硅钢资料

对CSP流程生产的高磁感无取向电工钢50W1300在偏离轧制方向不同角度处的磁性能进行了测试和分析。结果表明:在偏离轧向不同角度处,磁性能差异显著,尤其在α=60°时磁感最低;偏离轧制方向不同角度处的磁性能大小取决于织构类型、强度及分布状态;增强{100}<0vw>和α、η取向的有利织构组分,降低不利的γ取向织构组分,且使有利织构组分分布越漫散,磁各向异性越小。 Magnetic properties of high magnetic induction non-oriented electrical steel 50W1300 produced by CSP processes were investigated with different direction in relation to the rolling direction.The result shows that magnetic properties are significantly different in relation to the rolling direction,in particular,the minimum magnetic induction occurs at 60° in relation to the rolling direction.Magnetic properties of different directions in relation to rolling direction depend on type and distributi... 

本发明公开了一种适宜缠绕式加工的低铁损无取向硅钢及其生产方法，属于硅钢生产技术领域。本发明的无取向硅钢包括以下质量百分比的元素：Si：1.5～2.5％，Mn：0.15～1.0％、Als：0.5～1.5％，其余为Fe及不可避免的杂质。其生产工艺步骤为：铁水预处理、转炉冶炼、真空处理、连铸；加热热轧；常化处理；冷轧、退火；保温、冷却；涂覆绝缘层。本发明通过对无取向硅钢的组分及其配比，结合工艺操作进行优化，能够生产得到电磁性能及延伸率均优异的无取向硅钢，从而能够有效满足电工钢缠绕式加工及使用需求，且其制造工序流程短、成本相对较低。

对冷轧无取向硅钢在冶炼过程中各个工序的顶渣进行了检测,分析了顶渣变化原因,并得出结论:硅钢生产宜采用复吹转炉,以降低吹炼终点渣中TFe含量,进而减轻对精炼的压力;使用低S、低Al2O3含量中间包覆盖剂;RH脱氧及合金化顺序采用先加硅铁后加铝;首罐宜经LF提温并降低渣中TFe。 The top-surface slag used for the various production processes in smelting coldrolled non-oriented electrical steel is tested and based on tested results the cause of the top surface slag change is analyzed.So it is concluded that the combined blown converter is more suitable to be used for smelting electrical steel in order to reduce the content of TFe in slag at blow end point and then much better results can be achieved during the period of refining.Secondly the tundish flux contenting low co... 

本发明一种解决取向硅钢热轧板晶粒粗大的方法，在取向硅钢的成分设计中减少固溶温度较高的MnS的含量，降低铸坯加热温度，同时计算实际取向硅钢成分中γ‑相含量与温度之间的关系，依据计算结果设计取向硅钢的热轧工艺，可以保证20％～30％的γ‑相数量，成功解决取向硅钢热轧板晶粒粗大的问题。

本发明公开一种冷轧硅钢的横向同板差控制方法，具体如下：S1、确定冷轧钢板横向同板差的影响因子，包括：热轧钢卷的热卷凸度、工作辊辊型插入量、中间辊窜动值及冷轧钢卷的总切边量；S2、以影响因子为变量构建冷轧钢板横向同板差的计算模型；S3、将热轧钢卷的热卷凸度及冷轧钢板的目标横向同板差输入计算模型，确定最小冷轧钢卷总切边量下的工作辊辊型插入量及中间辊窜动值。明确客户所需的横向同板差，通过改变工作辊辊型插入量X2及工作辊窜动值X3，以此得到冷轧成品钢卷的总切边量最小值，在满足客户对横向同板差的使用要求前提下，降低生产成本，提高产品竞争力。

结合冶炼无取向硅钢的生产实际,对钢中硫的来源,以及炉渣性质、钢水温度、底吹强度对脱硫的影响进行了分析。研究表明,转炉钢中硫的主要来源为铁水、废钢、铁水渣及石灰带入;冶炼硅钢时,终渣碱度为3.0~3.5,w((FeO))≤20%,终点钢水温度大于等于1 680℃,加大底吹搅拌强度能提高转炉脱硫效果。硅钢平均出钢硫的质量分数为0.004 8%,能满足无取向硅钢对硫含量的要求。 With the actual production of non-oriented silicon steel,the source of sulphur and the effect of metallugic parameters like slag properties,temperature of molten steel and bottom stirring on desulphurizing ability were investigated.The results show that the main source of sulphur is molten metal,scrap,the remaining slag volume in hot metal and lime.The degree of desulphurization for smelting silicon steel can be increased through adopting the following measures,such as the basicity of finishing ... 

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

本发明提供一种改善表面麻点缺陷的薄规格中低牌号无取向硅钢及其生产方法，成分C≤0.0025％，1.2≤Si≤1.65％，0.25％≤Mn≤0.35％，0.06％≤P≤0.11％，0.1％≤Als≤0.2％，S≤0.0025％、N≤0.0025％，Ti≤0.0025％，其余为Fe及不可避免的杂质。与现有技术相比，本发明采用较低氢气浓度，防止炉内氧化铁皮还原，减轻碳套辊的腐蚀程度，减少碳套辊结瘤率，改善带钢表面质量；采用合理合金成分设计，提高带钢的力学强度，降低碳套辊结瘤对带钢表面的影响程度，改善带钢表面质量。产品厚度为0.35mm，板面麻点发生率降低，无手感，且辊身周长周期范围内麻点个数≤5个。

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

对无取向硅钢炼钢全流程钢液增钛的原因进行了分析,认为铁水钛含量、转炉出钢温度、转炉下渣量、精炼渣TiO₂含量、钢水罐及RH浸入管混钢种生产是影响钢液增钛的主要原因。通过采取低钛铁水冶炼,减少转炉下渣量,提高出钢温度,添加白灰改质精炼渣等措施,均能够降低钢液中的钛含量。 After analyzing the causes leading to increased content of titanium in molten nonoriented silicon steel during whole steelmaking process, it was concluded that such factors as content of titanium in hot metal, tapping temperature from converter, quantity of roughing slag entered into the ladle from converter, content of TiO₂ in refining slag, molten steel ladle car,carrying out the steelmaking of different steel grades by the same ladle and same RH immersion tube were the main causes ... 

【作者】 朱凤泉； 黄生银； ...