中间完全脱碳退火工艺,在其一次冷轧后进行5种不同工艺的脱碳退火处理,借助扫描电镜及电子背散射衍射技术研究了不同工艺脱碳退火后的组织、织构和脱碳效果。结果表明:经5种工艺脱碳退火处理后,初次再结晶的平均晶粒尺寸均约为19μm,且不随退火温度和时间的变化而变化;经840℃×10min工艺退火后的晶粒最均匀,高斯织构位向更准确,高斯织构面积分数最多,为3.1%,可将碳脱至0.003 5%。 In order to determine the optimal intermediate complete decarburizing annealing processes for common grain-oriented(CGO)silicon steel,five kinds of intermediate decarburizing annealing processes were conducted,the microstructure,texture and decarbonization after different decarburizing annealing processes were studied by scanning electron microscopy and electro back-scattered diffraction(EBSD)technology.The results show that the average grains sizes of primary recrystallization were about 19μm a...
电感耦合等离子体质谱法测定硅钢中痕量铝钼钒钛铌
研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c...
硅钢高温氧化铁皮的显微结构表征
利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy...
无取向硅钢冶炼过程中的夹杂物遗传变化
研究表明,硅钢中的夹杂物对成品带钢的磁性能有显著影响。为研究冶炼过程硅钢中的夹杂物遗传变化,进而提出更有效的控制措施加以去除,本文结合典型的无取向硅钢生产炉次,采用非水溶液电解提取+扫描电镜观察方法分析冶炼过程中上述炉次典型试样的夹杂物。结果表明:转炉冶炼结束、RH精炼开始时,钢的氧化物夹杂总量最大,约为0.23%;RH精炼过程中,氧化物夹杂总量不断降低,并在脱碳结束时达到最低,约为0.02%;连铸过程中,氧化物夹杂总量仍有不断降低趋势,但夹杂物的平均尺寸变化不大。本试验条件下,中间包试样的夹杂物数量约为1.59×104个/mm3。 As we all know, the non-metallic inclusion effects magnetic properties of silicon steel sheets obviously. The article aims to study the heredity of non-metallic inclusion in non-oriented silicon steels during the steel making process, and then provides a more effective controlling measure to remove the inclusions. Based on the typical non-oriented silicon steel charges, the non-aqueous solution extraction and SEM observation were adopted to analyze the non-metallic inclusions. Results show that,...
我国冷轧无取向硅钢涂层专利技术分析
对1990~2010年在我国申请的冷轧无取向硅钢涂层的专利数量、专利技术领域分布进行了统计,对典型涂层专利技术进行了分析,探讨了无取向硅钢涂层的发展趋势。统计分析结果表明,目前无取向硅钢涂层典型的专利技术主要有自粘结涂层、无铬含稀土元素涂层、含钼酸盐环保涂层及采用有机-无机纳米杂化材料为主成膜物形成的涂层等。无取向硅钢涂层发展的趋势主要是无铬环保的半无机、半有机型涂层。 The patent quantity of cold-rolled non-oriented silicon steel coating and distribution of technology fields applied in China in 1990-2010 were summarized.The analysis results indicate that typical patent technologies include self-adhesion coating,chromium-free and with rare earth element coating,environment-friendly and with molybdate coating,coatings with organic-inorganic hybrid materials as main forming agent and so on.The main development trends of coatings on silicon steel are among semi-in...
锰含量对无取向电工钢组织性能的影响
研究了锰含量对w(Si)=1.8%Si无取向电工钢组织和性能的影响。结果表明,钢中锰含量从0.3%增加到1.2%时,由于α_γ相变的产生,铸坯低倍组织、热轧板金相组织及成品织构等均发生了不同程度的变化,对成品表面质量及磁性能产生了明显的影响。 The effects of manganese content on structure and properties of w(Si)=1.8% non-oriented electrical steels have been studied.Results show that with increasing manganese content to 1.2% from 0.3%,macrostructure of continuous casting slab,hot rolled band metallurgical structure and finished product texture vary in some extent because of the occurrence of α-γ phase transformation,the surface quality and magnetic properties of finished product are affected greatly.
低温板坯加热取向硅钢形变和初次再结晶织构的演变规律
采用取向分布函数和取向线分析方法对低温板坯加热取向硅钢从热轧到初次再结晶工艺阶段的织构进行了研究。研究表明:一次冷轧后各层的织构组分与热轧板各层面的织构组分存在着继承关系,次表层存在很强的{001}<110>织构,中心层的织构和热轧板的中心层相似,存在强的{001}<110>和{112}<110>织构;中间退火后发生再结晶,各织构组分的强度有所减弱,Goss织构组分再次出现;二次冷轧后沿厚度方向上的织构不均匀性不明显,{111}<112>织构强度最高,几乎是其他织构组分的1倍,{001}<110>织构大幅降低;初次再结晶后织构沿厚度方向没有明显的不均匀性,{111}<110>为最强的织构组分,并且具有一定强度的Goss位向。 The texture from the first cold rolling to the primary recrystallization of low temperature slab reheating grain-oriented electrical steel were researched by orientation distribution function and orientation distribution intensity technique.The results show that after the first stage of cold rolling,there is a strong {001}<110> texture in the subsurface and the texture in center layer is very similar to the center layer of hot band which has strong {001}<110> and {112}<110> tex...
