硅钢资料

本发明公开了一种适应高频率工况下低铁损无取向电工钢及其生产方法，所述生产方法包括以下步骤：钢水连续浇铸成板坯—热轧—正火—酸洗—冷轧—连续退火—涂绝缘涂层并固化；所述冷轧步骤中，采用六辊单机架往复式轧机经5道次一次冷轧至目标厚度，冷轧过程中前三道次采用变速异步轧制方法，使钢板表层在剪应力作用下位错密度增加，这样在退火后表层晶粒尺寸细化而心部晶粒粗大，通过本发明的方法可生产得到心部为粗大等轴晶粒，表层为纳米级细等轴晶粒的电工钢产品，该产品的铁损P1.5/50≤2.35W/kg，P1.0/400≤14.0W/kg。

本发明涉及一种转炉冶炼回炉高硅钢水的方法，转炉中兑入回炉高硅钢水，再兑入铁水至预定装入量，使转炉中的钢水硅含量≤1.0％；转炉采用双渣冶炼的方法，加入的造渣料包括活性石灰、白云石、轻烧白云石、烧结矿；吹炼时氧累达到83％‑85％时使用副枪测量TSC，按TSC测量数据吹炼至钢水目标成分和目标温度后提枪，出钢。本发明实现转炉冶炼回炉高硅钢水的稳定控制。降低钢厂经济损失，减少炼钢生产事故率。提高了炼钢生产作业率。

对高牌号无取向电工钢国内生产情况、工艺技术、产品性能及应用领域等进行了阐述,并探讨了高牌号无取向电工钢产品的发展趋势。 This paper introduces basic facts on the production status,process technology and products’ properties and their applications of non-oriented electrical steel with high grade at home,and then discusses the development trend on technology for producing the non-oriented electrical steel with high grade. 

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

本发明涉及一种提高取向硅钢冷轧加工性的生产方法，工艺流程为：冶炼、连铸、热轧、常化、酸洗、冷轧、脱碳渗氮、涂MgO、高温退火、涂绝缘层及热拉伸平整；粗轧中坯厚度35‑45mm，两段常化后进行带钢横向分段式冷却水分布。本发明通过对热轧中坯厚度、终轧温度及卷取温度，常化冷却水量及控制方式的调控，使轧前表层晶粒尺寸降低5‑10μm、珠光体体积分数降低6％，轧材冷轧加工性明显改善、成材率可提高8％以上。通过后续冷轧、脱碳退火和高温退火等工序处理，可保证完善的二次再结晶组织及良好磁性能。

研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit...