硅钢资料

本发明公开了一种物理喷砂方式制备取向硅钢薄带无底层原料的方法，步骤包括：S1、坯料预处理；S2、涂覆隔离剂，后进行高温退火；S3、拉伸热平整；S4、表面喷砂处理，去除底层；S5、去应力退火；本发明优点在于，采用喷砂的物理办法制备取向硅钢薄带无底层原料，代替了传统的用酸去除取向硅钢涂层或硅酸镁底层，结合退火去应力，显著改善了加工质量，使整个加工过程更加环保，也有利于控制成本。

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r... 

通过实验室25 kg真空感应炉冶炼和锻轧研究了0.26%～0.95%Al含量对0.5 mm 2.2%Si无取向硅钢冷轧板组织、织构和磁性能的影响。试验结果表明,0.26%～0.81%Al含量时,随钢中Al含量的增加,成品退火钢板的晶粒尺寸增加同时铁损减少;当Al含量大于0.81%时,随Al含量增加,钢板的晶粒尺寸减小,同时铁损增加。Al含量对硅钢板磁感的影响没有明显的规律。2.2%Si无取向硅钢的合适Al含量为0.48%～0.81%。 The effect of 0.26%～0.95%Al content on structure,texture and magnetic performance of 0.5 mm cold rolled sheet of 2.2%Si non-oriented silicon steel has been studied by a 25 kg vacuum induction furnace smelting,and forging -rolling in laboratory.Results show that as 0.26%～0.81%Al,with increasing Al content in steel the grain size of annealed finished sheet increases while iron loss of sheet decreases,and as Al content in steel is more than 0.81%,the grain size of sheet decreases while iron loss in... 

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

本实用新型公开了一种硅钢片绝缘测试装置，包括检测箱体、固定调节装置、探测装置和绝缘探测仪，所述固定调节装置、探测装置和绝缘探测仪设于检测箱体内，固定调节装置包括底座、支撑杆、放置板、夹板和夹持螺杆，所述支撑杆设于底座上，支撑杆上设有旋转腔，旋转腔内设有旋转电机，放置板旋转设于旋转腔上，旋转电机输出端设于放置板上，所述夹板滑动设于放置板两侧，夹持螺杆旋转设于放置板上；本实用新型属于绝缘测试领域，具体是一种通过固定调节装置可将硅钢片夹持固定，便于不同位置的调节，通过探测装置进行探测，并通过绝缘探测仪的检测于控制计算机将数据呈现和计算，减少手动操作，提高安全性的硅钢片绝缘测试装置。

本发明提供了一种高硅钢及其制备方法，所述高硅钢由如下质量分数的化学成分组成：Si：5.0‑7.0％，Ni：0.001‑0.05％，Ce：0.0001‑0.0002％，其余为Fe和不可避免的杂质。本发明提供的高硅钢的延伸率为15‑22％，抗拉强度为739‑824MPa，磁感应强度B8为1.26‑1.29T，铁损P2/10k＝68‑80W/kg，矫顽力为10.6‑13.4/m，最大磁导率为19000‑25000，具有良好的磁性能和延伸性能，易加工且可大规模生产应用。

本发明属于硅钢制备技术领域，具体涉及一种无底层取向硅钢的制备方法。其中，所述脱碳退火的过程中，带钢表层的氧化膜厚度为1.5～2.5μm；所述氧化膜中Si元素和Fe元素的原子重量比满足：Si/(Si+Fe)≥0.76；所述高温退火的过程中，冷却段依次包括：在温度为1200～500℃时，罩内冷却；其中，保护气体为包括有氮气和氢气的混合气体，所述混合气体中氢气的体积百分比＞3％；在温度为500～200℃时，罩内冷却；其中，保护气体为氮气；在温度＜200℃时，揭开内罩进行空气冷却。本发明提供的无底层取向硅钢的制备方法中，通过控制带钢在脱碳退火阶段的氧化膜厚度以及高温退火的冷却段等一些工艺，从而得到了表面光洁化好、表面均质化好、成材率高、磁性能优良的无底层取向硅钢。

