硅钢资料

本发明涉及电磁钢板技术领域，尤其涉及一种免涂层高碳高强耐蚀电磁钢板及其生产方法。所述电磁钢板按重量百分比计，包括如下组分：C为0.010％～0.150％，Si为1.30％～2.50％，Mn为0.50％～1.50％，P为0.04％～0.15％，S≤0.015％，Cr为0.10％～1.50％，Cu为0.2％～0.6％，Al为0.10％～1.50％，Sn为0.02％～0.10％，Ni≤0.0050％，Nb≤0.0050％，Ti≤0.0050％，N≤0.0050％，V≤0.0050％，其余为Fe和不可控残余元素。所述钢板生产方法包括如下步骤：1)板坯浇铸；2)板坯连轧及卷曲；3)热轧卷酸洗及冷轧；4)罩式退火；5)钢卷矫直或拉矫。本发明所生产专用产品在电磁性能相近情况下，强度进一步提升、耐蚀性能提高、生产流程缩短、生产难度下降，减少了涂层工序，降低了生产成本，同时不同盐雾试验锈蚀减少85％以上。

一种在取向硅钢中获得沿晶断口的方法：将取向硅钢样品加工成俄歇电子能谱仪标准试样；对标准试样进行表面清理；充氢：将标准试样所设定的预设断口处放入充氢装置的含硫脲溶液中，并使取向硅钢样品为阴极；将铂片置入并作为阳极；阴极充氢电流为1.25～1.35A，充氢电流密度在0.1～0.8A/m2，充氢时间在12～50h，充氢电压为36～39V；进行表面分析。本发明不仅工艺简单，便于操作，用时短，所用毒化剂是硫脲，从而避免了采用剧毒的三氧化二砷作为毒化剂，对人体健康有极大威胁的问题，且所获得的取向硅钢断口均为典型沿晶断口，适用于取向硅钢晶界偏聚行为以及晶界微区成分分析。

根据本发明的一个实施例的无取向电工钢板，以重量％计，所述钢板包含Si：1.5％以下、C：0.01％以下且0％除外、Mn：0.03至3％、P：0.01至0.2％、S：0.001至0.02％、Al：0.01％以下且0％除外、N：0.005％以下且0％除外、和Cu：0.02至0.3％，Ca和Mg各自单独或以合计含量包含0.0001至0.005重量％，Sb和Sn各自单独或以合计含量包含0.001至0.2重量％，余量包含Fe和不可避免的杂质。

根据现场实际的生产控制情况,指出了热轧原料断面轮廓缺陷以一定的比列遗传给了冷轧带钢,分析了不同热轧原料断面轮廓对冷轧电工钢尺寸精度的具体影响,提出了相应的规律。并阐明了严格控制热轧原料断面轮廓形貌,对保证冷轧电工钢尺寸精度具有重大意义,对于中国现行的冷轧电工钢生产具有指导意义。 Based on the actual situation of production control,it was pointed out that the section profile defects of hot-rolled raw materials were geneticed to the cold-rolled strip.The specific impact analysis for the profile of different hot-rolled raw materials to the dimensional accuracy of cold-rolled silicon steel was analyzed.As a result, the corresponding orderliness are given;And the strict control to section profile of the hot-rolled material is of great significance to ensure the dimensional ac... 

【摘要】 <正>近日,世界上最先进的硅钢冷连轧酸轧...

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h... 

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

【作者】 周威； 刘侃； ...

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r... 

硅钢高温退火环形炉炉壳制作与安装精度要求较高,施工时通过对壳体原材料矫正、炉壳板拼焊、下料切割、型钢骨架组装及焊接、骨架及炉壳板矫正、骨架与炉壳板组装及焊接、炉壳矫正、零配件装置、定位钻孔、报验检查、出厂、内侧板安装、外侧板安装、顶板安装等环节的工艺技术控制,能保质高效地完成硅钢高温退火环形炉炉壳制作与安装,为以后同类工程的施工提供可借鉴经验。 The required precision of manufacture and installation technique of the silicon steel high temperature annealing annular-furnace shell is high.During construction , manufacture and installation of the silicon steel high temperature annealing annular-furnace shell could be finished high efficiently through correcting the raw materials of shell , furnace shell plate welding , material cutting , steel frame assembly and welding , skeleton and shell plate correction , skeleton and furnace shell asse...