硅钢资料

试验2.3Si无取向硅钢(/%:0.003C,2.30Si,0.16Mn,≤0.020P,≤0.005S,0.54Al)冷轧板由常化和未常化的2.5 mm热轧板冷轧至0.6 mm(压下率76%),经750~950℃2.5 min中间退火后再冷轧至0.5 mm(压下率16.7%),成品板经890℃+960℃2.5 min退火。研究了中间退火温度对该钢晶粒尺寸、织构和磁性能的影响。结果表明,随中间退火温度的升高,二次冷轧前晶粒和成品晶粒增大,成品中不利织构组分{111}和{112}减弱,磁性能得到改善。热轧板经过常化时的磁性能明显好于未经常化时的磁性能,但中间退火温度较高时常化对磁性能的有利作用减弱。 The test cold sheet of 2.3Si non-oriented silicon steel(/%:0.003C,2.30Si,0.16Mn,≤0.020P,≤0.005S,0.54Al) is first cold-rolled from normalized and un-normalizing 2.5 mm hot-rolled plate to 0.6 mm sheet(reduction 76%),then intermediate annealed at 750~950℃ for 2.5 min and double cold-rolled to 0.5 mm sheet(reduction16.7%),the finished sheet annealed at 890℃+960℃ for 2.5 min.Effect of the intermediate annealing temperature on grain size,texture and magnetic performance of the steel has been studied.... 

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc... 

对欧盟市场汽车压缩机专用产品进行技术解析,对比分析了其电磁性能、退火和发蓝处理、物理性能、化学成分、应用特点等参数。探讨国内外电工钢产品应用方式的不同特点,并结合鞍钢自身工艺装备和炼钢、热轧、冷轧工艺参数介绍了其生产可行性。提供了冶金工艺流程下,后工序电工钢专业生产线及传统冷轧系统生产线两种生产方式,均能满足用户最终使用要求。 The technology of automotive compressor accommodation manufacture of European Economic and Monetary Union market was described.The magnetic properties,annealing bluing,physical properties,chemical composition,application parameters were analysed.The different characteristics of the application of electrical steel products,the feasibility of manufacture on the existing technology and equipment,steelmaking,hot rolled,cold rolled technical parameters were discussed.The professional product line of ... 

组织和织构是影响无取向硅钢性能的重要因素。为改善产品性能，研究了冷轧压下率（71.7%～87.0%）对高牌号无取向硅钢组织、织构、磁性能和力学性能的影响。结果表明，随冷轧压下率的增加，退火晶粒平均尺寸先减小后增大；高斯和立方织构强度减弱，γ纤维织构增强，α纤维织构转变为较强的α^*（{h, 1, 1}〈1/h, 1, 2〉）织构，并随冷轧压下率的增加而增强，同时其峰值逐渐向{111}面移动；工频铁损P_1.5/50、高频铁损P_1.0/400和磁极化强度J₅₀₀₀同时降低，屈服强度变化不大，表面硬度逐渐增加。当冷轧压下率由84.7%增至87.0%、厚度减至0.30 mm时，高频铁损降幅是工频铁损的11倍，表面硬度增幅变大。以上研究成果对硅钢减薄后织构及组织的优化提供了很好的指导。 Microstructure and texture are critical factors on non-oriented silicon steel properties. In order to improve product properties, this paper studied the effect of cold rolling reduction rate（71.7%-87.0%） on microstructure, texture, magnetic properties and mechanical properties of high-grade non-oriented silicon steel. The results show that with the increase of cold rolling reduction rate, the average size of annealing grain decreases first and then increases. The intensity of Goss and λ fiber te... 

【机构】 中国金属学会电工钢分会； ...

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

阐述了电工钢在\"双碳\"中的作用,强调了电工钢的生产工艺技术及在减少碳排放、降低能耗中的作用,对下游能效升级带来明显的节能及降碳成果。同时,分析了2021年电工钢的生产运行情况,介绍了电工钢的未来发展,并针对如何减少碳排放以及生产更多的更低铁损、更高磁感的电工钢谈了几点启示。 The effects of electrical steels on carbon peak and carbon neutralization were expounded,especially on the achievements of obvious energy saving and carbon reduction to the downstream energy efficiency upgrading bringing from the production technology of electrical steels and their effects to reducing carbon emission and energy consumption.Meanwhile the production situation of electrical steels in 2021 was analyzed,and the future development of electrical steels was introduced,and some advices w... 

采用低温板坯加热制备取向硅钢,通过透射电镜(TEM)观察并研究热轧板中的析出物,用ODF织构法研究热轧板距表面1/8、1/4和1/2处的织构分布。结果表明,热轧板中的析出物主要是密排六方AlN,AlN形貌呈规则长方形,AlN颗粒大小不等,分布密度低;热轧板中的织构沿板厚方向,由亚表层的{110}<001>织构向1/2中心层的α线织构变化,其中{110}<001>织构在热轧板距表面1/4层处最强。 The low temperature grain-oriented silicon steels were produced by acquired inhibitor method.The precipitates in hot rolling strip were observed and studied by transmission electron microscope,and the texture distribution in 1/8,1/4 and 1/2 layers of hot rolling strip were analyzed by ODF method.The results showed that the square shaped h-AlN is the main precipitates in hot rolling strip.The precipitates are varying in size and distribution.The texture of hot rolling strip in thick direction are... 

【机构】 武钢研究院； ...

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

采用X射线衍射仪分析无取向硅钢冷轧织构和再结晶退火织构的演化,研究了热轧组织对无取向硅钢织构以及磁性能的影响。结果表明,具有均匀、粗大晶粒组织的热轧板,冷轧形成更多的剪切带,导致成品板形成高的高斯织构组分,并提高了{100}织构强度,降低了γ纤维织构,最终导致成品磁感应强度升高,铁损下降。 The texture evolution of non-oriented silicon steel during cold-rolling and recrystallization annealing was investigated by X-ray diffractometer.The effects of hot band microstructure on the texture and magnetic properties of non-oriented silicon steel were analyzed.The results show that more shear bands appear during cold rolling due to homogeneous coarse grain in hot band.So strong{110}<001> texture after recrystallization annealing forms.At the same time,the {100} texture components inc... 

分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained.