钢厂
高牌号无取向硅钢CSP流程铸坯及热轧板的组织和夹杂物分析
2.9 mm热轧3%Si高牌号无取向硅钢板(/%:0.004 6C、3.04Si、0.32Mn、0.49Als、0.004S、0.013P、0.0042N)由CSP(Compact Strip Production紧凑式带材生产线)流程:120 t BOF-70 mm CC-热轧工艺生产。热轧终轧温度872℃,卷取温度683℃。铸坯及热轧板的组织和夹杂物的分析结果表明,铸坯组织为典型的贯穿柱状晶组织;热轧板边部为再结晶组织,中部为纤维组织带有少量再结晶晶粒;高牌号无取向硅钢的主要夹杂物为铸坯-Al2O3,AlN和Cu2S+MnS;热轧板-Al2O3,AlN,AIN+MnS和Cu2S+MnS。 The 2.9 mm hot rolled 3%Si high grade non-oriented silicon steel plate(/%:0.004 6C,3.04Si, 0.32Mn,0.49Als,0.004S,0.013P,0.004 2N) is produced by CSP(Compact Strip Production) flow sheet i.e.120 t BOF-70 mm CC-hot rolling process with end rolling at 872℃and coiling at 683℃.The analysis results on structure and inclusions in casting slab and hot rolled plate show that the structure of slab is typical trans-columnar crystal,the structure of hot rolled plate at edge is recrystallized grain and in ce...
不同尺寸电工钢样品磁性能检测对比分析
对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ...
卷取工艺对新型冷轧无取向电工钢组织性能的影响
研究了卷取工艺对一种新型含铜无取向电工钢晶粒尺寸、织构演变、铁损和磁感应强度的影响。结果表明,试样织构组分主要为{111}、{112}、{100}和高斯织构,在550℃卷取、保温2~3h,{100}织构有增强趋势,磁感应强度较高,铁损较低。 The effects of coiling process on grain size,texture,core loss and magnetic induction of a new cold rolled non-oriented electrical steel with copper were investigated.The results show that there are mainly {111},{112},{100} and {110}<001> texture.Coiling at 550℃and keeping for 2~3 hours,the {100} texture is enhanced,magnetic induction is higher and core loss is lower.
电感耦合等离子体质谱法测定硅钢中痕量铝钼钒钛铌
研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c...
薄板坯连铸连轧流程生产高磁感取向硅钢的研究现状与技术分析
概述了高磁感取向硅钢生产工艺的研究现状及发展趋势。介绍了国内外薄板坯连铸连轧流程生产高磁感取向硅钢的研究现状。从流程工序特点、热履历、组织与抑制剂控制方面进行对比,分析了薄板坯连铸连轧流程相对传统板坯流程生产高磁感取向硅钢的技术优势,在此基础上提出了利用该流程生产高磁感取向硅钢需要解决的主要技术难点。 The current status and development trend of production process for high magnetic induction grain-oriented silicon steel are summarized.The research status of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process at home and abroad is introduced.The potential technical advantages of producing high magnetic induction grain-oriented silicon steel by thin slab casting and rolling process are obtained by analyzing in terms of process characteristics,t...
硅钢级氧化镁颗粒度检测工艺的研究
通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control.
一类非线性系统控制方法在硅钢生产上的应用
硅钢工业退火炉温度控制具有强耦合、纯滞后、多扰动等特点,它的控制方法代表着一类非线性系统控制的解决方法。以硅钢工业退火炉温度为控制对象,在双交叉限幅控制的基础上引入了智能学习系统,形成了基于智能学习系统的双交叉限幅控制方法来解决此类非线性系统的控制问题,并通过模块化的编程来实现其功能。结果表明:与传统的PID控制相比,该控制方法的控制精度、抗扰性等控制指标有明显提高,是解决此类非线性控制的一种有效方法。 The temperature control of silicon steel industrial annealing furnace has the features of strong coupling,pure lag,multidisturbance. The control method represents the solution of a class of nonlinear control systems. The control object is the temperature control of silicon steel industrial an-nealing furnace, the intelligent learning system based on Double Across Limit Control is introducedand used to solve control problem of this kind of nonlinear system, and the module programming isused to re...
