硅钢资料

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

本发明提供了一种取向硅钢的磁畴细化方法，属于高磁感取向硅钢生产技术领域技术领域，包括：采用激光在带钢表面烧蚀出若干沟槽；采用腐蚀液对所述沟槽进行腐蚀，获得刻槽；其中，所述沟槽与带钢宽度方向的夹角为0‑20°；所述沟槽的深度为0.5～20μm，宽度为30～200μm；所述刻槽深度为0.5～30μm、宽度为30～300μm。该方法能够显著的细化磁畴，降低取向硅钢片单位损耗，同时细化磁畴的效果能够承受800℃‑900℃的消除应力退火。本发明还提供了一种取向硅钢的磁畴细化方法在取向硅钢生产中的应用。

本发明提供的一种耐热型低损耗取向硅钢，取向硅钢的单面采用激光刻痕形成平行线状沟槽；所述激光刻痕为取向硅钢制备工艺中的渗氮步骤之后和在涂覆MgO涂层步骤之前实施；在渗氮步骤之后和在涂覆MgO涂层步骤之前进行激光刻痕加工不会破坏高温退火后形成的硅酸镁底层，底层完整性好，刻痕形成的沟槽位于取向硅钢带材金属基体表面，在高温退火过程中沟槽内直接反应生成硅酸镁底层，最终取向硅钢带材表面涂覆张应力涂层后光滑、平整、无凹凸，取向硅钢带材损耗低、叠片系数高、耐热，成品取向硅钢带材既可用于制备立体卷铁心变压器也可用于制备叠片铁心变压器。

利用OM、SEM、TEM等实验方法研究了卷取工艺对一种新型含铜无取向电工钢晶粒度和析出相的影响。结果表明,该电工钢热轧带卷取后的晶粒尺寸为18～24μm,在卷取过程中,热轧带中有一定数量的第二相析出,经EDS能谱及选区电子衍射分析,这些析出相主要为AlN。随着卷取工艺的变化,该电工钢的晶粒度大小变化不明显,析出相的类型、尺寸大小不发生改变,体积分数发生一定的改变。 The effects of coiling process on grain size and precipitates of a new copper-bearing non-oriented electrical steel were investigated by OM,TEM and other experimental method.The results show that the grain size of hot-rolled bands after coiling is 18～24 μm.The second phases precipitate during coiling process.They are mainly AlN by EDS spectra and selected area electron diffraction.With the change of coiling process,the grain size of the electrical steel does not change significantly;the type and... 

为了确定普通冷轧取向硅钢最优的中间完全脱碳退火工艺,在其一次冷轧后进行5种不同工艺的脱碳退火处理,借助扫描电镜及电子背散射衍射技术研究了不同工艺脱碳退火后的组织、织构和脱碳效果。结果表明:经5种工艺脱碳退火处理后,初次再结晶的平均晶粒尺寸均约为19μm,且不随退火温度和时间的变化而变化;经840℃×10min工艺退火后的晶粒最均匀,高斯织构位向更准确,高斯织构面积分数最多,为3.1%,可将碳脱至0.003 5%。 In order to determine the optimal intermediate complete decarburizing annealing processes for common grain-oriented(CGO)silicon steel,five kinds of intermediate decarburizing annealing processes were conducted,the microstructure,texture and decarbonization after different decarburizing annealing processes were studied by scanning electron microscopy and electro back-scattered diffraction(EBSD)technology.The results show that the average grains sizes of primary recrystallization were about 19μm a... 

