硅钢资料

研究了冷轧95%变形量无取向硅钢不同退火温度(710～1 050℃)下再结晶织构特征.再结晶刚完成时(710℃退火),呈现强γ({111<112>～<134>)与弱{114}<481>织构特征;随退火温度升高至900℃,γ明显减弱,{114}<481>组分持续增强,形成典型的{h,1,1}<1/h,1,2>织构;进一步升温至1 050℃,再结晶织构不再发生明显变化.基于EBSD分析,{114}<481>组分的持续强化可归因于其明显的尺寸优势以及较高频率的高能晶界(取向差角为20°～45°). A non-oriented silicon steel was heavily rolled to 95% reduction and subsequently annealed at 710~1 050 ℃ to investigate recrystallization texture evolution.When annealed at 710 ℃ with complete recrystallization,the texture is characterized by a strong partial γ fiber spreading from {111}<112> to {111}<134> and a weak {114}<481> component.As annealing at 900 ℃,γ fiber is decreased significantly while {114}<481> is increased consistently,producing a typical {h,1,1}<1/h,... 

本发明涉及取向硅钢技术领域，且公开了包括以下步骤：步骤一：冶炼，冶炼经转炉和RH精炼后得到钢水，在进行冶炼的过程中通入空气并设置总进气量100‑300Nl/min，且通入的空气中氧含量为20‑21％之间。该磁性优良的高磁感取向硅钢的气氛控制工艺，通过在不同的流程中，加入一定配比的氧气和氮气的含量，有效的提升每个阶段的气氛控制精度，从而得到最终的高磁感取向硅钢达到优良，避免了因气压、流量等因素影响最终高磁感取向硅钢磁力效果，炉渣中FeO含量减少，提高钢回收率和炉衬寿命，进而也起到降低生产成本的效果，且进行精确的气氛控制，使得在进行高磁感取向硅钢的冶炼中，使得冶炼的效果更好，使得冶炼出来的高磁感取向硅钢的磁性更加的优良。

本实用新型公开了E字型硅钢片的级进模冲压装置，属于冲压模具设备领域，所述下模具包括与冲孔凸模、冲方孔凸模、切断凸模分别对应且相适配的冲孔凹模、冲方孔凹模、切断凹模，所述上模具上设有对条料板进行输送的导料板，所述冲孔凸模、冲孔凹模均设有两对并且并排设置，且每对冲孔凸模、冲孔凹模均设有两个，每个所述冲孔凸模、冲方孔凸模、切断凸模的顶端均用微米级间隙固定安装于上模具上，所述冲孔凹模、冲方孔凹模、切断凹模的底端均用微米级间隙固定安装在下模具上。本实用新型中各个凸、凹模分别采用硬质合金拼块、镶块式的结构并用微米级间隙固定安装在上、下模具上，这样不仅可节省材料的费用，同时还便于人们后期对模具的维修和使用。

试验了通过NaCl-KCl-NaF-SiO₂熔盐在电流密度50 mA/cm²、电沉积脉冲电流正反向比9:1和750⁸50℃60min电沉积下阴极（/mm）20×20×0.5的1.6Si无取向冷轧硅钢片断面层硅的分布,并通过计算得出Si的扩散系数。结果表明,电沉积温度由750℃提高至850℃时,试样中Si含量增加,扩散的深度由18μm提高到40μm;电沉积温度与Si在钢中的扩散系数近似符合Arrhenius指数关系。 The distribution of silicon at cross section of cathode（/mm） 20 × 20 × 0.5 sheet of 1.6Si non-oriented cold rolled silicon steel after electro-deposit treatment by NaCl-KCl-NaF-SiO₂ molten salt with current intensity 50 mA/cm²,electro-deposit pulse current positive-negative ratio 9:1 at 750 850 ℃ for 60 min has been tested and the diffusion coefficient of Si is obtained by calculation.Results show that with increasing electro-deposit temperature from 750 ℃ to 85... 

阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili... 

通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p... 

