硅钢资料

对两种硅钢水溶性极厚绝缘涂层进行了不同温度的热老化实验。通过TG-DTA,GDS,FT-IR,SEM和光泽度仪等测试方法对老化的涂层进行分析表征,提出了评估硅钢水溶性极厚绝缘涂层热老化性能的合理温度区间,探讨了涂层热老化行为,并分析了两种涂层热老化性能的差异。结果表明,涂层附着性随着老化时间的延长逐渐下降。FT-IR表征结果显示,热老化过程中,涂料交联形成的化学键未发生断裂,交联剂氨基树脂的三嗪环被破坏是聚合物三维网络结构坍塌的主要原因。 Thermal aging expriments at different temperature were carried out on two types of water-soluble and extra-thick insulation coatings for non-oriented silicon steel,and a series of test methods such as glossmeters,TG-DTA,FT-IR,GDS,SEM were applied in analysis.For evaluating the thermal aging effect of this kind of insulation coating,the proper temperature range was proposed.The difference of aging performance between two coatings was been investigated and the related behaviors were been discussed... 

采用光学显微镜、X射线衍射仪等分析了宁波钢铁有限公司生产的取向硅钢不同工序下的组织及织构演变规律。结果表明:铸坯经过热轧后,沿着厚度方向组织不均匀;一次冷轧并经脱碳退火后,组织由条状纤维状变成等轴状的初次再结晶晶粒,初次再结晶平均晶粒尺寸为18.17μm,织构主要以α织构和γ织构为主;在二次冷轧后,晶粒再次被压缩,转变为纤维状,织构主要为γ织构;经过高温退火后,发生二次再结晶,晶粒异常长大,晶粒尺寸达到厘米级,织构成分为单一且锋锐的Goss织构。 The microstructure and texture evolution of oriented silicon steel produced by Ningbo Iron and Steel Co.,Ltd.were analyzed by optical microscope and X-ray diffraction.The results showed that the microstructure of the slab was inhomogenous along the thickness direction after hot rolling.After first cold rolling and decarburizing annealing,the microstructure changed from strip fibrous to equiaxed primary recrystallized grains,and the average grain size of the primary recrystallization microstructu... 

以市场上购买的取向硅钢成品板为原料，经不同压下率冷轧至0.23～0.08 mm不等。借助X射线衍射仪(XRD)检测了冷轧后样品中的织构组分及其含量，利用电子背散射技术(EBSD)测量了试样的取向因子分布情况。观察了孪晶的形貌与晶体学特征，分析了硅钢超薄带的塑性变形行为。结果发现，在平面压缩应力下，{112}<111>滑移系的取向因子较大。随冷轧压下率的增加，Goss织构的含量逐渐减少，{212}<141>织构组分的含量先增加后减少，{111}<112>织构组分的含量逐渐增加，织构组分以{110}<001>→{212}<141>→{111}<112>顺序演变。冷轧后样品中出现了孪晶，其晶体取向为{001}<110>,冷轧过程中孪晶取向没有发生变化。 The commercial finished oriented silicon steel plate as the raw material were rolled to 0.23-0.08 mm. With the X-ray diffractometer(XRD), the texture components and their volume fractions in the cold-rolled samples were detected. And the orientation factor distribution of the cross-section of the samples was measured by the electron backscattering technique(EBSD). The morphology and crystallographic characteristics of twins were observed, and the plastic deformation behaviors of the ultra-thin o... 

取向硅钢因其高磁导率、低矫顽力和大电阻系数等特性，被广泛应用于大中型变压器和大型电动机铁芯的制造。因取向硅钢性能和成分控制严格，生产工艺复杂，故其产品代表了钢铁企业特殊钢生产的最高水平。本文介绍了新钢公司卷板厂1580热连轧线生产取向硅钢过程中出现的窄尺问题，研究了取向硅钢产品的特点，分析了热轧过程中的组织转变，并结合生产实际提出了改进措施。通过对加热炉钢坯加热模式、粗轧轧制策略、精轧轧制工艺、二级模型等方面的优化和改进，取向硅钢窄尺情况明显好转，提高了产品的成材率和市场口碑。 The oriented silicon steel is widely used in the iron core manufacture of large and mediumsized transformers and large motors because of its high permeability, low coercivity and large resistance coefficient. Due to the performance and composition control of oriented silicon steel is strict, the production process is complex,therefore, its products represent the highest level of special steel production in iron and steel enterprises. This paper introduces the problem of narrow gauge in the produ... 

