硅钢资料

本发明属于涂料技术领域，具体涉及一种用于硅钢水性无机绝缘涂料的助剂及其制备方法，用于硅钢水性无机绝缘涂料的助剂，包括以下质量份配比的材料：磷酸二氢铝溶液10‑40份、氧化镁0.1‑5份、增稠剂0.01‑5份和水1‑80份。本发明还提供了上述助剂的制备方法，通过向磷酸二氢铝溶液中加入氧化镁悬浮液，得到铝镁混合液备用，然后在室温及搅拌条件下，向铝镁混合液中加入增稠剂预溶胶得到所需助剂，利用本申请的助剂制备了无机物料，结果表明，本发明提供的助剂适用于硅钢水性无机绝缘涂料，能改善涂料的稳定性，有效提高硅钢绝缘涂层的附着力和耐腐蚀性，改善硅钢涂层的综合性能。

为进行磷酸盐系无铬无取向硅钢涂层烧结固化工艺研究,首先对磷酸盐系无铬无取向硅钢涂层进行热重-差示扫描量热(TG-DSC)分析;然后在不同烧结固化温度条件下,测定涂层板温随时间变化曲线;最终获得涂层烧结固化温度与时间(T-t)工艺曲线。通过中性盐雾试验、动电位极化、交流阻抗、涂层附着力以及扫描电子显微镜(SEM)和能谱(EDS)分析验证。结果表明,根据涂层烧结固化温度与时间(T-t)工艺曲线制备的涂层结构致密、性能优异,证明该工艺曲线具有合理性与正确性。 In order to study the curing process of chromium-free non-oriented silicon steel coatings,phosphatic chromium-free non-oriented silicon steel insulating coating was prepared and TG-DSC analysis of the coating was conducted,then the change of the actual temperature of the coated non-oriented silicon steel sheet with time at different curing temperatures was studied. Based on the experiments,the processing curves of curing temperature vs. curing time( T-t) for the chromium-free non-oriented silico... 

利用背散射衍射技术(EBSD)和XRD,研究了两段式脱碳退火工艺对取向硅钢纵截面初次再结晶的微区取向、取向差分布、特殊晶界(CSL)及高温退火试样高斯织构。分析了初次再结晶晶界特征对取向硅钢高温退火后宏观织构的影响。结果表明:初次再结晶的纵截面基体中Σ3和Σ5晶界使得高斯晶粒有着较高的迁移率,在高温退火时借助20o～45°的大角度晶界的界面能吞并周围{111}<112>晶粒迅速长大,形成密度水平较高的高斯织构。 Micro area orientation of primary recrystallization,the misorientation distribution,special boundaries under different two-stage decarburization annealing and the Goss texture under high temperature annealing the longitudinal section of grain-oriented silicon steel were detected by electron back scattering diffraction(EBSD) and X-ray diffraction(XRD).The effect of primary recrystallization grain boundary on macrotexture after high temperature annealing was analyzed.The results show that the Σ3 a... 

本发明公开了叠片装置，以及采用该叠片装置的硅钢片收料设备，包括分料装置和本发明第一方面实施例的叠片装置，分料装置包括有分料件、上分料传送带和下分料传送带，上分料传送带的一端和下分料传送带的一端与分料件连接，分料件用于将硅钢片分别输送至上分料传送带和下分料传送带，本发明第一方面实施例的叠片装置，叠片装置的数量为两个，两个叠片装置上下平行设置，并且分别与上分料传送带和下分料传送带的远离分料件的一端连接。根据本发明的叠片装置，以及采用该叠片装置的硅钢片收料设备，可实现硅钢片的自动叠片，提高生产效率。

结合工业化生产过程中出现的同卷带钢头、尾磁性能差异现象,对50SW1300牌号无取向硅钢同卷带钢头、尾试样的夹杂物、晶体织构和显微组织进行了分析研究。结果表明,夹杂物、晶体织构是影响成品钢卷磁性能的重要因素。夹杂物是造成同卷带钢头、尾铁损差异的主要原因。夹杂物数量越多,尤其是小尺寸的夹杂物数量越多,对成品带钢的磁性能影响越大,对于本试验而言,AlN和MnS是影响成品带钢磁性能的主要夹杂物。晶体织构是造成同卷带钢头、尾磁感应强度差异的主要原因。有益的{100}和Goss织构含量越大,有害的{111}<110>和{111}<112>织构含量越小,即有益织构与有害织构含量比越大,成品带钢的磁感应强度越大。 Based on the industrial manufacture of non-oriented silicon steel sheets 50SW1300, the magnetic property variation of head and tail of the same finished steel sheets was discussed by analyzing non-metallic inclusion, crystal texture, and microstructure. Results show that, both of the non-metallic inclusion and the crystal texture will affect the magnetic properties significantly. The non-metallic inclusion is the key factor of the core loss variation of head and tail of the same finished steel s... 

