硅钢资料

本发明提供了一种无取向硅钢RH顶枪喷粉脱硫工艺，RH脱碳结束测温定氧，立即加入铝粒脱氧合金化、之后立即依次连续加入合金进行成分调整，合金加完后立即开始顶枪喷粉；加入铝粒的量＝铝粒理论加入量+0.2‑0.4kg/t钢；喷粉时，控制喷粉速度与钢液循环流量相匹配；本发明从真空条件下脱硫热力学和动力学角度出发对具有顶枪喷粉功能的RH脱硫工艺进行改进，提高脱硫率。

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

为了消除硅钢在连续退火机组产生的浪形缺陷,对浪形缺陷产生的主要原因进行了分析。制定了相应控制措施,对炉内带钢张力、冷却段输出、碳套辊与带钢的同步性、无氧化炉燃烧状态等参数进行了调整;在生产组织上安排高低牌号宽窄规格穿插生产、定期更换碳套辊等,实施后效果明显。 The main cause leading to waviness defects of silicon steel is analyzed in order to eliminate the waviness defects of silicon steel in continuous annealing line.And thus corresponding measures for controlling these defects are made by means of adjusting these parameters such as the tension of silicon steel coils in continuous annealing furnace,the output in cooling section and the combusting condition of the non-oxidation furnace as well as keeping the synchronization between carbon sleeved roll... 

本发明涉及一种取向硅钢热轧钢带的板形控制方法，所述取向硅钢热轧钢带的工艺流程包括铸坯加热过程、轧制过程及层流冷却过程；其中轧制过程中采取取向硅钢与普钢交叉轧制的方式；粗轧过程采取R1轧制1道次、R2轧制5道次的1+5轧制工艺，并控制轧制工艺参数；精轧过程中控制F1～F7轧制工艺参数。本发明通过设定合理的交叉轧制工艺及取向硅钢热轧工艺，使取向硅钢的轧制稳定性大幅提高，取向硅钢带形控制良好，凸度控制在30～50μm之内，楔形控制在30μm之内，板形平坦度控制在25iu之内；从而为冷轧工序提供了优质原料。

本发明公开了一种宽频率低铁损无取向电工钢及其制备方法，属于无取向电工钢生产制造技术领域。它从电工钢表面向内依次包括0.005mm～0.1mm的渗透层和钢材内芯；所述渗透层是由硅原子向电工钢内渗透形成，渗透层中的硅元素含量为3wt％～8wt％；所述钢材内芯包括2.0wt％～5.5wt％的硅元素和不少于93.2wt％的铁元素。本发明能保证无取向电工钢具有低频低铁损性能同时有效降低高频条件下的铁损，具体铁损性能为：铁损P1.5/50≤2.35W/kg，铁损P1.0/400≤13.8W/kg。

本发明公开了一种低铁损高磁导率无取向电工钢及其生产方法，所述生产方法包括以下步骤：钢水连续浇铸成板坯，板坯经加热炉加热，再经热轧得到热轧板，然后经空冷和水冷后在500～650℃进行卷取；热轧板经常化处理、盐酸酸洗；酸洗后在可逆轧机上进行冷轧；最后经成品退火，退火温度为840～900℃，加热时间为240～500s；然后以不超过3℃/s的冷却速度冷却至500℃以下；涂覆绝缘涂层、固化，后经二次退火，即可得到低铁损高磁导率无取向电工钢，其磁性能满足P1.5/50≤3.50W/kg，μ1.5≥3800Gs/Oe，B5000≥1.76T的要求。

本发明涉及一种冷连轧法生产无取向高硅钢的方法，RH真空脱碳处理后，铝脱氧及部分铝合金化，合金化后大罐钢水净循环大于3次或大于5分钟；熔炼合格钢水至连铸开浇前静置时间大于二十分钟；控制过热度5～15℃；采用电磁搅拌，控制等轴晶比例45％以上；3)热轧工序板坯装炉温度大于750℃；常化使晶粒尺寸在90～110μm范围内；连续退火炉加热段温度设定950～1150℃，均热段温度设定900～1050℃，全氮气干气氛保护，控制晶粒尺寸120～170μm。生产全过程中的热履历参数控制，充分发挥设计的微合金元素功能，改变析出物的组成、大小、形态及分布。

对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ... 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

本发明涉及电磁钢板技术领域，尤其涉及一种免涂层高碳高强耐蚀电磁钢板及其生产方法。所述电磁钢板按重量百分比计，包括如下组分：C为0.010％～0.150％，Si为1.30％～2.50％，Mn为0.50％～1.50％，P为0.04％～0.15％，S≤0.015％，Cr为0.10％～1.50％，Cu为0.2％～0.6％，Al为0.10％～1.50％，Sn为0.02％～0.10％，Ni≤0.0050％，Nb≤0.0050％，Ti≤0.0050％，N≤0.0050％，V≤0.0050％，其余为Fe和不可控残余元素。所述钢板生产方法包括如下步骤：1)板坯浇铸；2)板坯连轧及卷曲；3)热轧卷酸洗及冷轧；4)罩式退火；5)钢卷矫直或拉矫。本发明所生产专用产品在电磁性能相近情况下，强度进一步提升、耐蚀性能提高、生产流程缩短、生产难度下降，减少了涂层工序，降低了生产成本，同时不同盐雾试验锈蚀减少85％以上。

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca...