硅钢资料

用还原分离-原子荧光光谱法分析了硅钢中的痕量汞.分析方法的不确定度主要来自测量重复性,样品溶液浓度,工作曲线变动性,标准溶液,移取、配制标准溶液,仪器变动性等.文章分别对上述构成合成不确定度大小的分量进行了计算讨论. Trace mercury in silicon steel and galvanized sheet was analyzed by adopting reduced separation-atomic fluorescence spectrometry.The uncertainty of the analysis method mainly comes from measurement repeatability,sample concentration,working curve volatility,standard solution,pipetting and preparation of standard solution,and instrument variability,etc.The essay conducted all calculations and discussions on the above components that determine uncertainty. 

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

连续酸洗退火机组(CPAL)对于当前生产高磁感取向硅钢和高牌号无取向硅钢是必不可少的一个环节。常化炉是常化酸洗机组关键的组成部分。本文对国内自主建造的两条退火酸洗机组的工艺流程,特别是常化炉段进行了对比分析。总结出了常化炉的工艺及组成特点,对生产过程中暴露的问题进行了仔细的分析并提出了改进的意见,对于以后新建常化炉具有一定的提示作用。 The continous pickling annealing line(CPAL) is an essential step in producing high magnetic induction grain-oriented silicon steel and high grade non-oriented silicon steel.The normalizing furnace is a very important part of the CAPL.In this paper,the process flows of two CAPL with independent manufacture in our country have been compared,especially the part of normalizing furnaces.The characteristics of process and component are summarized and problems of the normalizing furnace during the prod... 

【作者】 李波； 杨晓江； ...

变压器D21硅钢铁芯片采用冲压工艺生产。首先对其工艺进行了分析,确定了冲压方案。对产品进行了排样设计,计算了冲压力,确定了压力中心。然后,设计了单工序落料模具,完成了模具装配图。 D21 silicon steel chips for transformer are produced by stamping.First,its stamping process was analyzed and the scheme of the stamping process was determined.The product layout was designed,the punching pressure was calculated,the pressure center was determined.Then,the blanking die with single procedure was designed,the die assembly drawing was completed. 

介绍了国内、外电工钢极薄带的生产现状及市场应用的情况,以及典型生产企业的生产规模、产品性能和应用领域,指出扩大高牌号无取向电工钢生产、提高产品质量是目前电工钢发展的迫切要求。 The production situation and market application of ultra thin electrical steel strip at home and abroad were described.The production capability,product property and application area of typical corporation were introduced.The results indicate that the urgency needed of electrical steel development is expanding high-grade non-oriented electrical steel production and improving products quality at present. 

【作者】 杨佳直； ...

采用取向分布函数和取向线分析方法对低温板坯加热取向硅钢从热轧到初次再结晶工艺阶段的织构进行了研究。研究表明:一次冷轧后各层的织构组分与热轧板各层面的织构组分存在着继承关系,次表层存在很强的{001}<110>织构,中心层的织构和热轧板的中心层相似,存在强的{001}<110>和{112}<110>织构;中间退火后发生再结晶,各织构组分的强度有所减弱,Goss织构组分再次出现;二次冷轧后沿厚度方向上的织构不均匀性不明显,{111}<112>织构强度最高,几乎是其他织构组分的1倍,{001}<110>织构大幅降低;初次再结晶后织构沿厚度方向没有明显的不均匀性,{111}<110>为最强的织构组分,并且具有一定强度的Goss位向。 The texture from the first cold rolling to the primary recrystallization of low temperature slab reheating grain-oriented electrical steel were researched by orientation distribution function and orientation distribution intensity technique.The results show that after the first stage of cold rolling,there is a strong {001}<110> texture in the subsurface and the texture in center layer is very similar to the center layer of hot band which has strong {001}<110> and {112}<110> tex... 

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r... 

无取向硅钢的磁性能主要取决于铁素体的晶粒尺寸、晶体织构和钢中的夹杂物。通过合适的化学成分设计以及采用适宜的夹杂物控制技术,可以获得最佳的夹杂物控制效果,使其纯净度大幅度提高或者无害,最终获得磁性能优良的高级别无取向硅钢。同时,为满足节能、环保、高效需求,无取向硅钢正朝着节能降耗、环境友好以及多功能、高效率、易加工等方向发展。 The magnetic properties of non-oriented silicon steel mainly depend on the grain size of ferrite,the crystallographic texture,and the inclusions in the steel.The optimum inclusion control effects can be obtained through a suitable chemical composition design and an appropriate inclusion control technique,and then the liquid steel will get be clean or the inclusion will get be harmless,finally the excellent magnetic property of the non-oriented silicon steel can be obtained.Meanwhile,in order to ... 

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

热轧轧制工艺对产品性能和轧制稳定性影响很大,对中低牌号无取向电工钢,当在两相区轧制时,热轧塑性明显降低,板形变坏,易出现边裂等情况。以50W1000为例,通过对其变形抗力进行研究,得出把两相区控制在F4与F5之间为最佳轧制工艺的结论。在此基础上制定了一套较为合理的热轧工艺制度。采用新的轧制工艺后,50W1000热轧精轧的稳定性明显改善,热轧产品合格率由开发初期的40%左右提高到95%以上。 The hot rolling process has great influence on product′s performance and rolling stability.For the low medium grade non-oriented electrical steel,when non-oriented electrical steel is rolled in tow phase region,the hot rolling plasticity reduces obviously,the shape of strip goes bad and easily to crack at the edge.The deformation resistance of 50W1000 steel was investigated.The results show that the optimal rolling process is to control the two phase region between F4 and F5.Based on the results...