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利用DSC、XRD,结合热焓分析对硅钢级氧化镁和二氧化硅的固相反应行为进行了研究。比较了不同二氧化硅原料及混合方法对硅钢级氧化镁反应性的影响,找到了一种更为有效的硅钢级氧化镁反应性的评估方法,克服了传统柠檬酸活性法在比较不同厂家生产的氧化镁的反应性上的局限性。进一步研究了Na2B4O7添加剂、TiO2添加剂对氧化镁和二氧化硅反应行为的影响,结果表明,Na2B4O7添加剂含量的增加对反应有利,而TiO2添加剂对反应有阻碍作用。 The solid-state reaction behavior between silicon-steel grade MgO and SiO2 was investigated by DSC and XRD combined with enthalpimetric analysis.The influence of different kinds of SiO2 and different preparation methods were studied and a specifical measurement that is more reliable was proposed to evaluate reactivity of silicon steel grade MgO.It overcomes the limitation of the traditional citric acid activity(CAA) method,which can not be used to evaluate the reactivity of... 
2014-03-28 169 5.8

结合工业化生产的无取向硅钢,进行了RH精炼添加稀土合金实验。结果表明,1.15%(质量分数)Si钢的脱硫反应,主要发生在添加稀土合金之后的前5min。最佳的稀土合金添加量为0.6~0.9kg/t钢。钢液经过稀土处理后,加入的稀土总量越多,稀土氧硫化物夹杂物的尺寸就越大,但热轧带钢再结晶效果会逐渐变差,成品带钢晶粒尺寸先是快速长大,而后逐渐减小。最佳的钢中存留稀土含量与钢的化学成分有关,应严格控制在2.0×10-3%~6.0×10-3%(质量分数)。在此范围内,钢的铁损先是快速降低,而后缓慢升高,钢的磁感应强度则单调降低。 Based on the industrial production of non-oriented electrical steel,rare earth(RE) alloy treatment during the RH refining process was studied.The results showed that the effects of desulfurization and total concentration of RE remained in steel mainly depended on the chemical compositions of different steel grades.For 1.15wt% Si steel grade,the desulfurization reaction mainly focused on the initial 5min after RE alloy added during the RH refining process.The suitable RE alloy addition was 0.6-0.... 
2013-07-28 193 5.8

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 
2014-05-28 181 5.8

本发明公开了一种硅钢环形炉内罩的内圆直径自动检测装置及方法,该内圆直径自动检测装置包括设置在检测点地面上的水平工作台,设置在所述水平工作台上的水平调节机构,设置在所述水平工作台上的扫描机构,以及与所述扫描机构通信互联的检测处理机构。该内圆直径自动检测装置是非接触式设备,不受内罩温度的限制,使用方便灵活,设备可靠性好,安全性高,对环境无污染,不仅能够有效节约校圆机的使用频次,而且大大增强了炉子的安全可靠性。
2021-03-25 161 6.8

对碳-锰-硅钢进行不同配分温度的Q&P(Quenching and Partitioning)处理,测试了热处理后不同钢的力学性能和残余奥氏体含量,并用扫描电子显微镜和透射电镜观察其显微组织,分析了配分温度对显微组织和力学性能的影响。结果表明:试验钢显微组织基本由低碳板条状马氏体、块状铁素体和条状残余奥氏体组成;随配分温度的升高,试验钢的抗拉强度呈下降趋势,伸长率与奥氏体含量的变化趋势相同,但变化规律不确定;提高锰含量能稳定残余奥氏体,从而提高试验钢的伸长率,并使伸长率对配分温度不敏感。 The C-Mn-Si steel was quenched and partitioned at different partitioning temperatures,the mechanical properties and residual austenite contents were investigated,the microstructure was observed by SEM and TEM,and the effect of partitioning temperature on microstructure and mechanical properties was analyzed.The results show that the microstructure of the tested steel consisted of lath martensite with low carbon,nubby ferrite and banded residual austenite.The tensile strength of the tested steel ... 
2011-09-28 176 5.8

采用电解法和扫描电镜研究了300 t转炉-RH精炼钙处理对无取向硅钢板(%:≤0.005C、1.2~2.2Si、0.2~0.6Mn、≤0.20P、≤0.005S、0.2~0.6Al、0~0.01Ca)中夹杂物的影响。结果表明,钢中Al含量为0.25%和0.35%时,钢中溶解氧均小于1×10-4%,钙处理后都会产生CaS夹杂物,尤其是含0.35%Al的钢水;钙处理可以有效减少钢中的夹杂物数量,尤其是0.5μm以下的微细夹杂物数量;钙处理后夹杂物的种类以AlN、CaS为主,同时还含有少量的氧化物夹杂物以及AlN-CaS复合夹杂物,尺寸主要为1.5~5.0μm。 The effect of 300 t converter-RH refining calcium treatment on inclusions in non-oriented silicon steel sheet (%:≤0.005C,1.2~2.2Si,0.2~0.6Mn,≤0.20P,≤0.005S,0.2~0.6A1,0~0.01Ca) has been studied by electrolysis and scanning electron microscope.Results show that with 0.25%and 0.35%Al content in steel,all the dissolved oxygen in liquid is less than 1×10-4%,and the CaS inclusions are produced after calcium treatment,especial for the liquid containing 0.35%Al;the amount of inclusions in ste... 
2011-01-28 203 5.8

