硅钢资料

利用OM、EBSD等手段研究了热轧板两段式正火时在700℃保温不同时间(0、10、30、60 min)对含Sb冷轧无取向电工钢磁性能的影响。结果表明,700℃保温10 min处理的样品铁损最小,磁感最高。对成品板的组织分析结果表明,试样的晶粒尺寸随700℃保温时间的延长先增大后减小,保温10 min时晶粒尺寸达到最大;分析成品试样织构发现,有利织构组分随700℃保温时间的延长先增加后减少,保温10 min时有利织构组分所占百分比最高。因此,含Sb冷轧无取向电工钢两段式正火时在700℃保温10 min时磁性能最好。 Effect of two-stage normalization on magnetic property of non-oriented electrical steel containing antimony was investigated by using optical microscope(OM) and electron back-scattered diffraction technology(EBSD).The experimental results show that the iron loss and magnetic permeability of the specimen insulated at 700 ℃ for 10 min are lowest and highest respectively.The grain size of the finish specimens increases first and then decreases with the increase of holding time.Similarly,the advanta... 

无取向硅钢特别是中牌号以上的无取向硅钢,随着含硅量的提高,常温下塑性较差,冷轧过程中轧制力明显提高,如果存在原料质量问题,极易发生断带事故,影响硅钢冷轧过程的成材率和生产效率。通过优化冷轧工艺参数,可提高冷轧稳定性。生产中通过合理分配冷轧各道次压下量和轧制速度,保证了轧制过程的稳定,很大程度减少了冷轧断带事故的发生。 Non-oriented silicon steel, especially in the low and middle grade, with the increase of silicon content, plasticity is poor at room temperature, rolling force in cold rolling process significantly improved .If there is the quality defect of raw materials , easily sheet is rolling off. Affect finished product rate and production efficiency in process of cold-rolled silicon steel. Through optimization of cold rolled process parameter , improve the stability of cold-rolling process. Through reason... 

借助电子背散射(EBSD)技术对AlN为主抑制剂的Hi-B取向硅钢常化工艺的中间冷却制度进行了研究。结果表明:常化后试样均发生了完全再结晶,在60℃/s冷速下组织最均匀;在合适的冷却制度下常化板表层保留了强的Goss织构,它深入到1/4厚度处,并且形成对Goss织构有利的强{554}<225>织构。 The intermediate cooling system of Hi-B oriented silicon steel with AlN main inhibitor in normalizing process was studied by means of electron back diffraction(EBSD) technique. The results show that:the specimens after normalizing are fully recrystallization, and the microstructure is most uniform under the intermediate cooling rate of 60℃/s; under suitable cooling system, normalized plate surface retains strong Goss texture, it penetrates into the 1/4 thickness of the plate and forming strong {... 

聚焦无取向硅钢产品标准,从电磁性能、表面性能、机械性能以及尺寸公差与边部质量等维度对国际标准IEC、EN、JIS、ASTM以及国标GB进行了分析研究。分析得出,各类标准在电磁性能方面要求基本一致;ASTM标准的机械性能要求有别于其他几个标准。 In this paper,non-oriented silicon steel standards of EN,JIS,GB and ASTM were compared and analyzed. It is showed that,all types of standards in electromagnetic performance requirements are basically the same. Surface properties in ASTM standard are expressed in the most detailed. The mechanical properties requirements of the standards,except for ASTM,are basically the same. 

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re... 

通过对35W300高牌号0.35 mm冷轧无取向电工钢卷(/%:0.002C、2.71Si、0.22Mn、0.015P、0.003S、0.0020N、0.55Als)头、中、尾组织、织构及对应的磁性能的试验研究,发现因热轧时12 MPa高压水连续冷却造成接触轧辊的钢卷头、中、尾在不同温度下轧制,卷取后钢卷头部处于卷心、温度略高而冷却速度略低于钢卷尾部,致使钢卷纵向组织、织构不同,成品卷头、尾各250 m内磁感逐渐增加,铁损逐渐降低,250 m外至钢卷中部磁性能稳定。通过将热轧辊的冷却方式改为周期冷却和卷取后的层流冷却改为钢卷70 m后开始冷却,至钢卷尾部70 m前停止冷却的方式使得钢卷纵向铁损差异明显减小,磁感差异略有改善。 According to the test research on structure and texture of head,meddle and end of 35W300 high grade 0.35 mm cold rolled non-oriented electrical steel strip coil(/%:0.002C,2.71Si,0.22Mn,0.015P,0.003S,0.002 0 N,0.55Als) and corresponding magnetic properties,It is found that due to 12 MPa high pressure water continuous cooling the roller in hot rolling process led to head,middle and tail of strip rolling at different temperature and after coiling the head of strip coil being in center of coil led t... 

