硅钢资料

【作者】 卢鹏； ...

结合实际生产0.4%Si无取向硅钢，统计了不含Sn和0.025%Sn无取向硅钢的磁性能变化，利用金相显微镜、X射线衍射仪观察分析不同成分下试样的显微组织和微观织构。试验结果表明：Sn元素可以显著降低无取向硅钢的晶粒尺寸，0.025%Sn试样的平均晶粒尺寸比不含Sn减小28.4%;加入Sn元素后抑制了无取向硅钢中不利于磁性能的{111}面织构组分强度，提高了对磁性能有利的{100}面织构组分强度，0.025%Sn与不含Sn相比磁感均值从1.756 T提升至1.768 T,铁损均值从5.476 W/kg降低至5.204 W/kg,明显改善了无取向硅钢磁性能。 In this paper combined with the actual production of 0.4% Si non oriented silicon steel, the magnetic properties of non oriented silicon steel without Sn and 0.025% Sn were counted. The microstructure and microtexture of samples with different compositions were observed and analyzed by metallographic microscope and X-ray diffraction. The results show that: Sn can significantly reduce the grain size of non oriented silicon steel, and the average grain size of 0.025% Sn sample is 28.4% smaller tha... 

连续酸洗退火机组(CPAL)对于当前生产高磁感取向硅钢和高牌号无取向硅钢是必不可少的一个环节。常化炉是常化酸洗机组关键的组成部分。本文对国内自主建造的两条退火酸洗机组的工艺流程,特别是常化炉段进行了对比分析。总结出了常化炉的工艺及组成特点,对生产过程中暴露的问题进行了仔细的分析并提出了改进的意见,对于以后新建常化炉具有一定的提示作用。 The continous pickling annealing line(CPAL) is an essential step in producing high magnetic induction grain-oriented silicon steel and high grade non-oriented silicon steel.The normalizing furnace is a very important part of the CAPL.In this paper,the process flows of two CAPL with independent manufacture in our country have been compared,especially the part of normalizing furnaces.The characteristics of process and component are summarized and problems of the normalizing furnace during the prod... 

通过后天抑制剂获得法制备了取向硅钢,对渗氮前后和高温退火升温阶段析出物的析出和转化规律进行了研究。研究结果表明,渗氮前脱碳退火态基体中存在少量的粗大AlN颗粒和细小AlN颗粒,渗氮处理后新析出大量的Si3N4析出物,高温退火升温阶段Si3N4将转化为(Al,Si)N,随着温度的继续升高(Al,Si)N颗粒将发生粗化,(Al,Si)N是后天抑制剂获得法制备取向硅钢的主要抑制剂。 Grain-oriented silicon steels were produced by acquired inhibitor method.The rule of precipitate transformation was studied after nitriding treatment and high-temperature finishing annealing.The results show that a small amount of large AlN and fine AlN are found in matrix before nitriding treatment,and a large amount of Si3N4 is precipitated in matrix after nitriding treatment.During the temperature rising period of high-temperature finishing annealing,Si3N4 would transform into(Al,Si)N,and(Al,... 

【机构】 宝山钢铁股份有限公司规划与科技部； ...

结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ... 

介绍了国内、外电工钢极薄带的生产现状及市场应用的情况,以及典型生产企业的生产规模、产品性能和应用领域,指出扩大高牌号无取向电工钢生产、提高产品质量是目前电工钢发展的迫切要求。 The production situation and market application of ultra thin electrical steel strip at home and abroad were described.The production capability,product property and application area of typical corporation were introduced.The results indicate that the urgency needed of electrical steel development is expanding high-grade non-oriented electrical steel production and improving products quality at present. 

利用OM、TEM与EDS技术,对Fe-3.2%Si低温取向硅钢热轧板进行不同常化冷却工艺处理后的显微组织、析出相及最终产品的磁性能进行分析,并与热轧板的组织和析出相进行对比。结果表明,常化板较热轧板的表层组织均匀,基体中再结晶比例增加,带状组织变窄;常化板中析出物的数量明显比热轧板的多,析出物主要有AlN、MnS及复合析出的(Cu,Mn)S等。在常化温度1120℃、保温3 min的条件下,采用二段式冷却较空冷、淬沸水、淬常温水的冷却工艺,常化板表层显微组织更均匀,沿板厚方向的显微组织的不均匀性显著,取向硅钢的磁性能最高;常化后采用二段式冷却工艺析出的细小析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利。 Microstructure, precipitate and magnetic characteristic of final products with different normalizing cooling processes for Fe-3.2%Si low-temperature hot-rolled grain-oriented silicon steel were analyzed and compared with the hot-rolled plate by optical microscopy(OM), transmission electron microscopy(TEM), and energy dispersive spectrometry(EDS). The results show that, the surface microstructure is uniform, the proportion of recrystallization in matrix increases, and the banding textures are nar... 

借助电子背散射(EBSD)技术对AlN为主抑制剂的Hi-B取向硅钢常化工艺的中间冷却制度进行了研究。结果表明:常化后试样均发生了完全再结晶,在60℃/s冷速下组织最均匀;在合适的冷却制度下常化板表层保留了强的Goss织构,它深入到1/4厚度处,并且形成对Goss织构有利的强{554}<225>织构。 The intermediate cooling system of Hi-B oriented silicon steel with AlN main inhibitor in normalizing process was studied by means of electron back diffraction(EBSD) technique. The results show that:the specimens after normalizing are fully recrystallization, and the microstructure is most uniform under the intermediate cooling rate of 60℃/s; under suitable cooling system, normalized plate surface retains strong Goss texture, it penetrates into the 1/4 thickness of the plate and forming strong {... 

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the... 

对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后，采用正火、退火两种热处理方式处理，并观察轧制过程中产生的裂纹，研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理，研究复合板中裂纹变化及其对磁性能的影响。结果表明：不同热处理工艺下合金内部的裂纹尺寸差异明显，裂纹尺寸对复合板的磁性能影响显著，相对于深裂纹，其他因素的影响较小；温轧变形加工后，复合板内层出现有序组织，但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能；扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹，但不能消除尺寸较大的裂纹，故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff... 

研究了CSP工艺流程生产的硅含量为1.5%的无取向电工钢在不同常化温度下对磁性能的变化。研究结果表明:随着常化温度的提高,热轧板的晶粒尺寸增大,且组织均匀性提高;此外成品的有利织构组分{100}<0vw>、α、η增强,不利织构组分减弱;铁损P1.5/50呈下降趋势,磁感B50上升平缓。在常化工艺为970℃×2.5min下,对应的铁损P1.5/50<3.4W/kg,磁感B50>1.74T。 The effect of normalizing temperature on the magnetic properties of non-oriented electrical steel containing 1.5%silicon produced by CSP process was studied.The results show that with increasing normalizing temperature,the average grain size of hot-rolled plate increases and the microstructure uniformity is improved.Furthermore,the texture components of finished products are improved through enhancing of{100}<0vw>,αandηtextures and weakening of{111}<112>texture;the core loss P1.5/50 ...