钢厂
ICP-AES法测定硅钢中铌的不确定度评定
分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained.
无取向硅钢表面环保涂层的发展
简述了无取向硅钢环保涂层发展背景,分析了硅钢环保涂层的特点及国内、外研究进展,提出了硅钢保涂层下一步的发展方向。 The back ground of environmental protection coating of non-oriented silicon steel was described in this paper.The characteristics and study progress in domestic and foreign of environmental protection coating of non-oriented silicon steel were analysised.The next development direction of environmental protection coating of non-oriented silicon steel was put forward.
取向硅钢中含铜抑制剂的固溶析出行为
含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10~50 nm Cu2S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;(Cu,Mn)1.8S、Cu1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30~50 nm(或大于50 nm),主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10~50 nm Cu2S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30~50 nm or more than 50 nm...
国内外中低牌号无取向硅钢夹杂物控制效果解析
选用国内外无取向硅钢标杆企业A、B、C的产品,采用非水溶液电解提取+SEM(EDS)方法,分析了其典型牌号对应成品试样中的夹杂物。结果表明,从磁性能控制角度而言,受钢的化学成分及生产工艺影响,A、B、C企业成品试样的夹杂物尺寸、种类、数量存在差异,这些差异对其磁性能产生显著影响;从夹杂物控制角度而言,A、B、C企业对应成品试样的夹杂物,以MnS、CuxS复合或者AlN、MnS、CuxS复合为主,其中1.0μm以下的夹杂物数量分别为2.34×107个/mm3、2.98×107个/mm3和11.98×107个/mm3,1.0μm以上夹杂物数量均很少,夹杂物的平均尺寸从大到小依次为A企业、B企业、C企业。 According to the production of three benchmarking manufacture enterprises A,B and C of non-oriented silicon steel at home and abroad,the inclusions in finished steel samples with typical grades were investigated by electrolytic extraction from non-aqueous solution and SEM(EDS).Results show that,from the viewpoint of improving the magnetic properties,affected by chemical composition and production technique,the size,type and amount of inclusions in finished steel samples are various,which will af...
高磁感取向硅钢涂层技术
涂层技术在高磁感取向硅钢生产中起着重要的作用.根据生产实践,介绍了高磁感取向硅钢生产中涂层的种类和作用、涂料的成分和对产品性能的影响、涂层工艺质量控制要点和检验方法等,并提出了通过优化涂层工艺改善高磁感取向硅钢性能和外观质量的方法. Surface coating technique plays an important role in producing high magnetic inductivity grain-oriented silicon steel.Based on production practice,this paper describes the types and function of the coating,the composition of the coating and its effect on the product performance,the quality control and inspection method for the coatings,as well as proposes ways to improve the magnetic property and surface quality of the steel by optimizing the coating process.
表面机械研磨/异步轧制无取向硅钢薄带的渗硅行为
对w(Si)=3%无取向硅钢进行表面机械研磨处理(SMAT)和异步轧制(CSR),获得表面纳米结构,再进行550~650℃、4 h固体粉末渗硅处理,用透射电镜(TEM)、扫描电镜(SEM)和X射线衍射仪(XRD)研究表层组织演变。结果表明:经过SMAT后,w(Si)=3%无取向硅钢表面形成了等轴状、取向呈随机分布的、晶粒尺寸为10 nm的纳米晶组织;异步轧制后,表面纳米晶组织保持不变;550~650℃、4 h渗硅处理后,SMAT+CSR样品表面形成化合物层,其厚度随着温度的升高由17μm增加到52μm;化合物层由Fe3Si和FeSi相组成. Nanostructured surface layer was fabricated on a 3%(mass fraction) non-grain oriented silicon steel by means of surface mechanical attrition treatment(SMAT) and cross-shear rolling(CSR),and then a solid powder siliconizing treatment was carried out for the SMAT+CSR sample at 550~650 ℃ for 4 h.The microstructural evolution was examined by using transmission electron microscopy(TEM),scanning electron microscopy(SEM) and X-ray diffraction(XRD).Experimental results show that: equiaxed nanocrystallin...
国产化高牌号无取向硅钢退火、涂层炉新技术
从影响高牌号无取向硅钢退火工艺的主要参数入手,介绍高牌号无取向硅钢退火炉在加热、气氛控制、冷却、涂层烘烤方面的新技术,并展望无取向硅钢退火炉的发展方向。 Based on the technology parameters of high-grade non-oriented silicon steel annealing,the new technology of the annealing line,which includes heating,atmosphere control,cooling,coating baking,is introduced,and the development direction of non-oriented silicon steel annealing furnace is pointed out.
