硅钢资料

本发明涉及冶金技术领域，具体涉及一种高牌号硅钢用连铸结晶器保护渣及其制备方法和应用。本发明提供的连铸结晶器保护渣，所述保护渣包括如下质量百分比的化学成分：SiO2：40‑45％、CaO：20‑27％、MgO：1.0‑2.5％、Al2O3：1‑3％、Na2O：12‑16％、F：10‑13％、C：1‑3％，其余为不可避免的杂质；其中所述保护渣的二元碱度CaO/SiO2为0.5‑0.6，熔点为950‑1000℃，1300℃下的粘度为0.25‑0.35Pa·s。本发明提供的连铸结晶器保护渣，通过低碱度、低熔点、低粘度的保护渣可有效抑制高牌号硅钢材料在连铸时铸坯表面易出现凹陷和裂纹的现象。

本发明涉及一种超纯净无取向冷轧硅钢中非金属夹杂物形貌的原位观察方法，包括如下步骤：制备无取向冷轧硅钢样品，将待测试面用打磨至1000#，使样品表面平整光滑，并进行机械抛光和表面清洗。对处理好的样品在电化学工作站上进行电化学腐蚀，电解液为：1~8wt%氯化物MCl溶液，余量为去离子水，通入CO2气体至饱和，加入适量NaHCO3和三乙醇胺作为稳定剂调节pH值将其稳定在6.0~6.5之间。电化学设定参数：开路：0.5~2h，动电位极化测试：扫描速率:0.1mV/S~1.0mV/S，测试区间：VS.SCE‑0.8V~0.2V，测试温度为：10~25℃。取不同区间内做完电化学腐蚀的样品用去离子水冲洗，吹干。通过扫描电子显微镜+能谱仪对非金属夹杂物的形貌进行原位观察和成分分析。

结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte... 

介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including... 

对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550～650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550～650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin... 

一种硅钢生产线退火炉前的换热装置，包含有抽风机（1）、立柱（2）、热交换器（3）、软管（4）和热风机（5）；其特征在于：所述的热交换器（3）由若干组U形不锈钢管连接而成，一端固定在轴套（8）上，另一端通过链条（10）连接在立柱（2）顶端的链条盘（9）上，当链条盘（9）转动时，链条（10）拉动热交换器（3）绕着横轴（7）抬起或放下。本实用新型通过抽风机（1）将清洁空气抽到热交换器（3）内进行加热，然后再通过软管（4）将热空气输送到热风机（5）内来加热硅钢板（14），有效的利用了热能，避免了凝露导致的板面发蓝现象。

为进行磷酸盐系无铬无取向硅钢涂层烧结固化工艺研究,首先对磷酸盐系无铬无取向硅钢涂层进行热重-差示扫描量热(TG-DSC)分析;然后在不同烧结固化温度条件下,测定涂层板温随时间变化曲线;最终获得涂层烧结固化温度与时间(T-t)工艺曲线。通过中性盐雾试验、动电位极化、交流阻抗、涂层附着力以及扫描电子显微镜(SEM)和能谱(EDS)分析验证。结果表明,根据涂层烧结固化温度与时间(T-t)工艺曲线制备的涂层结构致密、性能优异,证明该工艺曲线具有合理性与正确性。 In order to study the curing process of chromium-free non-oriented silicon steel coatings,phosphatic chromium-free non-oriented silicon steel insulating coating was prepared and TG-DSC analysis of the coating was conducted,then the change of the actual temperature of the coated non-oriented silicon steel sheet with time at different curing temperatures was studied. Based on the experiments,the processing curves of curing temperature vs. curing time( T-t) for the chromium-free non-oriented silico... 

取向硅钢利用析出物作为抑制剂,抑制初次再结晶晶粒的长大,抑制剂是取向硅钢发生二次再结晶的基本条件之一。文中通过低温板坯加热技术制备取向硅钢,采用透射电镜(TEM)观察并研究了高温退火阶段抑制剂的演化过程。结果表明,渗氮后形成的非晶态Si3N4析出物不稳定,在700～750℃退火升温阶段转化为(Al,Si)N;(Al,Si)N颗粒在800℃发生团聚,随后长大并粗化;(Al,Si)N是低温取向硅钢主要抑制剂,随退火温度的升高,(Al,Si)N抑制力大幅下降。 Precipitates as inhibitor are used to inhibit the grain growth of primary recrystallization in grain-oriented silicon steel,and inhibitor is one of the basic conditions for occurring of secondary recrystallization.The grain-oriented silicon steel was produced by low temperature slab heating and nitriding technique.The evolution of inhibitor was observed by transmission electron microscopy.The results show that Si3N4 particles are precipitated after nitriding,and Si3N4 particles are amorphous and... 

采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e... 

本实用新型涉及一种硅钢片叠装上料用转运装置，包括一输送单元，输送单元包括输送支架、输送辊，在各个输送支架均配备有一用于接收裁切好的硅钢片并堆放形成硅钢片料堆的放置板；一供料单元，包括供料板、供料支架、供料辊、支撑组件；一转运单元，包括转运支架、转运底座、转运辊、推料板、推动机构、电磁铁、转运齿条、转运齿轮、转运导轨、转运导座、导向轮、行走滚轮。本实用新型的优点在于：通过输送单元、供料单元及转运单元之间的相互配合，从而能够将满料的放置板自动输送并呈日字形自动排布好，无需再由人工搬运放置，大大减少了人工劳动，降低了人工劳动强度。

一种硅钢厂调功器故障报警自动复位的方法，包括：通过人机界面对炼钢炉温度进行设定，并在炼钢过程中实时获取炼钢炉温度；将炼钢炉实时温度与设定温度进行对比，当炼钢炉实时温度低于设定温度时，启动调节器；调节器输出功率使电阻带加热，使炼钢炉实时温度达到设定温度；当调节器发生故障时，调节器将故障信号发送给后台服务器，后台服务器根据故障指令，按预设规则控制与调节器连接的继电器，控制继电器按压复位按钮，使调节器自动复位。本发明解决了现有技术中通过电气人员来通过复位消除故障状态，耽误时间长，容易产生废品的问题。

选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase...