硅钢资料

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

研究了CSP工艺流程生产的硅含量为1.5%的无取向电工钢在不同常化温度下对磁性能的变化。研究结果表明:随着常化温度的提高,热轧板的晶粒尺寸增大,且组织均匀性提高;此外成品的有利织构组分{100}<0vw>、α、η增强,不利织构组分减弱;铁损P1.5/50呈下降趋势,磁感B50上升平缓。在常化工艺为970℃×2.5min下,对应的铁损P1.5/50<3.4W/kg,磁感B50>1.74T。 The effect of normalizing temperature on the magnetic properties of non-oriented electrical steel containing 1.5%silicon produced by CSP process was studied.The results show that with increasing normalizing temperature,the average grain size of hot-rolled plate increases and the microstructure uniformity is improved.Furthermore,the texture components of finished products are improved through enhancing of{100}<0vw>,αandηtextures and weakening of{111}<112>texture;the core loss P1.5/50 ... 

根据相关的取向电工钢典型专利技术,概述了日本高磁感低铁损取向电工钢低温板坯加热、抑制剂合理调节、关键成分Mn、C、Sn和Sb调节与利用、新型退火剂和绝缘溶液的制备及细化磁畴等生产工艺最新动态和进展情况,并提出了国内企业申请取向电工钢专利时应当借鉴之处。 According to related typical patent technology for grain-oriented electrical steel sheets,the recent trends and progress situation for production process of grain-oriented electrical steel sheets with high magnetic flux density and low core loss in Japan are summarized including low temperature slab heating,suitably regulating inhibitors,adjusting and utilizing key element Mn,C,Sn and Sb,manufacturing for new annealing agent and insulating solutions,and fining magnetic domain,and some suggestion... 

【作者】 朱凤泉； 黄生银； ...

通过对辉光放电发射光谱法分析电工钢样品光谱行为的研究,分析其工作参数如:电压、电流、预溅射时间和积分时间对光谱强度和稳定性的影响,并以铁为内标元素,优化了工作参数。确定了直流辉光放电光谱法测定电工钢中碳、硅、锰、磷、硫、铬、镍、铜共8种元素的定量分析方法,并对该方法分析的精密度和准确度进行验证,结果表明,各元素的测定结果与认定值和其他方法测定值一致,测量元素结果RSD值小于2%。 Based on research on analyzing the spectrum behavior of the sample taken from the electrical steel by glow discharge optical emission spectrometry,the effect of its operational parameters such as current,voltage,pre-sputtering time and integrating time on the spectral intensity and spectral stability is analyzed.Taking the Fe as an element applied by internal standard method,these operational parameters are optimized,and therefore the quantitative analysis method for testing eight kinds of eleme... 

本发明涉及一种常化后免酸洗生产取向硅钢的方法，取向硅钢的生产工艺路线为：冶炼→连铸→热轧→常化退火→拉伸矫直→抛丸→冷轧→脱碳退火→渗氮→涂MgO→高温退火→热拉伸平整及涂绝缘膜；本发明在常化退火后通过物理方法去除带钢表面的氧化铁皮，且效率高、效果好、操作简单、易于控制；与常规工艺相比，省去了酸洗及后续废酸处理工作，排除了酸雾对环境的污染，消除了取向硅钢带因酸洗而产生的潜在缺陷，产品质量更加稳定可靠。

本发明涉及一种取向硅钢热轧钢带的板形控制方法，所述取向硅钢热轧钢带的工艺流程包括铸坯加热过程、轧制过程及层流冷却过程；其中轧制过程中采取取向硅钢与普钢交叉轧制的方式；粗轧过程采取R1轧制1道次、R2轧制5道次的1+5轧制工艺，并控制轧制工艺参数；精轧过程中控制F1～F7轧制工艺参数。本发明通过设定合理的交叉轧制工艺及取向硅钢热轧工艺，使取向硅钢的轧制稳定性大幅提高，取向硅钢带形控制良好，凸度控制在30～50μm之内，楔形控制在30μm之内，板形平坦度控制在25iu之内；从而为冷轧工序提供了优质原料。

本发明公开了一种超高效变频空调压缩机用无取向硅钢薄带及其制造方法，属于无取向硅钢技术领域。本发明包括以下重量百分比的组分：C≤0.003％，Si：2.0％～2.5％，Mn：0.15％～0.5％，Als：0.3％～0.7％，Sn：0.05％～0.11％，S≤0.003％，P≤0.03％，B：0.002％～0.004％，Ca：0.003％～0.005％，N≤0.003％，Ti≤0.003％，其余为Fe及不可避免的杂质，且Mn/S比控制在20～60范围内，B/N比控制在0.7～1.5，Ca/S的比例≥1。为解决现有技术中存在的问题，本发明通过添加合金元素以及偏析元素，配合连铸、热轧、常化和连续退火等热处理工艺，以及优良的冷轧板形控制技术，实现0.30～0.35mm厚度薄规格的高效无取向硅钢产品，具备优异的磁性能和高屈强比的力学性能，满足高效变频空调压缩机电机磁性能和关节式定子高速冲裁对力学性能和板形的高标准要求。

为了消除硅钢在连续退火机组产生的浪形缺陷,对浪形缺陷产生的主要原因进行了分析。制定了相应控制措施,对炉内带钢张力、冷却段输出、碳套辊与带钢的同步性、无氧化炉燃烧状态等参数进行了调整;在生产组织上安排高低牌号宽窄规格穿插生产、定期更换碳套辊等,实施后效果明显。 The main cause leading to waviness defects of silicon steel is analyzed in order to eliminate the waviness defects of silicon steel in continuous annealing line.And thus corresponding measures for controlling these defects are made by means of adjusting these parameters such as the tension of silicon steel coils in continuous annealing furnace,the output in cooling section and the combusting condition of the non-oxidation furnace as well as keeping the synchronization between carbon sleeved roll... 

为开发高效电机用冷轧无取向电工钢,借助实验室薄板坯连铸连轧模拟设备及扫描电镜、透射电镜等检验手段研究了成分、组织、织构和析出物等对无取向电工钢磁性能的影响规律;结果表明:常化处理使组织均匀化并增加有利于磁性提高的织构组分;采用CSP流程开发的高效电机用无取向电工钢铁损平均值3.4 0 W/kg,磁感≥1.68 T。 In order to develop electrical steel for high efficiency motor,effect of components,microstructure,texture and precipitation on magnetic property of electrical steel are analyzed.From the result,normalizing treatment makes microstructure uniform and increases component of favorable texture.Iron loss of electrical steel developed by CSP line is 3.40W/kg and magnetic induction is more than 1.68T. 

介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel. 

本发明公开了一种宽频率低铁损无取向电工钢及其制备方法，属于无取向电工钢生产制造技术领域。它从电工钢表面向内依次包括0.005mm～0.1mm的渗透层和钢材内芯；所述渗透层是由硅原子向电工钢内渗透形成，渗透层中的硅元素含量为3wt％～8wt％；所述钢材内芯包括2.0wt％～5.5wt％的硅元素和不少于93.2wt％的铁元素。本发明能保证无取向电工钢具有低频低铁损性能同时有效降低高频条件下的铁损，具体铁损性能为：铁损P1.5/50≤2.35W/kg，铁损P1.0/400≤13.8W/kg。