硅钢资料

简要介绍了宝钢无取向电工钢的发展历程、产品大纲、电磁性能控制情况,以及高附加值新产品的开发、应用情况。概述了近年来宝钢无取向电工钢生产技术进步,主要包括夹杂物控制技术、连轧机高牌号硅钢制造技术、同板差控制技术、环保涂层开发技术等。 This paper briefly summarizes the development history, product catalogue, and magnetic properties of non-oriented electrical steel sheets at Baosteel, as well as the development and application of high-value-added steel grades. Recent advances in manufacturing electrical steel sheets are also introduced, including technologies for controlling inclusion, producing high-grade steel strips by a tandem rolling mill, and controlling the transverse thickness difference of steel sheets, as well as the ... 

目前高磁感冷轧硅钢生产过程中，采用经验方法确定的乳化液流量设定值往往会造成硅钢产品的磁感性能达不到预期目标，针对此情况，基于轧机轧制机理研究了的乳化液流量数学模型，确定了乳化液流量设定值。实践表明，使用该数学模型输出的乳化液流量设定值，可提高轧制过程中乳化液流量控制精度，从而提高高磁感冷轧硅钢的轧制性能。 In view of the current production process of high magnetically inductive cold-rolled silicon steel, the mathematical model of emulsified fluid flow based on mill rolling mechanism is studied in view of the situation in which the magnetic sensing performance of silicon steel products is often not up to the expected target by using empirical method to determine the emulsified liquid flow setting. Practice shows that the emulsified fluid flow setting value output from this mathematical model improv... 

对取向硅钢熔融态钢液进行处理,对比研究了不同脉冲参数的作用效果。结果表明,电脉冲对钢锭晶粒组织具有明显的细化作用,凝固组织等轴晶比例大幅上升。在脉冲电容、频率、处理时间和电压中,影响等轴晶比例的最显著性因素为脉冲频率;最优正交实验参数为:电容1 200μF,脉冲频率1 Hz,处理时间5 s,脉冲电压800 V;随着输入能量的增大,等轴晶率先增大后减小,脉冲输入能量为某值时,等轴晶率最大,通过经典形核理论和热力学对这一现象进行了解释。 Research on the influence of the electric pulse on the solidification structure of oriented silicon steel was preformed.Electric pulses in different parameters were applied to molten steel and results were compared.The result shows that solidification structure of oriented silicon steel can be improved by the electric pulse,and the equiaxed crystal ratio increases obviously.Among the four parameter factors of electric capacity,frequency,applied time and voltage,the most effective factor is frequ... 

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

传统轧制法制备6.5wt.%高硅钢过程中温轧工艺具有显著不同于3 wt.%Si的电工钢的特点及组织织构特征,是开发新型基于织构优化的高硅钢的关键环节。采用EBSD技术对通过热轧、温轧、冷轧及退火工艺制备0.3mm厚的6.5wt.%Si电工钢板的组织和织构进行分析,重点研究温轧过程中的中间退火和大、小压下率组合以控制织构。结果表明,在热轧退火板是部分再结晶组织的情况下,一次性温轧或先小形变量、中间退火后再大形变量的工艺可得到更多的Goss晶粒;经过最终退火后Goss取向会发生偏转,形成部分黄铜取向,而{111}〈112〉取向的晶粒内形核生成近Goss取向的再结晶晶粒;大压下量轧制是最终组织中{111}取向晶粒较多的主要原因。 Warm rolling,a key process of developing new type high-Si electrical steel based on texture optimization,has significant different characteristics from 3wt% Si steel in conventional preparing process. 0. 3mm thickness 6. 5wt. % Si steel,obtained by a series of processes including hot and warm rolling,intermediate annealing and then cold rolling,was analyzed from microstructure and texture by EBSD,which are utilized mainly for investigating the intermediate annealing process and the combination o... 

研究了退火温度和退火时间对电沉积硅钢试样中的断面层组织、硅在试样中的分布情况、织构分布和磁性能的影响。结果表明:退火温度为1000℃、退火时间为210 min时得到的试样晶粒分布均匀、硅在试样中分布均匀、硅平均浓度为6.3715%(接近6.5%)。试样的织构分析及磁性能检测的结果表明,在较高温度下延长退火时间可增加{100}和{110}面织构,降低铁损,所得试样的磁性能较为良好。 The effect of annealing temperature and time on the microstructure, distribution of silicon,texture and magnetism of the high silicon steel prepared by electrodeposition was investigated. The results showed that after annealing at 1000℃ for 210 min, the mean grain size of steel was about 190 μm with a uniform grain size distribution, and the silicon is also uniformly distributed on the entire cross section with an average Si concentration 6.3715%(close to 6.5%); With the increasing annealing tim... 