火花源原子发射光谱法测定取向硅钢中碳硅锰磷硫
通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination...
奥氏体化温度对高碳含硅钢等温转变的影响
采用XRD物相分析、金相组织观察及TEM精细组织分析研究了奥氏体组织结构状态对Fe-0.88C-1.35Si-1.03Cr-0.43Mn钢中温等温相变鼻温和孕育期的影响,以及不同温度奥氏体化后240℃等温20 min试样的组织结构特征。试验发现,随着奥氏体化温度的升高,中温等温开始转变的鼻温移向更低温度并且相变孕育期缩短;不同温度奥氏体化后同为240℃等温20 min处理,虽然均形成由贝氏体铁素体亚条平行排列构成的束状贝氏体组织,但贝氏体组织的精细结构状态不同,突出的差别在于对应低温奥氏体化贝氏体亚条端部边界具有凸起结构,而对应高温奥氏体化贝氏体亚条端部边界较为平齐且呈现楔形结构。不能简单地以马氏体切变机制认识试验钢中贝氏体组织的形成。 The influence of austenitization temperature on the incubation period and the bainitic phase transformation behaviour in high-carbon silicon steel has been investigated using X-ray diffraction(XRD), optical microscopy and transmission electron microscopy(TEM). The microstructure characteristics of the isothermal transformation(240 ℃, 20 min)products were also studied. It was found that the nose temperature of bainite transformation and incubation period decreased with the increasing austenitizin...
热处理工艺对含Mn高硅钢热轧带的组织及硬度的影响
研究了热处理工艺(退火温度、保温时间、冷却方式)对含Mn的Fe-6.5wt%Si高硅钢热轧带的显微组织及硬度的影响。结果表明,退火温度对Fe-6.5wt%Si合金的组织和显微硬度均有较大影响,随退火温度升高,平均晶粒尺寸和显微硬度均明显增大。小于1 h退火时,晶粒长大缓慢,而长时间(>1 h)退火时,一些次表层晶粒将发生异常长大。水冷组织比空冷组织略细小,但水冷显著降低了显微硬度。Mn含量提高能抑制850℃退火时晶粒的长大,并且促进退火后高硅钢的软化。 The influences of heat treatment process(annealing temperature,heating time,cooling methods) on the microstructure and microhardness of Fe-6.5wt%Si high silicon steel containing manganese for hot rolled strip were studied.The results show that the annealing temperature has a great effect on the microstructure and microhardness of Fe-6.5wt%Si alloy,and as the annealing temperature increases,the average grain sizes and microhardness will significantly increase.When annealing time for less than 1 h...
无取向硅钢钙处理前后夹杂物的行为研究
研究了无取向硅钢钙处理前后夹杂物的行为,重点考察了钙处理前后夹杂物的成分、类型、形貌和尺寸研究的变化情况,为实际生产中无取向硅钢的钙处理提供理论指导。试验发现:钙处理前夹杂物主要以Al2O3、Al2O3-MgO为主,且在夹杂物表面有AlN析出,钙处理后夹杂物以Al2O3-MgO-CaS-CaO系复合夹杂物为主,还含有少量的SiO2或AlN;钙处理前后,夹杂物形貌由多边形或不规则形逐渐向球形或近似球形转变,并且夹杂物尺寸不断增大;钙处理前后,含钙夹杂物的比例发生突变,由10%增大到74.5%,且随着钙处理时间的延长,含钙夹杂物比例下降,表明钙处理使夹杂物变性后易聚集长大并上浮去除。 Behavior of inclusions before and after calcium treatment in non-oriented silicon steel was researched by investigating changes of compositions,types,shapes and sizes of inclusions before and after calcium treatment,for the purpose of providing theoretical guidance for calcium treatment of non-oriented silicon steel in actual situation. Results indicated that Al2O3 and Al2O3-MgO were main types of inclusions before calcium treatment,sometimes AlN maybe precipitate in the outer of inclusions. Al2...

