钢厂
硅钢50A1300的流变应力和临界动态再结晶行为
用Gleeble1500D模拟试验机在变形温度为950~1 200℃、应变速率为0.01~8s-1、最大变形程度为60%的条件下,对硅钢50A1300做单道次压缩试验,首先分析了不同参数对流变应力的影响,然后用回归法确定了应力模型中的变形激活能及材料常数,得到硅钢50A1300在峰值应力条件和稳态应力条件下的变形激活能分别为270.360和91.557kJ/mol,同时得到了流变峰值应力模型,模型的相关系数为0.997。最后通过作lnθ-ε图的方法找到了硅钢50A1300发生动态再结晶的临界应变量,并回归得到峰值应变量、临界应变量与参数Z/C的关系式。 To analyze the effects of different parameters on the flow stress and critical strain of the dynamic recrystallization,single-pass compression experiments were carried out with silicon steel 50A1300 specimens using a Gleeble1500D thermal simulator at a temperature range of 950-1 200 ℃ and strain rate range of 0.01-8 s-1 under the condition of maximum deformation of 60%.The average deformation activation energy is respectively 270.360 and 91.557 kJ/mol under the peak stress and steady-state stres...
高Cu无取向电工钢的制备
运用EBSD和光学显微镜,研究了0.25%~0.45%Cu对无取向电工钢热轧板显微组织,成品板显微组织、织构和磁性能的影响。实验结果表明:卷取过程中Cu元素在热轧板表层的偏聚作用显著阻碍了热轧板表层再结晶晶粒长大,导致热轧板表层晶粒尺寸随着Cu含量增加而逐渐较小,但热轧板中间晶粒尺寸变化不大。同时发现Cu元素能够明显改善织构类型,使有利织构组分增加,不利织构组分减少,同时减弱织构强度。从实验结果可知0.35%Cu能够显著改善电工钢的磁性能,铁损P15/50最低达到4.1 W/kg,磁感B50最高值达到1.8 T。 Effects of high content Cu on microstructure of hot rolled plates and microstructure,texture and magnetic properties of annealed finish product plates of non-oriented electrical steel were examined by means of EBSD technique and optical microscope. The results show that surface segregation of Cu significantly hindered recrystallized grain growth of surface layer in hot rolled plate during the coiling,as a result,the surface grain sizes of the hot-rohed plates decrease with the increase of Cu con...
ZnO对无铬无取向硅钢绝缘涂层性能的影响研究
主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t...
微合金元素Sn、Nb、Re对无取向硅钢性能的影响
介绍了微合金元素锡、铌、稀土对无取向硅钢性能的影响,并扼要分析了这些元素对硅钢性能的影响机理:晶界偏聚元素Sn可细化晶粒提高硅钢磁性能;微合金元素Nb细化铁素体晶粒,提高硅钢的强度、韧性和塑性及磁性能;稀土元素(RE)在硅钢中的主要作用包括净化钢液、变质夹杂物、改善铸态组织和性能及微合金化,减少晶界上出现偏析的几率。 The influence of micro-alloy elements on properties of non-oriented silicon steel and the mechanism for effect of the micro-alloy elements including Sn、Nb and RE on the properties of steel are presented and analyzed in this paper.Grain boundary segregation elements Sn in steel can grain refinement and improve the magnetic properties;Micro-alloy elements Nb can refine the ferrite grain,increase the silicon steel strength,toughness and plastic;The main role of the RE in the silicon steel including...
高温退火气氛对硅钢表面硅酸镁底层形貌的影响
对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟,利用X射线衍射仪(XRD)分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成,采用场发射扫描电镜(SEM)观察了样品表面氧化层和底层在截面方向上的微观形貌特征,并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明:当退火气氛的露点温度保持一定时,较高的氢气含量有利于生成完整连续的底层;当退火气氛的水氢分压比保持一定时,在露点温度与氢气含量两者较低的条件下,底层附着性不佳易脱落,较高条件下,底层中夹杂着较多的铁单质;当氧化层中无FeO时,底层完整连续但易脱落,当FeO层较薄时,底层下方存在部分未反应的SiO2,当FeO层较厚时,底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer(XRD) was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy(SEM) was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ...
