论文

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

目前高磁感冷轧硅钢生产过程中，采用经验方法确定的乳化液流量设定值往往会造成硅钢产品的磁感性能达不到预期目标，针对此情况，基于轧机轧制机理研究了的乳化液流量数学模型，确定了乳化液流量设定值。实践表明，使用该数学模型输出的乳化液流量设定值，可提高轧制过程中乳化液流量控制精度，从而提高高磁感冷轧硅钢的轧制性能。 In view of the current production process of high magnetically inductive cold-rolled silicon steel, the mathematical model of emulsified fluid flow based on mill rolling mechanism is studied in view of the situation in which the magnetic sensing performance of silicon steel products is often not up to the expected target by using empirical method to determine the emulsified liquid flow setting. Practice shows that the emulsified fluid flow setting value output from this mathematical model improv... 

结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte... 

为探究铬、锰元素及退火温度对高强无取向硅钢性能的影响规律,借助OM、SEM、EBSD与万能拉伸试验机等分析不同制造工艺下3组不同含量铬、锰元素的无取向硅钢热轧、常化及退火处理后组织与性能。结果表明,试验钢热轧后组织不均匀,心部为沿轧向分布纤维状组织,边部为少量再结晶晶粒,常化处理能显著改善热轧板组织均匀性,消除热轧板中心部位的纤维状组织。经冷轧及退火后得到多边形铁素体晶粒,其中960℃退火,晶粒尺寸偏大,有利织构{100}组分体积分数减少,不利织构{111}组分体积分数增加,成分为0.2Mn-1Cr的1号试验钢960℃退火后铁损最大,磁感强度偏小;成分为0.5Mn-1Cr的2号试验钢930℃退火后,磁性能与强度等综合性能最佳,工频铁损P_1.5/50为2.41W/kg,高频铁损P_1.0/400为17.36W/kg,磁感应强度B_{5 000}为1.638T,抗拉强度为685MPa。 In order to study the effect of Cr,Mn and annealing temperature on the properties of high-strength non-oriented silicon steel,the microstructure and properties of three groups of non-oriented silicon steel with different Cr,Mn content under different manufacturing processes were analyzed by means of OM,SEM,EBSD and universal tensile tester.The results show that the structure of experimental steel is not uniform after hot rolling,and the core is distributed in fibrous structure along the rolling ... 

【作者】 陶永根； ...

聚焦无取向硅钢产品标准,从电磁性能、表面性能、机械性能以及尺寸公差与边部质量等维度对国际标准IEC、EN、JIS、ASTM以及国标GB进行了分析研究。分析得出,各类标准在电磁性能方面要求基本一致;ASTM标准的机械性能要求有别于其他几个标准。 In this paper,non-oriented silicon steel standards of EN,JIS,GB and ASTM were compared and analyzed. It is showed that,all types of standards in electromagnetic performance requirements are basically the same. Surface properties in ASTM standard are expressed in the most detailed. The mechanical properties requirements of the standards,except for ASTM,are basically the same. 

采用X射线衍射仪分析无取向硅钢冷轧织构和再结晶退火织构的演化,研究了热轧组织对无取向硅钢织构以及磁性能的影响。结果表明,具有均匀、粗大晶粒组织的热轧板,冷轧形成更多的剪切带,导致成品板形成高的高斯织构组分,并提高了{100}织构强度,降低了γ纤维织构,最终导致成品磁感应强度升高,铁损下降。 The texture evolution of non-oriented silicon steel during cold-rolling and recrystallization annealing was investigated by X-ray diffractometer.The effects of hot band microstructure on the texture and magnetic properties of non-oriented silicon steel were analyzed.The results show that more shear bands appear during cold rolling due to homogeneous coarse grain in hot band.So strong{110}<001> texture after recrystallization annealing forms.At the same time,the {100} texture components inc... 

【作者】 王爱华； ...

介绍了普通取向硅钢(CGO)和高磁感取向硅钢(Hi-B)铸坯高温加热两次冷轧、一次冷轧和铸坯低温加热两次冷轧、一次冷轧法4种成熟生产工艺的主要技术参数,取向硅钢理论研究(Goss晶核和抑制剂)和生产技术现状。取向钢的发展趋势为:提高(110)[001]晶粒取向度,降低取向硅钢铁损,发展铸坯低温加热(≤1 300℃)和薄板坯连铸连轧流程生产取向硅钢工艺。 Main technology parameters of four developed process:cast bloom higher temperature heating-double cold rolling or single cold rolling,lower temperature heating-double cold rolling or single rolling process for production of common grain oriented silicon steel(CGO) and high magnetic induction grain oriented silicon steel(Hi-B),theory research on grain oriented steel(Goss nucleus and inhibitor) and present situation of process are summarized in this paper.The development trend of grain oriented si... 

通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination... 

【作者】 周威； 刘侃； ...

采用ZMLMC超高梯度定向凝固装置,研究了5种凝固速率(10、35、80、150和450μm/s)对定向凝固50W600无取向硅钢的固液界面稳定性转变规律和一次、二次枝晶间距的影响。研究结果表明,在特定的温度梯度下,随着凝固速率的增加,定向凝固的固液界面由胞状晶转变为胞状枝晶,再转变为细小的树枝晶。随着凝固速率的增加,定向凝固组织的枝晶形貌逐渐细化,一次和二次枝晶间距逐渐减小,且与冷却速率之间都符合指数关系:λ1=151.73×(G L·R)-0.31,λ2=22.07×(G L·R)-0.44。当冷却速率达到4.275℃/s时,一次、二次枝晶间距分别为112μm、14.1μm。 Under the conditions of certain temperature gradient and different solidification rate,the directional solidification experiment of non-oriented electrical steel 50W600 was carried out.The microstructure of 50W600 steel was also analyzed in different solidification rate.The result shows that the solid/liquid interface of the steel undergoes an evolution from cellular,cellular dendrite and finally to fine dendrite morphologies.The dendrite refines gradually and the distance between dendrites decr...