本发明公开了一种取向硅钢极薄带的工业连续化生产方法，包括异步轧制、脱脂、热处理、急速冷却、涂绝缘层、烘干烧结、卷带收集各工序；其中，异步轧制中使用异步比为1：1.05～1：1.24；脱脂、热处理、急速冷却、涂绝缘层、烘干烧结、卷带收集工序为连续化生产工艺；热处理工序中，第一步为预热，预热温度为500℃～700℃，预热时间4秒～120秒；第二步为相变热处理，相变热处理温度为820℃～920℃，相变加热时间100秒～600秒；急速冷却工序中，钢带30秒内降温到350℃以下。优点在于：实现工业化连续生产取向硅钢极薄带，有效提高产能，生产的取向硅钢极薄带制备高磁感、低铁损等磁性能。

无取向硅钢中夹杂物的存在会抑止晶粒生长,使基体的均匀连续性中断,其在钢中的形态、含量及分布情况都不同程度影响着硅钢的性能,尤其是对磁性能起关键的作用。因此,全尺度分布考察夹杂物对无取向硅钢夹杂物的研究极为重要。本实验确定了适用于不同牌号无取向硅钢夹杂物全尺度分布的分析方法:样品制备—小样电解—过滤喷金—根据不同牌号的要求选择合适的放大倍率扫描观测—夹杂物颗粒的分类统计。通过统计的结果,结合电解的失重量可以得到不同尺度的体积分布数据。实验分析了不同牌号和工艺无取向硅钢夹杂物的种类、形貌、大小和尺度分布,并初步考查了夹杂物与磁性能的关系,对无取向硅钢的工艺研究具有一定参考价值。 Inclusions in non-oriented silica steel could inhibit the growth of grain and cause discontinuity of micro-structure.The configuration,content and size distribution of inclusion have different effects on the performance of silica steel,especially significant on the magnetic property.Therefore,it is very useful to completely characterize inclusions with full size distribution in silica steel.In our research,full size analysis method for inclusion in silica steel had been established as follows: s... 

对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

本实用新型公开一种稀土永磁变频电机加工硅钢片冷却装置，包括左、右间隔设置的悬架端杆；悬架端杆之间装配连接有若干个前后间隔设置的硅钢片卷料收卷部件，硅钢片卷料收卷部件均包括转动连接在悬架端杆上的旋转座，旋转座之间固定连接有若干个折形搭料杆，折形搭料杆包括横杆部，所述横杆部的左右两端均具有一体成型的折形端，折形端均固定连接在旋转座上；硅钢片卷料收卷部件之间通过传动部件传动连接；上述装置还包括若干个装配连接在悬架端杆顶部之间的风冷部件。采用上述装置部件设计实现对热处理加工的硅钢片快速卷绕，并且卷绕收卷过程中快速对物料进行冷却，有效提高了加工过程中硅钢片物料的冷却、收卷效率。

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

对低温加热工艺生产的普通取向(common grain-oriented,CGO)硅钢的高温退火过程进行了中断实验,材料为含3.0%Si、0.5%Cu、0.009 8%S(均为质量分数)的以Cu2S为主抑制剂的普通取向CGO钢。原始板坯厚度为230 mm,于1 200℃均热后经4道次粗轧、7道次精轧至2.3mm;热轧板采用两次冷轧法轧至0.3mm,中间完全脱碳退火,最后于1 200℃高温退火。最后样品的磁性能:铁损P17/50为1.182W/kg,磁感应强度B8为1.897T。借助配有EDAX OIM电子背散射衍射(EBSD)系统的ZEISS SUPRA 55VP扫描电子显微镜,对高温退火过程中高斯晶粒的演变进行了研究,结果表明:升温过程中晶粒尺寸增长缓慢,650℃时取向分布函数(ODF)图出现高斯织构组分,但强度很弱,高斯晶粒偏离角小于9°;950℃时高斯晶粒平均生长速度超过其他晶粒;950~1 000℃时高斯晶粒异常长大,偏离角降至约3°;在950℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势。 The high-temperature annealing process of common grain-oriented(CGO)silicon steel was investigated by interrupting test.The samples were rolled from CGO silicon steel slab under low reheating temperature.The CGO silicon steel,taking Cu2S as the main inhibitor,contains3.0%Si,0.5%Cu,and 0.0098%S.The original casting slab is 230mm in thickness.After 1 200℃reheating,four-pass rough rolling and seven-pass finish rolling were conducted to make the thickness of the slab get to 2.3mm.Then the hot rolled...