本发明公开了一种超高效变频空调压缩机用无取向硅钢薄带及其制造方法，属于无取向硅钢技术领域。本发明包括以下重量百分比的组分：C≤0.003％，Si：2.0％～2.5％，Mn：0.15％～0.5％，Als：0.3％～0.7％，Sn：0.05％～0.11％，S≤0.003％，P≤0.03％，B：0.002％～0.004％，Ca：0.003％～0.005％，N≤0.003％，Ti≤0.003％，其余为Fe及不可避免的杂质，且Mn/S比控制在20～60范围内，B/N比控制在0.7～1.5，Ca/S的比例≥1。为解决现有技术中存在的问题，本发明通过添加合金元素以及偏析元素，配合连铸、热轧、常化和连续退火等热处理工艺，以及优良的冷轧板形控制技术，实现0.30～0.35mm厚度薄规格的高效无取向硅钢产品，具备优异的磁性能和高屈强比的力学性能，满足高效变频空调压缩机电机磁性能和关节式定子高速冲裁对力学性能和板形的高标准要求。

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re... 

取向硅钢热轧板中织构梯度对发展完善的二次再结晶十分关键,通过添加铜可以显著降低取向硅钢板坯加热温度,从而影响热轧板织构分布。利用X射线衍射仪,分析了实验室模拟薄板坯连铸连轧(TSCR)工艺的3种不同铜含量的取向硅钢热轧板织构。结果表明:不同铜含量热轧板表面到厚度1/4处均为弱的热轧织构,热轧板心部主要为{100}面织构;铜含量约在0.4%时,热轧板次表层的{110}<001>织构比例最高,而热轧板心部的{100}<110>织构比例最低;铜含量对热轧织构中{114}<110>和{001}<100>织构发展有显著影响。 The texture gradient in hot rolled grain oriented silicon steel strip is one of the essential factors to achieve a perfect secondary recrystallization.The addition of copper can significantly reduce the slab reheating temperature of grain oriented silicon steel,so as to impact the texture distribution in the hot rolled strip.The texture of hot rolled grain oriented silicon steel strip as-rolled by thin slab casting and rolling process(TSCR) in laboratory with three different copper contents was ... 

从取向硅钢生产路线的选择、工艺技术的改进和生产设备的改造三方面进行了生产取向硅钢的节能降耗技术改造.通过完善多元抑制剂配方生产低温取向硅钢,通过加抛丸的酸洗、带面超声波清洗、改进连续退火炉以及余热循环利用等技术改造,使2012年取向硅钢的产量与未进行技术改造前的2009年相比提高了2.5倍,产品磁性上升了一个半牌号,能耗下降了8.9%,成材率提高了6.4%,生产成本下降了22%,综合效益显著. Energy saving technological transformation was carried out in the production of grain oriented silicon steel from three aspects of the oriented silicon steel production process route selection,technology improvement and equipment renovation.Through the improvement of multiple inhibitor formulations for producing low-temperature grain-oriented silicon steel,and by adding the blasting pickling,the belt surface ultrasonic cleaning,improvement of continuous annealing furnace,waste heat recycling tec... 

利用EBSD技术研究了电工钢中长轴平行于轧向的柱状晶样品在热轧和退火过程中组织和取向的演变规律,并与长轴平行于板法向的样品的已有研究结果进行对比。结果表明,无论柱状晶按何种方向排列,只要表面存在剪切力,热轧后都可形成剪切织构,同时中心形成轧制织构,主要包括旋转立方织构和{112}<1-10>。柱状晶造成的影响主要体现在板中心层,长轴平行于轧向排列的样品热轧时形成的粗大旋转立方晶粒要到脱碳退火后才能完全消除,但破坏了正常的不同取向晶粒间的取向差分布及尺寸均匀性,导致二次再结晶不完全及磁性能降低。 The evolution of microstructure and grain orientation in an electrical steel containing columnar grains with its long axis being parallel to the rolling direction of sheet was studied during hot rolling and annealing by EBSD technique.The results are compared with those of samples containing columnar grains being parallel to normal direction of sheet reported in the reference [3].It was shown that,whether the long axis of columnar grains was arranged in RD or ND,shear textures can be formed in t... 

本实用新型涉及一种取向硅钢氧化镁线涂层装置，尤其涉及一种取向硅钢氧化镁涂层线用冷涂辊，具有涂层辊本体及包覆在涂层辊本体外层的橡胶涂层；涂层辊本体内部为空腔结构，空腔结构内通有循环冷冻液。本实用新型涂层辊内部设计成空腔结构，并通过循环冷冻液对涂层辊进行冷却降温，既可以达到通过涂层辊对氧化镁进行降温的目的，从而满足工艺要求，防止质量缺陷的产生，还可延缓涂层辊因反复摩擦生热造成橡胶层老化，从而延缓涂层辊使用寿命。