制备{100}织构无取向电工钢方法综述
{100}织构因具有两个易磁化方向能够明显的提高磁性能,因此如何在表面获得具有{100}织构一直是无取向电工钢研究焦点。本文主要介绍了获得{100}织构的主要工艺方法及其基本原理,并结合实际生产过程对各工艺方法的优缺点进行了分析;一方面,优化无取向电工钢的成分,降低碳、锰元素含量以避免脱碳退火和真空退火,简化生产工艺;另一方面,调节升温速度、降温速度和退火气氛,使{100}晶面的表面能或弹性应变能最低,制备具有{100}织构柱状晶组织的无取向电工钢是今后的发展方向。 Because { 100} texture has two easy magnetization directions,which can significantly improve magnetization properfies,how to develop { 100} texture is a focus for researchers and manufactures. In the paper,main manufacturing processes and basic principle are introdued,and their advantages and disadvantages in practical production are analyzed. On the one hand,the production process can be simplified by optimizing chemical compositions,such as reducing the content of C and Mn,which can avoid deca...
修正GTN模型及其在预测硅钢冷轧边裂中的应用
考虑剪应变对微孔洞损伤演化的影响,对GTN损伤模型的损伤演化机制进行修正,建立了适用于不同应力三轴度水平的损伤模型。结合隐式应力更新算法和显式有限元计算,采用VUMAT子程序实现了修正GTN模型在有限元软件ABAQUS中的数值计算。通过模拟纯剪切和剪切-拉伸两组试样的损伤演化和断裂行为,验证了修正GTN模型在不同应力三轴度承载条件下的有效性。运用修正GTN损伤模型模拟含边部缺口的带钢在轧制过程中裂纹的萌生和扩展行为,模拟结果与实验相一致,表明该模型可有效地用于带钢缺陷在轧制过程中扩展行为的分析和预测。模拟和实验结果表明,带钢边部缺口在轧制过程中,缺口前沿和后沿均会萌生裂纹,且后沿裂纹扩展更为明显。 Considering the effect of shear strain of micro-void on damage evolution, a modified GTN model applicable to various stress triaxiality conditions is proposed by modifying the damage evolution mechanism of the GTN damage model. The modified model is implemented in commercial finite element software ABAQUS by combining the implicit stress update method with an explicit finite element solving algorithm and through the user-defined material subroutine VUMAT. The damage evolution and the failure pro...
硅钢连退机组辐射管加热段数值模拟
文章以国内某公司硅钢厂连续退火机组1号辐射管加热段为研究对象,分析炉内传热机理,建立并开发了辐射管加热段的传热模型。采用生产实际数据对模型进行了验证,以总燃料消耗量最小为目标,得出该炉段长度方向上燃料的最佳分配机制。所得结论为该公司连续退火机组节能控制提供理论依据。 Taking the radiant tube heating section of No.1 continuous annealing unit in a silicon steel plant of a domestic company as the research object, the heat transfer mechanism in the furnace is analyzed, and the heat transfer model of the radiant tube heating section is established and developed. The model is verified by the actual production data. Aiming at the minimum total fuel consumption, the optimal fuel distribution mechanism in the length direction of the furnace section is obtained. The co...
双辊连铸无取向硅钢铸带特征及常化作用研究
双辊连铸技术是冶金及材料领域内的一项前沿技术,对于生产高品质硅钢具有独特优势.本实验研究了一种双辊铸轧w[Si]=4.5%的无取向硅钢,考察其铸态和常化处理后样品的组织、织构及析出相尺寸特征.结果表明:铸带组织以与铸带法向成5~20(°)倾角的柱状晶为主,晶内存在少量0.3~0.4μm的AlN析出相,铸带织构以λ(<001>//ND)织构为主,表层织构漫散.950℃/10 min常化处理后,析出相尺寸增大,表层λ织构增强. As an advanced technique of metallurgy and material science,twin- roll strip casting has unique advantages for producing high quality silicon steel. The present study was aimed at a 4. 5% Si non- oriented electrical steel for analyzing the structure,texture and the size of precipitates at the initial and normalized state. The results revealed that the initial structure mainly consisted of columnar grains with 5 ~ 20( °) angle to the normal of cast strip,and some AlN precipitates of 0. 3 ~ 0. 4 μ...
CSP流程生产高磁感无取向电工钢磁各向异性研究
对CSP流程生产的高磁感无取向电工钢50W1300在偏离轧制方向不同角度处的磁性能进行了测试和分析。结果表明:在偏离轧向不同角度处,磁性能差异显著,尤其在α=60°时磁感最低;偏离轧制方向不同角度处的磁性能大小取决于织构类型、强度及分布状态;增强{100}<0vw>和α、η取向的有利织构组分,降低不利的γ取向织构组分,且使有利织构组分分布越漫散,磁各向异性越小。 Magnetic properties of high magnetic induction non-oriented electrical steel 50W1300 produced by CSP processes were investigated with different direction in relation to the rolling direction.The result shows that magnetic properties are significantly different in relation to the rolling direction,in particular,the minimum magnetic induction occurs at 60° in relation to the rolling direction.Magnetic properties of different directions in relation to rolling direction depend on type and distributi...