研究了取向硅钢制备过程中常见的两种冷轧工艺,主要研究了一阶段冷轧与两阶段冷轧+中间退火工艺对初次再结晶组织及织构的影响.结果表明:采用两阶段冷轧+中间退火工艺制备以Cu2S为主抑制剂的取向硅钢,其初次再结晶平均晶粒尺寸为18.1μm,高斯晶粒的体积分数为0.6%,迁移性强的重位点阵晶界(Σ5+Σ9)和高能晶界(20°~45°取向偏差角)所占比例分别为1.8%和50.4%.与一阶段冷轧工艺相比,其初次再结晶晶粒较细,且高斯晶核与特征晶界所占的比例较高,有利于高斯晶粒发生二次再结晶. Two common cold-rolling processes of grain oriented silicon steel and the effects of the single stage cold rolling and tw o-stage cold rolling w ith intermediate annealing processes on the primary recrystallization microstructure and texture w ere investigated. The results revealed that for the grain oriented silicon steel prepared under the tw o-stage cold rolling process w ith intermediate annealing w ith Cu 2 S as the main inhibitor,the average grain size of the primary recrystallization micr... 

对硅钢板材分别进行异步和同步轧制,研究了轧制参数包括速比、压下量和道次对板材表面显微组织的演变的作用.结果表明,异步轧制硅钢板材表面形成了晶粒尺寸为10~50 nm,取向接近随机分布的纳米晶,而同步轧制板材的表面只形成了位错胞,证明异步轧制可以诱发表面纳米化.异步轧制板材表面纳米晶的形成过程为:在剪切力的反复作用下,高密度位错形成、滑移、湮灭和重组形成亚微米尺度的亚微晶/位错胞.随着压下量和轧制道次增加,高密度位错重复以上过程使晶粒尺寸减小、取向差增大,最终形成取向接近随机分布的纳米晶组织.大压下量和多道次是异步轧制诱发板材表面纳米化的关键,而速比的增加可以加快纳米化进程. Surface nanocrystallization(SNC) can effectively enhance the surface and global properties of the metallic materials,such as microhardness,intensity,fatigue,wear and corrosion resistances,therefore provides more promising practical industrial applicability.Up to now,several SNC treatment methods were developed based either on the principles of ball impactions or friction sliding,however,difficulty still exists for the surface treatment of large-dimensional samples with high efficiency.Recently,m... 

针对某硅钢车间ST机组的除尘系统除尘效率较低、排放浓度不达标、二次污染较严重的问题,通过现场调研,对除尘系统、含尘气体组分与物性参数等进行测试和分析,运用管道伴热技术改善粉尘黏性后,再选取合适的除尘器对粉尘进行除尘处理,大大地提高了系统的除尘效率。 To solve the problems of low dust removal efficiency, substandard emission concentration and severe secondary pollution, some investigations are conducted to test and analyze the dust removal system,dust-gas composition and relevant physical parameters.Moreover, dust removal efficiency is greatly improved by the use of pipe heat tracing technology and by choosing appropriate dust remover. 

本发明涉及涂层液技术领域，且公开了取向硅钢绝缘涂层液，其配比为：二氧化硅10‑15%、硼酸5‑8%、磷酸二氢盐2‑5%、金属溶胶20‑25%、氢氧化铝占5‑6%、有机酸处理的复合盐溶液20‑30%、分散剂0.5‑1%，其余为水，采用硅溶胶作为辅助成膜物，粘结力较强，对附着性影响很大。硅溶胶能够很均匀地包裹在被胶结物质的表面，通过自干成膜，保持了很高的常温结合强度；而磷酸盐涂层的固化是通过受热分解，脱水聚合完成的，低温强度差，中温强度高，充分利用了硅溶胶低温的结合强度和磷酸盐中、高温时的结合性能，消除了常规涂层烘烤时容易出现的收缩、起泡现象，阻止了微气孔的形成，提高了涂层的表面光滑度，粘结强度和稳定性同时保持绝缘涂层的光泽、光滑和稳定性。