硅钢资料

本文以热轧常化板为初始材料,采用二次冷轧法与三次冷轧法制备了0.1 mm厚的取向硅钢薄带,测定相应的磁性能,并通过EBSD取向成像技术检测了二次冷轧法与三次冷轧法各工艺过程中织构与组织演变规律。结果表明,采用最终冷轧压下率适中的三次冷轧法,能在冷轧至0.1 mm时保存较多的高斯晶核,使得高温退火后的磁性能明显优于二次冷轧法。最终冷轧压下率通过影响脱碳退火后样品中的{111}<112>织构组分及Goss晶粒数量对最终二次再结晶产生重要影响。 Grain-oriented silicon steel sheets with a thickness of 0. 1 mm were produced from hot-rolled and normalized sheets by two-step-rolling and three-step-rolling methods. Their magnetic properties were measured,and the textures were detected by EBSD technique. The results show that the three-step-rolling method,which has a moderate reduction rate of final cold rolling,can maintain more { 110} < 001 >nucleus,and thus obtaining better magnetic properties compared with the two-step-method. The f... 

本发明一种解决取向硅钢热轧板晶粒粗大的方法，在取向硅钢的成分设计中减少固溶温度较高的MnS的含量，降低铸坯加热温度，同时计算实际取向硅钢成分中γ‑相含量与温度之间的关系，依据计算结果设计取向硅钢的热轧工艺，可以保证20％～30％的γ‑相数量，成功解决取向硅钢热轧板晶粒粗大的问题。

通过对辉光放电发射光谱法分析电工钢样品光谱行为的研究,分析其工作参数如:电压、电流、预溅射时间和积分时间对光谱强度和稳定性的影响,并以铁为内标元素,优化了工作参数。确定了直流辉光放电光谱法测定电工钢中碳、硅、锰、磷、硫、铬、镍、铜共8种元素的定量分析方法,并对该方法分析的精密度和准确度进行验证,结果表明,各元素的测定结果与认定值和其他方法测定值一致,测量元素结果RSD值小于2%。 Based on research on analyzing the spectrum behavior of the sample taken from the electrical steel by glow discharge optical emission spectrometry,the effect of its operational parameters such as current,voltage,pre-sputtering time and integrating time on the spectral intensity and spectral stability is analyzed.Taking the Fe as an element applied by internal standard method,these operational parameters are optimized,and therefore the quantitative analysis method for testing eight kinds of eleme... 

本发明公开了一种批量稳定生产高牌号无取向电工钢的方法，包括以下步骤：开卷→加热→水套冷却→水雾冷却→水喷淋冷却→抛丸→酸洗→切边→卷取→使用单机架六辊轧机进行轧制成卷；该方法可实现高牌号无取向电工钢在六辊UCM轧机冷轧后无边裂产生，可将带钢板形值控制在‑5I～+5I，厚度精度控制在±3μm，该方法生产的高牌号无取向电工钢无板形及表面质量缺陷，产品质量良好，可实现高牌号无取向电工钢的批量稳定轧制。

取向硅钢热轧板中织构梯度对发展完善的二次再结晶十分关键,通过添加铜可以显著降低取向硅钢板坯加热温度,从而影响热轧板织构分布。利用X射线衍射仪,分析了实验室模拟薄板坯连铸连轧(TSCR)工艺的3种不同铜含量的取向硅钢热轧板织构。结果表明:不同铜含量热轧板表面到厚度1/4处均为弱的热轧织构,热轧板心部主要为{100}面织构;铜含量约在0.4%时,热轧板次表层的{110}<001>织构比例最高,而热轧板心部的{100}<110>织构比例最低;铜含量对热轧织构中{114}<110>和{001}<100>织构发展有显著影响。 The texture gradient in hot rolled grain oriented silicon steel strip is one of the essential factors to achieve a perfect secondary recrystallization.The addition of copper can significantly reduce the slab reheating temperature of grain oriented silicon steel,so as to impact the texture distribution in the hot rolled strip.The texture of hot rolled grain oriented silicon steel strip as-rolled by thin slab casting and rolling process(TSCR) in laboratory with three different copper contents was ... 

【作者】 卢鹏； ...

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

本发明涉及一种含磷高磁感无取向硅钢的生产方法，工艺路线：铁水脱硫－转炉冶炼－RH精炼－连铸－热轧－酸洗－冷轧－连续炉退火－涂层－性能检验－包装，具体步骤包括：1)将钢水冶炼至目标成分后采用连铸方式将钢水铸成坯；2)热轧板坯加热炉均热段板坯温度950～1050℃，终轧温度控制在780～830℃，卷取温度600～680℃；3)酸洗后冷轧，控制冷轧整体压下率80％以上，至成品厚度，增加剪切带组织；4)连续退火炉快速加热段温度设定1000～1150℃，增加有利织构组织形核；均热段温度设定750～830℃，全氮气干气氛保护，退火工艺速度110～150m/min，满足晶粒度8～4级。本发明在减少硅、铝、锰合金添加量的情况下，改善铁损提高磁感性能，提高机械性能。

本发明提供了一种CSP流程生产高效冷轧无取向电工钢及生产方法，成分：C≤0.0030％、Si 1.00‑1.70％、Als≤0.0050％、Mn 0.10‑0.30％、Sn0.01‑0.3％、P≤0.050％、S≤0.0080％、N≤0.0030％、Nb≤0.0030％、V≤0.0030％、Ti≤0.0030％，其余为Fe以及不可避免的杂质。与现有技术相比，本发明CSP流程生产高效冷轧无取向电工钢的方法，通过控制钢中的化学成分，并采用合适的生产工艺，实现了表面质量优良，低铁损、高磁感、低制造成本且生产高效。

本发明提供了一种无取向硅钢RH顶枪喷粉脱硫工艺，RH脱碳结束测温定氧，立即加入铝粒脱氧合金化、之后立即依次连续加入合金进行成分调整，合金加完后立即开始顶枪喷粉；加入铝粒的量＝铝粒理论加入量+0.2‑0.4kg/t钢；喷粉时，控制喷粉速度与钢液循环流量相匹配；本发明从真空条件下脱硫热力学和动力学角度出发对具有顶枪喷粉功能的RH脱硫工艺进行改进，提高脱硫率。

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

通过对35W300高牌号0.35 mm冷轧无取向电工钢卷(/%:0.002C、2.71Si、0.22Mn、0.015P、0.003S、0.0020N、0.55Als)头、中、尾组织、织构及对应的磁性能的试验研究,发现因热轧时12 MPa高压水连续冷却造成接触轧辊的钢卷头、中、尾在不同温度下轧制,卷取后钢卷头部处于卷心、温度略高而冷却速度略低于钢卷尾部,致使钢卷纵向组织、织构不同,成品卷头、尾各250 m内磁感逐渐增加,铁损逐渐降低,250 m外至钢卷中部磁性能稳定。通过将热轧辊的冷却方式改为周期冷却和卷取后的层流冷却改为钢卷70 m后开始冷却,至钢卷尾部70 m前停止冷却的方式使得钢卷纵向铁损差异明显减小,磁感差异略有改善。 According to the test research on structure and texture of head,meddle and end of 35W300 high grade 0.35 mm cold rolled non-oriented electrical steel strip coil(/%:0.002C,2.71Si,0.22Mn,0.015P,0.003S,0.002 0 N,0.55Als) and corresponding magnetic properties,It is found that due to 12 MPa high pressure water continuous cooling the roller in hot rolling process led to head,middle and tail of strip rolling at different temperature and after coiling the head of strip coil being in center of coil led t...