无取向电工钢深脱硫试验
为满足用户对无取向电工钢中硫含量的要求,采用CaO-CaF2复合渣系为脱硫剂,利用RH投入法对无取向电工钢进行深脱硫试验。试验结果表明,RH精炼渣成分控制在w CaO43%~51%、w Al2O325%~31%、w MgO4%~6%、w SiO29%~12%、w(FeO+MnO)3%~6%,在脱硫剂加入量为6~8 kg/t时,钢中平均硫含量从32×10-6降低到18×10-6,RH平均脱硫率为43.3%,最高达47.1%。利用KTH模型计算精炼终渣平均硫容量为0.003 1,RH精炼结束时渣-钢间实际平均硫分配比从14增加到52。 In order to satisfy the requirements of consumers on sulfur content in non-oriented electrical steel,taking( CaO-CaF 2) based flux as desulfurizer,industrial experiments on deep desulphurization of non-oriented electrical steel were carried out during RH process. The results show that as the compositions of refining slag are appropriately controlled with w CaO of 43% ~ 51%,w Al2O3 of 25% ~ 31%,w MgO of 4% ~ 6%,w SiO2 of 9% ~ 12%,and w( FeO + MnO) of 3% ~ 6%,and the desulfurizer added are at 6 ~ ...
取向硅钢的晶体衍射花样特征研究
广泛应用于电子电力行业的取向硅钢材料的磁性能与其晶体取向密切关联,对取向硅钢晶体衍射花样的研究非常重要.采用理论计算的方式研究了取向硅钢的晶体衍射花样特征,并绘制了取向硅钢的高斯织构理论极图、理论单晶透射电子衍射斑点花样和理论电子背散射衍射(Electron backscatter diffraction, EBSD)菊池花样.取向硅钢理论单晶衍射花样不仅可以为以后标定样品实测晶体衍射花样提供一种简单快捷的方法,也可以为样品检测提供一种标准.这种研究方法不仅限于取向硅钢,也被期待应用于其他材料晶体衍射花样研究. The magnetic properties of oriented silicon steels which are widely used in electronic and power industries are closely related to their crystal orientations, so it is very important to study the crystal diffraction patterns of oriented silicon steels. The characteristics of crystal diffraction patterns of oriented silicon steels are studied by means of theoretical calculation. The theoretical pole figures, theoretical single crystal transmitted electron diffraction patterns and theoretical elec...
纳米TiO_2轧制液对硅钢冷轧性能的影响
分别采用传统冷轧轧制液和纳米TiO2的冷轧轧制液,对无取向硅钢板进行了四辊冷轧实验.重点研究两种冷轧轧制液的轧制润滑性能和对轧后硅钢薄带表面质量和耐蚀性能的影响.通过场发射电子显微镜和能谱仪对使用两种轧制液轧后得到的硅钢薄带表面形貌和成分进行了分析.给出了轧制液中TiO2纳米粒子在轧制过程中的抗磨减摩机理.在轧制载荷较高时,纳米TiO2轧制液具有优良的轧制润滑性能并能显著改善轧后硅钢薄带的表面质量.同时在高载荷作用下,TiO2纳米粒子被压入硅钢薄带基体,形成一个滑动系来支撑载荷,从而使润滑膜的耐磨性提高. Non-oriented silicon steel strips were rolled on a four-high cold rolling mill lubricated by a traditional cold rolling liquid and a nano-TiO2 cold rolling liquid,with emphasis on studying the rolling lubrication performance of both the liquids and their effect on the surface quality and corrosion resisting property of the silicon steel strips.The surface micrograph and composition of the silicon steel strips after being rolled with both the liquids were characterized by field emissio...
冷轧无取向硅钢产品标准浅析
聚焦无取向硅钢产品标准,从电磁性能、表面性能、机械性能以及尺寸公差与边部质量等维度对国际标准IEC、EN、JIS、ASTM以及国标GB进行了分析研究。分析得出,各类标准在电磁性能方面要求基本一致;ASTM标准的机械性能要求有别于其他几个标准。 In this paper,non-oriented silicon steel standards of EN,JIS,GB and ASTM were compared and analyzed. It is showed that,all types of standards in electromagnetic performance requirements are basically the same. Surface properties in ASTM standard are expressed in the most detailed. The mechanical properties requirements of the standards,except for ASTM,are basically the same.
基于GTN损伤模型对含边部缺陷硅钢薄板冷轧时边裂的预测
采用拉伸试验和显微组织观测的方法确定了GTN损伤模型中的9个损伤参数,运用GTN损伤模型对冷轧硅钢薄板边部缺陷的扩展及边裂的产生进行了有限元模拟,并与预置缺口的钢板轧制试验进行对比。结果表明:轧制过程中边部缺陷是造成钢板边部裂纹萌生和扩展的一个重要原因,GTN损伤模型可用来预测含边部缺陷硅钢薄板在冷轧过程中边裂的产生;预测结果与试验结果基本一致。 The crack initiation and propagation of silicon steel strip with edge defect during cold rolling process was studied by using GTN damage model in this paper.Nine damage parameters in GTN model were identified by tensile testing and microstructure observing,and then the FE simulation of edge defect evolution of silicon steel strip during rolling process was conducted on the base of GTN damage model,and then the results were compared with rolling experimental results.The results show that the edge...

