硅钢资料

本发明公开了一种新能源汽车驱动电机用低铁损高强度无取向电工钢及其制造方法，所述无取向电工钢的化学成分及重量百分比包括C：0.001‑0.005％、Si：2.4‑3.0％、Mn：0.25‑0.5％、Al：0.70‑1.10％、P：≤0.02％、S：≤0.005％、0.015％≤Ce+Sn≤0.035％，余量为铁和不可避免的杂质，本发明通过加入Ce和Sn，净化钢质、微合金化提高无取向电工钢强度和磁性能，不需要添加固溶金属元素，且避免了高Si体系下的轧制困难问题，且不需要高温退火，解决了退火温度过高使晶粒异常长大，晶粒尺寸均匀性降低的问题，生产出的无取向电工钢具有较高强度的同时，还具有优良的磁性能。

本发明提供一种改善表面麻点缺陷的薄规格中低牌号无取向硅钢及其生产方法，成分C≤0.0025％，1.2≤Si≤1.65％，0.25％≤Mn≤0.35％，0.06％≤P≤0.11％，0.1％≤Als≤0.2％，S≤0.0025％、N≤0.0025％，Ti≤0.0025％，其余为Fe及不可避免的杂质。与现有技术相比，本发明采用较低氢气浓度，防止炉内氧化铁皮还原，减轻碳套辊的腐蚀程度，减少碳套辊结瘤率，改善带钢表面质量；采用合理合金成分设计，提高带钢的力学强度，降低碳套辊结瘤对带钢表面的影响程度，改善带钢表面质量。产品厚度为0.35mm，板面麻点发生率降低，无手感，且辊身周长周期范围内麻点个数≤5个。

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}～{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot... 

根据相关的取向电工钢典型专利技术,概述了日本高磁感低铁损取向电工钢低温板坯加热、抑制剂合理调节、关键成分Mn、C、Sn和Sb调节与利用、新型退火剂和绝缘溶液的制备及细化磁畴等生产工艺最新动态和进展情况,并提出了国内企业申请取向电工钢专利时应当借鉴之处。 According to related typical patent technology for grain-oriented electrical steel sheets,the recent trends and progress situation for production process of grain-oriented electrical steel sheets with high magnetic flux density and low core loss in Japan are summarized including low temperature slab heating,suitably regulating inhibitors,adjusting and utilizing key element Mn,C,Sn and Sb,manufacturing for new annealing agent and insulating solutions,and fining magnetic domain,and some suggestion... 

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

对CSP流程生产的高磁感无取向电工钢50W1300在偏离轧制方向不同角度处的磁性能进行了测试和分析。结果表明:在偏离轧向不同角度处,磁性能差异显著,尤其在α=60°时磁感最低;偏离轧制方向不同角度处的磁性能大小取决于织构类型、强度及分布状态;增强{100}<0vw>和α、η取向的有利织构组分,降低不利的γ取向织构组分,且使有利织构组分分布越漫散,磁各向异性越小。 Magnetic properties of high magnetic induction non-oriented electrical steel 50W1300 produced by CSP processes were investigated with different direction in relation to the rolling direction.The result shows that magnetic properties are significantly different in relation to the rolling direction,in particular,the minimum magnetic induction occurs at 60° in relation to the rolling direction.Magnetic properties of different directions in relation to rolling direction depend on type and distributi... 

对应用动态加热进行短时温度退火的取向电工钢进行了二次再结晶研究。所进行研究的实验用取向电工钢是经过终冷轧和后续罩式退火后的一条工业化生产线生产的。研究结果表明,运用短时热处理条件可引起研究钢完全的异常晶粒长大。在实验室处理的材料的织构和金相组织与工业化生产的经过终退火而获得的相同的取向电工钢类似。但是,在实验室处理的取向电工钢的二次再结晶的矩阵中可观测到\"寄生\"晶粒。从磁性观点看,这些\"寄生\"晶粒含有不理想的{111}取向织构。 The present study was made to investigate secondary recrystallization in grain-oriented steels annealed at short time temperature exposures with application of dynamical heating.The investigated GO(Grain Oriented) steels for experiments were taken from one industrial line after final cold rolling reduction and subsequent box annealing.It was shown that application of short time heat treatment conditions could lead to complete abnormal grain growth in the investigated GO steel.The texture and mic... 

【作者】 王磊； ...

本发明提供了一种无取向硅钢RH顶枪喷粉脱硫工艺，RH脱碳结束测温定氧，立即加入铝粒脱氧合金化、之后立即依次连续加入合金进行成分调整，合金加完后立即开始顶枪喷粉；加入铝粒的量＝铝粒理论加入量+0.2‑0.4kg/t钢；喷粉时，控制喷粉速度与钢液循环流量相匹配；本发明从真空条件下脱硫热力学和动力学角度出发对具有顶枪喷粉功能的RH脱硫工艺进行改进，提高脱硫率。

本发明公开了一种批量稳定生产高牌号无取向电工钢的方法，包括以下步骤：开卷→加热→水套冷却→水雾冷却→水喷淋冷却→抛丸→酸洗→切边→卷取→使用单机架六辊轧机进行轧制成卷；该方法可实现高牌号无取向电工钢在六辊UCM轧机冷轧后无边裂产生，可将带钢板形值控制在‑5I～+5I，厚度精度控制在±3μm，该方法生产的高牌号无取向电工钢无板形及表面质量缺陷，产品质量良好，可实现高牌号无取向电工钢的批量稳定轧制。

研究了CSP工艺生产≤0.005%C-1.1%Si的2.2mm无取向电工钢热轧板在800～1000℃常化对0.5mm冷轧板840℃退火后组织和磁性能的影响。结果表明,热轧板常化温度升高,冷轧板退火后的再结晶晶粒增大,铁损降低,磁感增加;热轧板常化温度超过900℃,因第二相固溶而后弥散析出,退火后冷轧晶粒细化,铁损增加,因此该无取向电工钢热轧板最佳常化温度为900℃。 The effect of normalizing at 800-1000℃ of CSP produced plate(≤0.005%C-1.1%Si) on the microstructure and magnetic properties of downstream cold-rolled non-oriented electrical steel annealed at 840℃ was studied.Results show that with increasing normalizing temperature of hot-rolled material the recrystallized grain size of annealed sheet increases,iron loss reduced and magnetic induction increases.As normalizing temperature excesses 900℃,grain is refined and iron loss increases after annealing due...