试验研究了球刻痕法对高磁感取向硅钢的铁损、矫顽力、相对磁导率、巴克豪森噪声等磁学性能的影响.研究结果表明:经过球刻痕处理后,高磁感取向硅钢的铁损明显降低,矫顽力下降,8 mm球刻痕过后铁损值与矫顽力分别下降16.2%和14.7%,且铁损和矫顽力均随刻痕间距降低而减少.刻痕后的高磁感取向硅钢磁导率在高磁感应强度下明显上升,刻痕后巴克豪森噪声值明显降低,经过对比分析确定8 mm为球刻痕的最佳刻痕间距.从磁畴观察、细化磁畴的原理等方面解释了细化磁畴对高磁感取向硅钢性能的影响原因. The effects of the ball scribing on magnetic properties of high permeability grain-oriented silicon steels,including the iron loss,coercive force,relative permeability,and Barkhausen noise were investigated. The results showed that the iron loss and coercive force of the high permeability grain-oriented silicon steels apparently decreased 16. 2% and 14. 7% respectively after 8 mm ball scribing and they both decreased with the decrease of the scribing spacing at the same magnetic flux density. At... 

通过对3%Si CGO硅钢进行恒变形速率、不同变形温度下的单道次压缩实验,结合Thermal-Calc软件,金相分析,SEM及EBSD技术,研究了取向硅钢热变形过程中组织和微观织构的变化规律。结果表明:实验钢是在双相区变形,变形后组织主要是铁素体和少量的珠光体。随变形温度的升高,晶粒由长条状变为等轴状,尺寸逐渐变大;CGO硅钢在热变形过程中立方{100}<001>取向是较为稳定存在的。随着变形温度的提高,{111}<110>等取向逐渐转向{110}<1 10>取向,且{110}<1 10>取向逐渐变得锋锐。 3% Si CGO silicon steel was studied at constant strain rate and different deformation temperatures by single-pass compression deformation experiments to reveal the evolution of microstructure and texture during thermal deformation in oriented silicon steel,and the Thermal-Calc software,metallurgical,SEM and EBSD technique was used in the experiment. The results show that experimental steel is deformed at the temperatures of two-phase zone. The microstructure of the deformed steel consists of fer... 

两炉次无取向硅钢XG800WR（/%:0.003～0.004C、0.71～0.75Si、0.32～0.33Mn、0.004～0.007S、0.016P）的炼钢流程为铁水预处理（KR）-210 t顶底复吹转炉-钢包吹氩-RH脱碳精炼-230mm×1220 mm板坯连铸。53 t中间包钢水过热度为25～30℃,钢包到中间包采用长水口全程吹氩保护浇铸,中间包至结晶器采用浸入式水口浇铸。结果表明,在RH、中间包、结晶器过程中钢中总氧以及夹杂物数量和尺寸均明显降低;但在钢包到中间包过程T[O]、[N]和钢中夹杂物数量增加,说明长水口浇铸过程存在二次氧化。连铸坯中T[O]、[N]平均他分别为11×10^-6和30×10^-6,显微夹杂物数量平均为4个/mm²。铸坯中的显微夹杂物主要为3～5μm的AlN,同时存在少量的MnS、Al₂O₃·AlN和Al₂O₃·MgO·MnS。 The steelmaking flow sheet for two heats non-oriented silicon steel XG800WR（/%:0.003～0.004C. 0.71～0.75Si,0.32～0.33Mn,0.004～0.007S,0.016P） is hot metal pretreatment（KR）-210 t top and bottom combined blown converter-ladle argon blowing-RH decarburization refining-230 mm×1 220 mm slab casting.The superheating extent of liquid in 53 t tundish is 25～30℃,whole casting is shielded by blowing argon with long nozzle from ladle to tundish and the submerged nozzle is adopted in casting from tundish to mold... 

研究了CSP流程试制50W270高牌号无取向硅钢热轧→常化→冷轧→退火过程中织构的演变.利用电子背散射衍射技术对全流程织构进行测量和分析.发现热轧板织构在厚度方向上存在较大差异,表层主要为铜型、黄铜和高斯织构,1/4层存在微弱的高斯织构和旋转立方织构,中心层以γ纤维织构和旋转立方织构为主,还含有较弱的α纤维织构.与热轧板相比,常化板表层和1/4层织构变化不大,中心层旋转立方织构和α纤维织构增强.冷轧板各层均具有α纤维织构和γ纤维织构.与冷轧板相比,成品板各层中α纤维织构基本消失,还出现了立方织构和高斯织构. This article focuses on texture evolution in 50W270 high-brand non-oriented silicon steel produced by CSP in hot rolling,normalizing,cold rolling,and annealing processes.The texture in the whole process was measured and analyzed by electron back-scatter diffraction.It is found that the texture along the thickness direction in hot-rolled strips changes obviously;there are mainly copper,brass,and Goss textures in the surface layer;the 1/4 layer has weak Goss texture and rotating cube texture;γ-fib... 

综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i... 

结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ...