论文

结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte... 

研究了热处理工艺(退火温度、保温时间、冷却方式)对含Mn的Fe-6.5wt%Si高硅钢热轧带的显微组织及硬度的影响。结果表明,退火温度对Fe-6.5wt%Si合金的组织和显微硬度均有较大影响,随退火温度升高,平均晶粒尺寸和显微硬度均明显增大。小于1 h退火时,晶粒长大缓慢,而长时间(>1 h)退火时,一些次表层晶粒将发生异常长大。水冷组织比空冷组织略细小,但水冷显著降低了显微硬度。Mn含量提高能抑制850℃退火时晶粒的长大,并且促进退火后高硅钢的软化。 The influences of heat treatment process(annealing temperature,heating time,cooling methods) on the microstructure and microhardness of Fe-6.5wt%Si high silicon steel containing manganese for hot rolled strip were studied.The results show that the annealing temperature has a great effect on the microstructure and microhardness of Fe-6.5wt%Si alloy,and as the annealing temperature increases,the average grain sizes and microhardness will significantly increase.When annealing time for less than 1 h... 

某冷连轧机生产无取向硅钢板材时,其边缘降的长度合格率频繁超标。为满足用户的叠片厚度精度要求,这类产品必须以增大切边量的方式来保证交货质量,而这种方式又直接降低了金属收得率,提高了生产成本。基于此,以该产线现有设备特性为基础,详细分析其软、硬件功能模式,分别对辊形与反馈控制进行全面分析与优化改进。通过现场试验论证,充分明确依托辊形优化与反馈控制程序的改进能显著提高边缘降的控制水平,该技术的使用为生产现场的边缘降控制提供了合理的技术支撑。 A cold rolling mill production of non-oriented silicon steel sheet,the thickness difference of the edge( edge-drop) is usually exceed the preset standard value,In order to meet the accuracy requirements of the user flatness,these production must be trimed wider length to meet the delivery quality of the user need, which directly reduce the metal yield and increase the manufacturing cost. Therefor,the software and hardware of the production line has been analyzed, and the work roll shape and feed... 

结合工业化生产的50A1300牌号无取向硅钢,分析了化学成分、RH精炼脱氧方式、板坯装炉温度以及热轧平整工艺等对磁性能的影响,探讨成品钢磁性能的改善。结果表明,采取改善后,50A1300牌号无取向硅钢的磁性能得到明显改善。2012年,该钢种平均铁损、磁感应强度分别达到5.26 W/kg、1.762 T,能够较好地满足用户市场需求及同行对标需要。 Based on the industrial manufacture of 50A1300 grade non-oriented silicon steel sheets,effects of chemical composition,deoxidization method in RH vacuum refining,charging temperature of steel slabs,hot rolling and flattening progress on magnetic properties are analyzed.The optimization methods of magnetic properties of steels are discussed. Results show that the magnetic properties are obviously improved by the adopted measures above. In 2012,the average core loss and the magnetic induction of 5... 

结合工业化生产的无取向硅钢,进行了RH精炼添加稀土合金实验。结果表明,1.15%(质量分数)Si钢的脱硫反应,主要发生在添加稀土合金之后的前5min。最佳的稀土合金添加量为0.6～0.9kg/t钢。钢液经过稀土处理后,加入的稀土总量越多,稀土氧硫化物夹杂物的尺寸就越大,但热轧带钢再结晶效果会逐渐变差,成品带钢晶粒尺寸先是快速长大,而后逐渐减小。最佳的钢中存留稀土含量与钢的化学成分有关,应严格控制在2.0×10-3%～6.0×10-3%(质量分数)。在此范围内,钢的铁损先是快速降低,而后缓慢升高,钢的磁感应强度则单调降低。 Based on the industrial production of non-oriented electrical steel,rare earth(RE) alloy treatment during the RH refining process was studied.The results showed that the effects of desulfurization and total concentration of RE remained in steel mainly depended on the chemical compositions of different steel grades.For 1.15wt% Si steel grade,the desulfurization reaction mainly focused on the initial 5min after RE alloy added during the RH refining process.The suitable RE alloy addition was 0.6-0.... 

提出以“云边一体化架构”构建硅钢智慧决策系统，来解决原硅钢制造L1～L5系统架构模式下的数字信息孤岛、业务功能割裂等问题。在此基础上，开发了云边协同的自学习型控制模型及业务决策模型，构建起硅钢“智慧大脑”，形成了以研发、制造、服务等核心业务数字化融合的智能化决策支持新模式，探索出一条钢铁制造业数字化、智能化转型之路。 SIDS(Silicon-steel Intelligent Decision-making System)based on \"cloud-edge integration architecture\" was proposed to solve the problems of data silos and business function fragmentation in the original L1～L5 system architecture.On this basis,the self-learning control model and decision-making model of cloud-edge collaboration were developed,the \"smart brain\" of silicon steel department was constructed,and a new intelligent decision-making support model of digital integration of core businesses s... 