采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e... 

通过金相分析和电子背散射衍射技术研究了一种新型含铜无取向电工钢在950℃退火不同时间(3～180s)空冷后的组织和织构取向的演变。结果表明:该钢在退火3s时的主要织构为α和γ线织构,{100}<110>织构最强;退火20s时织构以<111><112>、{111}<110>、{112}<110>、高斯织构和立方织构为主,随着退火时间的延长,高斯织构和立方织构强度呈减弱趋势;合理控制保温时间有利于提高{100}、{110}面织构的占有率。 Evolution of microstructure and texture oriented of a new non-oriented electrical steel during annealing at 950℃for different times(3-180) s and air cooling was studied by metallography and electron back-scattering diffraction analysis.The results show that after annealing for 3 s most of the texture oriented alongα-fibre andγ-fibre,the intensity of {100}〈110〉was the strongest.{111}〈112〉,{111}〈110〉,{112}〈110〉,Gauss texture and cube texture were the main texture after annealing for 20 s,with the ... 

研究了无取向硅钢钙处理前后夹杂物的行为,重点考察了钙处理前后夹杂物的成分、类型、形貌和尺寸研究的变化情况,为实际生产中无取向硅钢的钙处理提供理论指导。试验发现:钙处理前夹杂物主要以Al2O3、Al2O3-MgO为主,且在夹杂物表面有AlN析出,钙处理后夹杂物以Al2O3-MgO-CaS-CaO系复合夹杂物为主,还含有少量的SiO2或AlN;钙处理前后,夹杂物形貌由多边形或不规则形逐渐向球形或近似球形转变,并且夹杂物尺寸不断增大;钙处理前后,含钙夹杂物的比例发生突变,由10%增大到74.5%,且随着钙处理时间的延长,含钙夹杂物比例下降,表明钙处理使夹杂物变性后易聚集长大并上浮去除。 Behavior of inclusions before and after calcium treatment in non-oriented silicon steel was researched by investigating changes of compositions,types,shapes and sizes of inclusions before and after calcium treatment,for the purpose of providing theoretical guidance for calcium treatment of non-oriented silicon steel in actual situation. Results indicated that Al2O3 and Al2O3-MgO were main types of inclusions before calcium treatment,sometimes AlN maybe precipitate in the outer of inclusions. Al2... 

利用FE-SEM、EDS分析了含不同抑制剂成分的成品取向硅钢中夹杂物的组成和形貌,统计其尺寸及数量分布;结合对磁性能测试的结果,分析了Sn、Cu、Nb和Cr对取向硅钢磁性能影响的机理。结果表明:含Sn的取向硅钢试样中夹杂物主要为块状的微米级Al-Ti-C-N-O复合物,还有少量的球形Al-N-O颗粒和块状Ti-C-N-O颗粒,棒状夹杂物较少;含Cr的取向硅钢试样中夹杂物主要为球形的微米级Al2O3,还有少量Cu-Al-N-O-S复合物,棒状夹杂物和不规则夹杂物均较少;含Cr试样中1~3μm夹杂物的平均尺寸较含Sn试样小,但数量多,而大于3μm夹杂物的平均尺寸较含Sn试样大,但数量很少。磁性能测试结果表明,外场为800A/m和2500A/m时,含Cr试样磁感应强度偏低,铁损值P1.7/50较含Sn试样高,为1.171W/kg。 The composition and morphology of inclusions in the finished grain-oriented silicon steels are analyzed by using FE-SEM and EDS, and the number density and size distribution of the inclusions are counted. The influence mechanism of Sn, Cu, Nb, and Cr on the magnetic properties of the steel is also discussed. Results show that the inclusions composition in the grain-oriented silicon steel samples containing Sn is mainly block Al-Ti-C-N-O, compounding with a few spherical Al-N-O and block Ti-C-N-O... 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

目前随着电工钢用户冲压设备的升级,冲压速度逐步提高,对电工钢产品的硬度和强度指标提出了更高的要求。与普通硬度级别的无取向硅钢相比,高硬度50BW600的Hv硬度提高15~20,达到125以上,同时对电磁性能指标也有较高要求。本钢通过化学成份和热轧及冷轧连退生产工艺的设计,经过小批量生产试验,满足用户要求。通过对工艺的严格控制,在大批量生产过程中,保证了产品的力学性能和电磁性的检验合格率。 Currently with upgrading of stamping equipment of silicon steel user, gradually increasing of stamping speed, propose higher demand for hardness and strength of silicon steel. Compared with conventional 50BW600, high hardness 50BW600 have higher hardness, reach greater than 125Hv. Through design of chemical composition with hot mill and annealing, production test of small quantities, stamping performance meet user request.