硅钢资料

根据相关的取向电工钢典型专利技术,概述了日本高磁感低铁损取向电工钢低温板坯加热、抑制剂合理调节、关键成分Mn、C、Sn和Sb调节与利用、新型退火剂和绝缘溶液的制备及细化磁畴等生产工艺最新动态和进展情况,并提出了国内企业申请取向电工钢专利时应当借鉴之处。 According to related typical patent technology for grain-oriented electrical steel sheets,the recent trends and progress situation for production process of grain-oriented electrical steel sheets with high magnetic flux density and low core loss in Japan are summarized including low temperature slab heating,suitably regulating inhibitors,adjusting and utilizing key element Mn,C,Sn and Sb,manufacturing for new annealing agent and insulating solutions,and fining magnetic domain,and some suggestion... 

研究了罩式炉常化工艺对50W350硅钢热轧板组织、夹杂物和性能的影响。研究结果显示，罩式炉常化工艺在温度一定的情况下，随着保温时间延长，硅钢晶粒逐步再结晶并长大，同时析出物也在聚集长大。通过制定合理的罩式炉常化工艺，可以实现硅钢晶粒的再结晶和长大，从而达到连续退火炉常化工艺产品技术要求。 The influence of normalization process with a bell furnace on the structure,inclusions and properties of 50W350electrical steel hot-rolled sheet was studied.The research results showed that:when the steel was normalized at a certain temperature in the bell furnace,the silicon steel grains gradually recrystallized and grew up with the extension of the annealing holding time,and at the same time,the precipitates also gathered and grew up.The recrystallization and growth of the silicon steel grains... 

【作者】 周威； 刘侃； ...

运用电子背散射衍射(EBSD)和X射线衍射(XRD)技术对硅钢热轧板的织构在板厚方向的分布进行了研究,并分析了两种织构测量方法的特点。EBSD技术能直观给出板厚方向的微观织构,XRD能得到钢板的宏观统计织构信息,结合两种技术的分析,能更直观更精确的研究不同织构在板厚方向的分布。 The texture distribution along the thickness of the silicon steel has been investigated by electron backscatter diffraction(EBSD) and X-ray diffraction(XRD) technique.The characteristics of two technique of texture analysis have been investigated.Combined the two techniques,the texture distribution along the thickness of the silicon steel could be realized distinctly and accurately. 

采用EBSD技术研究了有、无拉应力作用下无取向硅钢在晶粒长大过程中织构转变及晶界变化的规律。结果表明:在晶粒生长期间,无应力作用下的硅钢中,{111}〈112〉,{111}〈110〉织构组分强化,而{100}〈001〉织构组分弱化;与无拉应力作用下的情况相比,施加5MPa的拉应力时,{111}〈112〉,{111}〈110〉织构组分强化的速率下降,{100}〈001〉织构组分变化不明显。对于在晶粒生长期间持续变化的{111}〈112〉,{111}〈110〉和{100}〈001〉织构组分而言,虽然有、无拉应力作用下硅钢的{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率均下降,而{100}〈001〉织构组分的高取向差角度晶界频率则上升,但当有拉应力作用后,{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率下降的速率变小,{100}〈001〉织构组分的高取向差角度晶界频率上升的速率稍有变小。通过对无取向硅钢在晶粒长大过程中织构转变及晶界变化规律的研究,分析了合金原子在晶界的偏聚行为。 The rules of texture and grain boundary transformation in the nonoriented silicon steel under applied stress or without applied stress during grain growth were investigated by EBSD.The results show that the {111}〈112〉 and {111}〈110〉 components in the nonoriented silicon steel without stress are strengthened during grain growth whereas {100}〈001〉 component is weakened,but the growth rate of {111}〈112〉 and {111}〈110〉 component decreases,while the area fraction of {100}〈001〉 component doesn’t chang... 

研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0～2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w... 

以青海盐湖氯化镁为初级原料,采用喷雾热解法制备原料氧化镁。原料氧化镁通过水化制备氢氧化镁。将氢氧化镁过滤、洗涤、烘干、粉碎、煅烧,制备硅钢级氧化镁。本文重点考察煅烧温度、煅烧时间、料层厚度等因素对氧化镁水化率的影响,采用均匀实验设计和DPS数据处理,确定最优煅烧实验条件为:煅烧温度1250℃,煅烧保温时间4小时,料层厚度0.5cm。在此条件下得到的硅钢级氧化镁完全满足硅钢及氧化镁的行业标准。 The magnesium oxide is prepared by Spray pyrolysis process,which magnesium chloride from Qinghai Salt Lake is used as primary raw material,and hydrated to magnesium hydroxide,then obtained silicon steel magnesia through filtering,washing,drying,crushing and calcinations.In this paper,influences of some factors on magnesia hydration rate are studied,such as calcination temperature,calcination time and material thickness.After average experimental design and DPS data processing,optimal calcination... 

针对攀钢高硫铁水冶炼现状,结合不同生产工艺路线,论述了攀钢近年来为实现低硫电工钢的生产,在铁水预处理、转炉冶炼、钢水精炼过程中硫控制技术的开发与应用,形成了低硫洁净钢生产工艺技术,实现了低硫电工钢的生产。低硫电工钢RH脱硫率可达到20%左右,成品[S]控制在0.006%左右。 According to the smelting situations of hot metal with high sulphur content at Panzhihua Steel,combined with different produce processes,technologies for controlling the sulfur content during hot metal pretreatment,converter smelting,and second refining are developed. Technologies in low-sulfur clean steelmaking are formed. Low-sulfur electric steel are produced. As for the desulfurization rate of lowsulfur electric steel can reach about 20%,and the content of [S] in products is controlled to ab... 

对欧盟市场汽车压缩机专用产品进行技术解析,对比分析了其电磁性能、退火和发蓝处理、物理性能、化学成分、应用特点等参数。探讨国内外电工钢产品应用方式的不同特点,并结合鞍钢自身工艺装备和炼钢、热轧、冷轧工艺参数介绍了其生产可行性。提供了冶金工艺流程下,后工序电工钢专业生产线及传统冷轧系统生产线两种生产方式,均能满足用户最终使用要求。 The technology of automotive compressor accommodation manufacture of European Economic and Monetary Union market was described.The magnetic properties,annealing bluing,physical properties,chemical composition,application parameters were analysed.The different characteristics of the application of electrical steel products,the feasibility of manufacture on the existing technology and equipment,steelmaking,hot rolled,cold rolled technical parameters were discussed.The professional product line of ... 

对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550～650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550～650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin... 

通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d... 

双辊连铸技术是冶金及材料领域内的一项前沿技术,对于生产高品质硅钢具有独特优势.本实验研究了一种双辊铸轧w[Si]=4.5%的无取向硅钢,考察其铸态和常化处理后样品的组织、织构及析出相尺寸特征.结果表明:铸带组织以与铸带法向成5~20(°)倾角的柱状晶为主,晶内存在少量0.3~0.4μm的AlN析出相,铸带织构以λ(<001>//ND)织构为主,表层织构漫散.950℃/10 min常化处理后,析出相尺寸增大,表层λ织构增强. As an advanced technique of metallurgy and material science,twin- roll strip casting has unique advantages for producing high quality silicon steel. The present study was aimed at a 4. 5% Si non- oriented electrical steel for analyzing the structure,texture and the size of precipitates at the initial and normalized state. The results revealed that the initial structure mainly consisted of columnar grains with 5 ~ 20( °) angle to the normal of cast strip,and some AlN precipitates of 0. 3 ~ 0. 4 μ...