硅钢资料

本发明公开了一种切口耐蚀性良好的无取向硅钢及其生产方法，属于电工钢生产技术领域。本发明的无取向硅钢包括以下质量百分比的元素：Si：0.2～2.7％，Mn：0.15～1.0％、Als：0.5～1.0％，Cr：0.1～0.3％；Ni:0.2～0.5％，P：≤0.01％，其余为Fe及不可避免的杂质。其生产工艺为：铁水预处理、转炉炼钢、真空处理、连铸、加热、热轧、酸洗、冷轧、退火处理和涂覆绝缘层。本发明通过合理的成分配比以及相匹配的生产工艺进行生产，最终得到了切口耐蚀性优良的低铁损、高磁感的无取向硅钢，从而能够有效满足电工钢的使用需求。

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali... 

本发明公开了一种宽频率低铁损变频电机用无取向电工钢及制造方法，属于无取向电工钢领域。针对现有无取向钢在较宽频率范围内电磁性较差的问题，本发明提供一种宽频率低铁损变频电机用无取向电工钢，包括如下重量百分比的各组分：Si：2.80％～3.50％；Als：0.20％～0.60％；Mn：0.20％～0.60％；P：0.01％～0.20％；C：≤0.005％；S：≤0.02％；N：≤0.02％；Ti：≤0.005％；其余为铁和不可避免的杂质；其中C、S、N和Ti的重量百分比满足下式：C％+S％+N％+Ti％≤0.009％。通过控制合金元素的含量达到电工钢电阻率增加、磁滞伸缩减小，涡流和磁滞损耗均降低的目的。通过本发明提供的制造方法在正火过程中选用低温工艺，改善随着合金元素量的增加金属强度增加、塑性降低、冷加工性能降低的问题，使其最终在较宽频率范围内电磁性能优异。

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

采用中、厚板坯生产技术对取向硅钢进行了研制和开发,对热轧及后工序样品进行了金相组织观察和EBSD分析,探讨了两种组织及织构的差异性,研究结果表明:除高温退火样品外,中板坯生产的取向硅钢各工序样品平均晶粒尺寸大;厚板坯生产的取向硅钢热轧和常化样品亚表层Goss织构强;中板坯和厚板坯的脱碳退火板织构没有明显区别。中板坯生产的取向硅钢成本低,产品磁性能和质量与厚板坯相当。 Grain oriented silicon steel was researched and developed by medium thickness slab and thick slab.Microstructures observation and EBSD analysis to the samples of hot rolling and following processes were carried out,respectively.The differences between the two kinds of microstructures and textures were discussed.The results show that the average grain sizes of every process samples are larger except that of high temperature annealing samples of grain oriented silicon steel produced by medium thic... 

本发明公开一种冷轧硅钢的横向同板差控制方法，具体如下：S1、确定冷轧钢板横向同板差的影响因子，包括：热轧钢卷的热卷凸度、工作辊辊型插入量、中间辊窜动值及冷轧钢卷的总切边量；S2、以影响因子为变量构建冷轧钢板横向同板差的计算模型；S3、将热轧钢卷的热卷凸度及冷轧钢板的目标横向同板差输入计算模型，确定最小冷轧钢卷总切边量下的工作辊辊型插入量及中间辊窜动值。明确客户所需的横向同板差，通过改变工作辊辊型插入量X2及工作辊窜动值X3，以此得到冷轧成品钢卷的总切边量最小值，在满足客户对横向同板差的使用要求前提下，降低生产成本，提高产品竞争力。

对CSP流程生产的高磁感无取向电工钢50W1300在偏离轧制方向不同角度处的磁性能进行了测试和分析。结果表明:在偏离轧向不同角度处,磁性能差异显著,尤其在α=60°时磁感最低;偏离轧制方向不同角度处的磁性能大小取决于织构类型、强度及分布状态;增强{100}<0vw>和α、η取向的有利织构组分,降低不利的γ取向织构组分,且使有利织构组分分布越漫散,磁各向异性越小。 Magnetic properties of high magnetic induction non-oriented electrical steel 50W1300 produced by CSP processes were investigated with different direction in relation to the rolling direction.The result shows that magnetic properties are significantly different in relation to the rolling direction,in particular,the minimum magnetic induction occurs at 60° in relation to the rolling direction.Magnetic properties of different directions in relation to rolling direction depend on type and distributi... 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

【作者】 王磊； ...

对CSP流程生产的无取向电工钢M50W800不同尺寸样品的磁性能进行了测试和分析,结果表明:采用不同单片检测的磁性能结果与标准的Epstein方圈样品检测对比,存在明显的偏差;且同一尺寸的单片纵横向样品之间相比较,对应的磁性能差异性也较大。几种不同尺寸的单片样品,以320mm×30mm尺寸的纵横向平均值最接近标准Epstein方圈样的性能值,其铁损偏差最小。 The magnetic properties of M50W800 non-oriented electrical steel produced by CSP process were tested and analyzed with samples of different sizes,showing that significant deviation existed compared to that of Epstein square circle sample.In particular,obvious difference in magnetic properties also existed between longitudinal and transverse samples of the same size.For test samples of different sizes,the average magnetic properties of 320mm×30mm samples are the closest to that of Epstein square ... 

本发明提供了一种超高磁感无取向硅钢及其制造方法和在汽车发电机生产中的应用，成分：C：≤0.005％、Si：0.5‑1.2％、Mn：0.1‑0.5％、P：0.01‑0.1％、S：≤0.004％、Al：≤0.005％、N：≤0.005％、Ti：≤0.003％，余量为铁和不可避免的杂质。通过成分设计，配合CSP薄板坯连铸连轧工艺、常化工艺，不用添加贵金属元素，不添加贵金属元素，流程短、成本低、磁感高、性能稳定；节省成本的同时，具有优良的磁性能，采用本发明生产的汽车发电机铁芯，与常规产品生产的铁芯相比，重量可减轻15％以上，缩小了发电机尺寸，满足汽车发电机小型化、高效化的要求。

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,...