钢厂
钇元素对6.5%Si无取向硅钢组织、高温拉伸及断裂机制的影响
通过微观组织表征、高温拉伸和断口形貌分析,研究了钇(Y)元素对6.5%Si无取向硅钢组织、高温拉伸及断裂机制的影响。研究结果表明,添加Y元素可以在钢液中形成YS和YP的复合析出。YS和YP可以充当异质形核基底,提高形核率,细化凝固组织。热轧组织不均匀,由表层至芯部分别形成等轴晶、等轴晶/拉长晶和拉长晶的混合组织。退火后,热轧变形组织转变为等轴晶,含Y实验钢的退火组织得到明显细化。500℃时效处理后,含Y实验钢具备较低的有序度,300℃的拉伸断口呈现韧性断裂特征,断后伸长率达到20.2%。相反,无Y实验钢发生脆性断裂,断后伸长率仅为2.1%。研究结果证实,Y元素可以通过组织细化和降低有序度提高6.5%Si无取向硅钢的中温塑性。 The effects of yttrium(Y)on microstructure,elevated-temperature tensile properties and fracture mechanism of 6.5% Si non-oriented electrical steel were investigated by means of microstructure characterization,high-temperature tensile test and fracture analysis.The results showed that the doping of Y introduced composite Y-rich precipitates(YS/YP)in the melt.YS and YP precipitates were qualified for heterogeneous nucleation agents,which thus raised the nucleation rate and refined the solidificati...
微合金元素Sn、Nb、Re对无取向硅钢性能的影响
介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including...
冷轧无取向硅钢横向厚差控制
冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile...
ICP-AES法测定硅钢中铌的不确定度评定
分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained.
无取向硅钢磷酸盐型杂化涂层性能测试
以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in...
二次冷轧压下率对高牌号无取向硅钢组织结构和磁性能的影响
研究二次冷轧压下率对于硅的质量分数为3.0%的无取向硅钢组织结构和磁性能的影响。结果表明:当第二次冷轧压下率从0变化至16.7%时,铁损逐渐增加,磁感逐渐降低。当第二次冷轧压下率大于16.7%时,随压下率的增加,铁损逐渐减小,磁感逐渐增加。当第二次冷轧压下率大于38%时,二次冷轧法所能获得的磁性能明显优于一次冷轧法。 Effect of double cold reduction on magnetic,microstructure and texture of 3.0% Si non-oriented silicon steel sheets was investigated.The results show that the iron loss increases and magnetic induction reduces as the percentage redcution in secondary cold rolling changes from 0 to 16.7%.The core loss can be reduced remarkably,and magnetic induction can get a little benefit if the percentage redcution in double cold reduction is higher 16.7%.In case of higher than 38% of the percentage redcution ...
钒钛对取向硅钢组织、织构和析出物的影响
通过在实验室条件下模拟薄板坯连铸连轧流程,并在以Cu2S为主抑制剂制造普通取向硅钢(CGO)的基础上,加入适量钒钛,研究了钒钛对取向硅钢组织与磁性能的影响。结果表明,适量钒钛使热轧板和脱碳退火板组织更好,尤其使脱碳退火板的晶粒更加细小和均匀;加入适量钒钛不但使热轧板表面高斯织构强度更高,更使脱碳退火板中有利于高斯织构发展的γ织构强度更高;适量钒钛能形成Cu2S+(V,Ti)N等复合析出物,起到辅助抑制剂作用,加强抑制能力。细小均匀的晶粒、强度更高的有利织构和更强的抑制能力使CGO钢磁性能更佳。 Effect of V and Ti on microstructure and magnetic properties of conventional grain-oriented silicon steel(CGO) were investigated under simulated thin slab continuous casting and rolling process in laboratory with Cu2 S as the dominant inhibitor. The results show that appropriate amount V and Ti make the microstructures of the hot rolled sheet and the decarburizing annealed sheet better,especially make the grains of the decarburizing annealed sheet more tiny and uniform. Adding appropriate V and ...
无取向硅钢钢液增钛原因分析
对无取向硅钢炼钢全流程钢液增钛的原因进行了分析,认为铁水钛含量、转炉出钢温度、转炉下渣量、精炼渣TiO2含量、钢水罐及RH浸入管混钢种生产是影响钢液增钛的主要原因。通过采取低钛铁水冶炼,减少转炉下渣量,提高出钢温度,添加白灰改质精炼渣等措施,均能够降低钢液中的钛含量。 After analyzing the causes leading to increased content of titanium in molten nonoriented silicon steel during whole steelmaking process, it was concluded that such factors as content of titanium in hot metal, tapping temperature from converter, quantity of roughing slag entered into the ladle from converter, content of TiO2 in refining slag, molten steel ladle car,carrying out the steelmaking of different steel grades by the same ladle and same RH immersion tube were the main causes ...
氢氧化镁煅烧制备硅钢级氧化镁的研究
以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination...
热轧工艺对TSCR流程生产取向硅钢组织和性能的影响
取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}~{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot...