利用光学显微镜（OM）和扫描电镜（SEM）研究了不同稀土Ce含量的50W470无取向硅钢的铸坯、热轧板和冷轧退火板的宏观和微观组织，并采用磁性能测试仪测定其磁性能。结果表明：当稀土Ce的加入量从0增加到66×10^-6（质量分数）时，铸坯的柱状晶平均宽度从3.82 mm减小到3.24 mm,等轴晶率从43.1%增加到51.3%;热轧板的平均晶粒尺寸逐渐增加，从26.2μm增加到33.3μm,再结晶百分数从24%增加到37%;退火板的平均晶粒尺寸从36.2μm增加到39.3μm;磁性能测试表明，微观组织的变化有利于50W470无取向硅钢铁损降低和磁感提高。 Macro-structure and microstructure of as-cast plate, hot rolled plate and cold rolled annealed plate of 50 W470 non-oriented silicon steel with different rare earth Ce content was studied by optical microscope（OM） and scanning electron microscopy（SEM）, and their magnetic properties were measured by magnetic property tester. The results show that when the addition amount of rare earth Ce increases from 0 to 66×10^-6（mass fraction）, the average width of columnar crystal of the as-cast pl... 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

本发明属于酸洗设备技术领域，具体涉及一种硅钢生产用酸洗设备，包括酸洗池、放卷机构和收卷机构，酸洗池被依次分隔为第一酸洗腔、第二酸洗腔、浸泡腔和喷洗腔；第一酸洗腔和第二酸洗腔内滑动连接有刷洗架，浸泡腔内滑动连接有定位架，喷洗腔内滑动连接有喷洗架；刷洗架、定位架和喷洗架上均转动连接有多根转辊，转辊上设有刷毛；刷洗架和喷洗架上设有用于驱动转辊转动的驱动件；喷洗架上的转辊开有空腔和多个与空腔连通的喷孔，喷洗架上开有与空腔连通的通道和与通道连通的进水口；喷洗腔的底部和侧壁设有多个喷头；酸洗池内转动连接有多根位于第一隔墙上方的刷辊。在本方案，通过酸洗以及充分的刷洗，能够充分有效的除去硅钢表面的氧化皮。

采用双辊连铸工艺制备了硅的质量分数分别为0.5%,1.0%,3.0%,4.5%的硅钢薄带,用光学显微镜观察其组织,并研究了后处理工艺对薄带组织和性能的影响。结果表明:硅含量为0.5%和1.0%的薄带适合采用一次冷轧+850～950℃退火的后处理工艺,而硅含量在3.0%以上的薄带适合采用二次冷轧+950℃退火的后处理工艺;硅含量为3.0%和4.5%的薄带在冷轧并950℃退火后,其磁性能最佳,铁芯损耗约为4.30 W·kg^-1,磁感应强度约为1.68T。 Silicon steel thin strips with silicon content of 0.5wt%,1.0wt%,3.0wt%and 4.5wt%were prepared by twin-roll continuous casting process,and the microstructure of the strips were observed by means of optical microscopy,and on the basis,the effect of post-treatment process on microstructure and properties of the strips was studied.The results show that the post-treatment process of one-time cold rolling and annealing between 850—950℃was suitable for the strips with silicon content of 0.5wt%and 1.0wt... 

本实用新型公开了一种用于硅钢绝缘涂料生产的吸尘装置，包括底板、支撑平台和集尘箱，所述底板底端四角处通过螺栓连接固定有可制动万向轮，所述底板上端四角处焊接有导向套。有益效果在于：本实用新型通过设置真空泵、集尘箱、万向吸气臂、吸尘罩以及活性炭滤网，可在硅钢绝缘涂料生产过程中将逸出的物料粉尘进行有效的收集，确保硅钢绝缘涂料生产环境的洁净，有利于人体健康，通过设置电机、螺套、螺杆、导向柱以及导向套，可实现根据实际吸尘的需要实现装置高度的便捷调节，提高了装置的实用性。

对低温加热工艺生产的以AlN为主抑制剂的高磁感取向硅钢高温退火过程进行中断实验,借助电子背散射衍射技术对高温退火过程中高斯晶粒的演变进行了研究.在升温过程中高斯晶粒平均尺寸先减小再增大.800℃时取向分布函数图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;900℃时高斯晶粒平均生长速率超过其他晶粒;950~1000℃时高斯晶粒异常长大,偏离角3°~6°;在1000℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势. The high-temperature annealing process of high permeability grain-oriented silicon steel with AlN as an inhibitor was studied by interrupting test.The evolution of Goss texture in this process was analyzed by electron back-scattered diffraction.It is found that the Goss grain size first decreases and then increases with the rise of temperature.Goss texture appears in the orientation distribution function at 800 ℃,but the intensity is very weak and the deviation angle is more than 10°.The average... 

介绍了双蓄热燃烧技术的特点和高温硅钢加热炉的特点,探讨了双蓄热燃烧技术在高温硅钢加热炉中使用的技术难点,分析了双蓄热燃烧技术在高温硅钢加热炉上使用的可能性。 Introduced characteristics of double regenerative combustion technology and high temperature silicon steel reheating furnace,discussed technical difficulties for using double regenerative combustion technology,analyzed the possibility of double regenerative combustion technology applied to high temperature silicon steel reheating furnace.