论文

对高牌号无取向电工钢国内生产情况、工艺技术、产品性能及应用领域等进行了阐述,并探讨了高牌号无取向电工钢产品的发展趋势。 This paper introduces basic facts on the production status,process technology and products’ properties and their applications of non-oriented electrical steel with high grade at home,and then discusses the development trend on technology for producing the non-oriented electrical steel with high grade. 

【作者】 王磊； ...

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the... 

对冷轧无取向硅钢在冶炼过程中各个工序的顶渣进行了检测,分析了顶渣变化原因,并得出结论:硅钢生产宜采用复吹转炉,以降低吹炼终点渣中TFe含量,进而减轻对精炼的压力;使用低S、低Al2O3含量中间包覆盖剂;RH脱氧及合金化顺序采用先加硅铁后加铝;首罐宜经LF提温并降低渣中TFe。 The top-surface slag used for the various production processes in smelting coldrolled non-oriented electrical steel is tested and based on tested results the cause of the top surface slag change is analyzed.So it is concluded that the combined blown converter is more suitable to be used for smelting electrical steel in order to reduce the content of TFe in slag at blow end point and then much better results can be achieved during the period of refining.Secondly the tundish flux contenting low co... 

结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ... 

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

通过对辉光放电发射光谱法分析电工钢样品光谱行为的研究,分析其工作参数如:电压、电流、预溅射时间和积分时间对光谱强度和稳定性的影响,并以铁为内标元素,优化了工作参数。确定了直流辉光放电光谱法测定电工钢中碳、硅、锰、磷、硫、铬、镍、铜共8种元素的定量分析方法,并对该方法分析的精密度和准确度进行验证,结果表明,各元素的测定结果与认定值和其他方法测定值一致,测量元素结果RSD值小于2%。 Based on research on analyzing the spectrum behavior of the sample taken from the electrical steel by glow discharge optical emission spectrometry,the effect of its operational parameters such as current,voltage,pre-sputtering time and integrating time on the spectral intensity and spectral stability is analyzed.Taking the Fe as an element applied by internal standard method,these operational parameters are optimized,and therefore the quantitative analysis method for testing eight kinds of eleme... 

根据相关的取向电工钢典型专利技术,概述了日本高磁感低铁损取向电工钢低温板坯加热、抑制剂合理调节、关键成分Mn、C、Sn和Sb调节与利用、新型退火剂和绝缘溶液的制备及细化磁畴等生产工艺最新动态和进展情况,并提出了国内企业申请取向电工钢专利时应当借鉴之处。 According to related typical patent technology for grain-oriented electrical steel sheets,the recent trends and progress situation for production process of grain-oriented electrical steel sheets with high magnetic flux density and low core loss in Japan are summarized including low temperature slab heating,suitably regulating inhibitors,adjusting and utilizing key element Mn,C,Sn and Sb,manufacturing for new annealing agent and insulating solutions,and fining magnetic domain,and some suggestion... 

针对马钢无取向电工钢孔洞缺陷的分布规律及形貌特征,对缺陷样进行了显微分析,并利用生产实绩数据分析了该缺陷产生的原因。结合热轧生产过程,主要通过避免带钢撞击导卫以及降低导卫结瘤的产生等措施,可有效抑制热卷异物压入产生,从而降低冷轧工序孔洞的产生。 In viewing of the distribution and morphology characteristics of the hole defect of non-oriented electrical steel in Maanshan Iron and Steel Co.,Ltd.,the causes of the defect were analyzed by micro analysis of the defect sample and the production data.Combined with the production process of hot rolling,by avoiding the impact of strip steel on the guide and reducing the nodule formation on the guide,the pressing of foreign bodies in hot coiling could be effectively suppressed,thus reducing the fo... 

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali... 

研究了CSP工艺生产≤0.005%C-1.1%Si的2.2mm无取向电工钢热轧板在800～1000℃常化对0.5mm冷轧板840℃退火后组织和磁性能的影响。结果表明,热轧板常化温度升高,冷轧板退火后的再结晶晶粒增大,铁损降低,磁感增加;热轧板常化温度超过900℃,因第二相固溶而后弥散析出,退火后冷轧晶粒细化,铁损增加,因此该无取向电工钢热轧板最佳常化温度为900℃。 The effect of normalizing at 800-1000℃ of CSP produced plate(≤0.005%C-1.1%Si) on the microstructure and magnetic properties of downstream cold-rolled non-oriented electrical steel annealed at 840℃ was studied.Results show that with increasing normalizing temperature of hot-rolled material the recrystallized grain size of annealed sheet increases,iron loss reduced and magnetic induction increases.As normalizing temperature excesses 900℃,grain is refined and iron loss increases after annealing due...