结合工业化生产的高效硅钢,进行了RH精炼稀土处理试验研究。针对不同的稀土处理条件,观察了夹杂物的形貌和尺寸分布,探讨了稀土处理后钢中的夹杂物形成、变化规律。结果表明:试验条件下,最佳的稀土合金添加数量为0.6～0.9 kg/t。经过合适的稀土处理后,可以有效抑制尺寸相对较小的、不规则的AlN、MnS复合夹杂生成,促进钢中微细夹杂物的聚合、上浮,钢质纯净度得到明显提高。此时,钢中全氧含量最低,脱硫效果最佳,钢中的夹杂物主要是尺寸相对较大的、近似球形或者椭球形的稀土类夹杂。 Based on the industrial production of non-oriented silicon steel,the experiment on RE treatment during the RH refining process was studied.The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions.Further more,the formation and change of inclusions of final steel sheets after RE treatment were discussed.The results show that the suitable RE added amount was 0.6～0.9 kg/t.After the suitable RE treatment,the formation of AlN and Mn... 

为了弄清楚高硫硅钢中的硫化物析出行为及其对钢的微观组织和电磁性能的影响，以便为工业化生产制定更为合理的硫含量控制标准和采取更为有效措施减轻炼钢生产的硫含量控制压力，结合0.25% Si 无取向硅钢 ，采用非水溶液电解提取 + 扫描电镜/透射电镜观察相结合的方法 ，研究了0.006 8%、0.010 2%、0.025 5% 和 0.035 3% 硫含量条件下，钢中的硫化物夹杂物组成和存在形式及其形貌、种类、尺寸、数量变化，以及相应的热轧、成品试样的微观组织和电磁性能变化。结果表明，随着钢中硫含量的增加，钢中的硫化物逐渐由 MnS→MnS+Cu₂S→Cu₂S转变，数量逐渐增多，尺寸向高低两个方向发展。相应地，导致热轧再结晶组织劣化和抑制了成品晶粒尺寸长大。随着钢中硫含量的增加，钢的磁感、铁损劣化程度逐渐增大。钢中的硫含量平均每增加 0.01%，涡流损耗、磁滞损耗分别劣化0.24 W/kg 和 0.41 W/kg，而磁感会劣化 0.009 T。但是 ，在硫含量为 0.010 2% 时 ，铁损可以低于 6.0W/kg，而在硫含量为 0.025 5% ... In order to find out the precipitation behavior of sulfide inclusions and the corresponding changes of microstructure and electromagnetic properties of high sulfur silicon steel sheets, so that to design more suitable sulfur concentration controlling limit for industrial manufacture and to release the steel-making difficulty effectively, Based on the change of given sulfur concentration 0.006 8%, 0.010 2%0.025 3% and 0.035 3%, the type and composition, the size and number, and the size distribut... 

采用RH精炼添加钙合金方式对硅钢进行钙处理,结果表明,钙合金添加量为0.67、1.00和1.67 kg/t钢时,钢中Ca含量分别为0、2×10-6和4×10-(6质量分数);随着钙合金添加量的增加,钢中夹杂物粒度逐渐由0～2μm向2～4μm、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或与AlN、CaS夹杂复合;钢中粒径为5～10μm的夹杂物基本以Ca的氧化物和硫化物为主。与未经钙处理的炉次相比,钙合金添加量为0.67、1.00和1.67 kg/t钢时,粒径小于1.0μm的夹杂物减少幅度分别为68.06%、87.50%和94.94%。钙合金添加量为1.67 kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 In order to improve the properties of final silicon steels,the calcium treatment was adopted by adding Ca alloys into the liquid steel during the RH refining process.Results show that when the addition of Ca alloys is 0.67 kg/t,1.00 kg/t and 1.67 kg/t,the corresponding Ca content in silicon steels is 0,2 × 10-6 and 4 × 10-6 respectively.With the increase of Ca alloy addition,the particle sizes of inclusions in steels become 2～4 μm and 4～6 μm,from 0～2 μm.Under different calcium treatments,there e... 

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

对碳-锰-硅钢进行不同配分温度的Q&P(Quenching and Partitioning)处理,测试了热处理后不同钢的力学性能和残余奥氏体含量,并用扫描电子显微镜和透射电镜观察其显微组织,分析了配分温度对显微组织和力学性能的影响。结果表明:试验钢显微组织基本由低碳板条状马氏体、块状铁素体和条状残余奥氏体组成;随配分温度的升高,试验钢的抗拉强度呈下降趋势,伸长率与奥氏体含量的变化趋势相同,但变化规律不确定;提高锰含量能稳定残余奥氏体,从而提高试验钢的伸长率,并使伸长率对配分温度不敏感。 The C-Mn-Si steel was quenched and partitioned at different partitioning temperatures,the mechanical properties and residual austenite contents were investigated,the microstructure was observed by SEM and TEM,and the effect of partitioning temperature on microstructure and mechanical properties was analyzed.The results show that the microstructure of the tested steel consisted of lath martensite with low carbon,nubby ferrite and banded residual austenite.The tensile strength of the tested steel ...