本发明公开了一种免常化中间退火的无取向电工钢板,其各化学元素质量百分含量为:0<C≤0.004%、Si:1.0~2.6%、Mn:0.2~1.0%、Al:0.2~1.6%、Ca:0.0003%~0.0035%,余量为Fe和其他不可避免的杂质。此外本发明还公开了上述无取向电工钢板的制造方法,其包括步骤:(1)冶炼和连铸,其中在该步骤不采用电磁搅拌;(2)热轧,其包括:粗轧、精轧、卷取和保温;其中控制粗轧之后、精轧之前的中间坯温度≥950℃;(3)上述热轧步骤后不进行常化中间退火或罩式炉中间退火而直接进行冷轧;(4)连续退火。本发明所述的无取向电工钢板通过采用合理的化学成分和工艺设计,可以在保证较低生产成本的同时,获得高磁感和低铁损的特性。
2021-04-09 211 6.8

研究表明,硅钢中的夹杂物对成品带钢的磁性能有显著影响。为研究冶炼过程硅钢中的夹杂物遗传变化,进而提出更有效的控制措施加以去除,本文结合典型的无取向硅钢生产炉次,采用非水溶液电解提取+扫描电镜观察方法分析冶炼过程中上述炉次典型试样的夹杂物。结果表明:转炉冶炼结束、RH精炼开始时,钢的氧化物夹杂总量最大,约为0.23%;RH精炼过程中,氧化物夹杂总量不断降低,并在脱碳结束时达到最低,约为0.02%;连铸过程中,氧化物夹杂总量仍有不断降低趋势,但夹杂物的平均尺寸变化不大。本试验条件下,中间包试样的夹杂物数量约为1.59×104个/mm3。 As we all know, the non-metallic inclusion effects magnetic properties of silicon steel sheets obviously. The article aims to study the heredity of non-metallic inclusion in non-oriented silicon steels during the steel making process, and then provides a more effective controlling measure to remove the inclusions. Based on the typical non-oriented silicon steel charges, the non-aqueous solution extraction and SEM observation were adopted to analyze the non-metallic inclusions. Results show that,... 
2014-05-28 189 5.8

结合工业化生产的高效硅钢,进行了RH精炼稀土处理试验研究。针对不同的稀土处理条件,观察了夹杂物的形貌和尺寸分布,探讨了稀土处理后钢中的夹杂物形成、变化规律。结果表明:试验条件下,最佳的稀土合金添加数量为0.6~0.9 kg/t。经过合适的稀土处理后,可以有效抑制尺寸相对较小的、不规则的AlN、MnS复合夹杂生成,促进钢中微细夹杂物的聚合、上浮,钢质纯净度得到明显提高。此时,钢中全氧含量最低,脱硫效果最佳,钢中的夹杂物主要是尺寸相对较大的、近似球形或者椭球形的稀土类夹杂。 Based on the industrial production of non-oriented silicon steel,the experiment on RE treatment during the RH refining process was studied.The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions.Further more,the formation and change of inclusions of final steel sheets after RE treatment were discussed.The results show that the suitable RE added amount was 0.6~0.9 kg/t.After the suitable RE treatment,the formation of AlN and Mn... 
2011-03-28 215 5.8

本发明公开了一种利用取向硅钢氧化镁废弃物生产镁质球团的方法,采用取向硅钢生产过程中的废氧化镁污泥、废氧化镁粉等氧化镁废弃物,以及粗粒铁矿粉、镜像赤铁矿、磁铁精矿、膨润土和石灰石粉为原料,依次经预处理、配料、造球后,再在链箅机‑回转窑‑环冷机上进行干燥预热、焙烧和冷却,得到镁质球团。本发明利用氧化镁废弃物制备镁质球团,既有利于减少氧化镁废弃物带来的环保压力及其外运时产生的处置费用,也能显著降低镁质球团的制造成本,综合利用了钢铁厂的现有资源,生产出环境友好、低成本的镁质球团,为高炉提供优质原料,最终降低炼铁过程的污染物排放,减少环境污染。
2021-01-15 147 6.8

本发明公开一种表面状态良好的无取向电工钢板,其含有Fe和不可避免的杂质,其还含有质量百分含量如下的下述各化学元素:0<C≤0.005%,Si:1.0~2.0%,Mn:0.2~1.0%,Al:0.2~1.0%,Ca:0.0003~0.010%,Sb:0.005~0.2%,其中Si+Al:1.4~2.6%。此外,本发明还公开了一种上述的无取向电工钢板的制造方法,其包括步骤:(1)冶炼;(2)铸造:控制连铸坯在连铸机出口位置处的表面温度≥780℃,以使得连铸坯在其厚度方向上与宽度方向上的晶粒尺寸之比为2.5~6.0;(3)热轧:在热轧粗轧结束之后,控制中间坯头尾温度之差≤25℃;(4)冷轧;(5)连续退火。该表面状态良好的无取向电工钢板无瓦楞缺陷,其具有较低的铁损以及优良的磁感,其具有十分良好的推广前景和应用价值。
2021-08-09 159 6.8

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