以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in... 

选取了三种50W 800无取向电工钢,分析了化学成分、晶粒尺寸、织构、以及200℃时效处理48 h前后的磁性能和第二相粒子析出状态的变化。结果表明,钢板中第二相粒子的分布密度对钢板铁损有最重要的影响。降低钢中C、N元素含量,或改进钢板热加工参数以降低成品钢板中第二相粒子形成元素的过饱和度均有利于明显降低钢板磁时效过程中的铁损增幅。钢板中对磁性能有利的织构也有利于降低钢板铁损的时效幅度。 The evolution of chemical composition,grain size,texture,as well as magnetic property after aging treatment at 200 ℃ for 48 h and distribution of second phase particles precipitation in three selected 50W800 non-oriented electrical steels were analyzed.The results show that the distribution density of second phase particles has great influence on core loss.Reducing C and N content,or improving hot-working parameters to reduce the supersaturation of elements forming second phase particles in prod... 

依据GB/T 15616—2008《金属及合金的电子探针定量分析方法》,采用电子探针波谱仪对某W600硅钢中的硅含量进行了定量测定,对影响其定量测定结果的不确定度分量进行了分析,并对不确定度的各个分量进行了计算和合成,最后给出了硅钢中硅含量测定结果的不确定度报告:该硅钢中的硅含量(质量分数)为1.50%,扩展不确定度U=0.20%,取包含因子k=2。 According to GB/T 15616-2008\"Quantitative Method for Electron Prohe Microanalysis of Metals and Alloys\",the quantitative results of Si content in some W600 silicon steel was measured hy EPMA-WDS.The uncertainty components which might affect the measurement results were considered,calculated and synthesized. Finally the uncertainty result for the quantitative value of Si content in the silicon steel was got.The mass content of Si was 1.50%,and expanded uncertainty U=0.20%under the condition of co... 

【机构】 商务部进出口公平贸易局； ...

【作者】 张正贵； 李战库； ...

通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows... 

研究的两种取向硅钢（%:No1-0.042C、3.16Si、0.009Al、0.07Mn、0.50Cu、0.015S、0.0084N和No2-0.040C、3.20Si、0.014Al、0.22Mn、0.49Cu、0.016S、0.008 2N）由50 kg真空感应炉冶炼,锻成（mm）350×120×35板坯,经1 250℃30 min加热,开轧温度1 100℃,5道次热轧成2.3 mm板,终轧温度950～1 000℃。实验结果表明,两热轧板沿板厚方向存在组织和织构的不均匀性,热轧板次表层为再结晶组织,有较强的Goss织构组分;中心层为形变组织,具有典型的形变织构。含0.22%Mn的No2钢次表层{110}〈001〉织构组分比含0.07%Mn的No1钢弱,中心层{001}〈110〉织构组分大大强于0.07%Mn No1钢,导致两者磁性能差异,0.22%Mn No2钢磁感应强度(B₈₀₀)和铁损(P_1.7/50)分别为1.87 T和1.24 W/kg,0.07%Mn No1钢分别为1.88 T和1.18 W/kg。 Studied both grain-oriented silicon steels（%:No1- 0.042C,3.16Si,0.009Al,0.07Mn,0.50Cu, 0.015S,0.0084N and No2-0.040C,3.20Si,0.014Al,0.22Mn,0.49Cu,0.016S,0.0082N） are melted by a 50 kg vacuum induction furnace,forged to（mm） 350×120×35 slab,heated at 1 250℃for 30 min,with beginning rolling temperature 1 100℃hot-rolled to 2.3 mm plate by 5 passes,finishing-rolled at 950～1000℃.Test results show that the structure and texture along thickness of both hot-rolled plates are inhomogeneous:the subsurface ... 

结合工业化生产过程中出现的同卷带钢头、尾磁性能差异现象,对50SW1300牌号无取向硅钢同卷带钢头、尾试样的夹杂物、晶体织构和显微组织进行了分析研究。结果表明,夹杂物、晶体织构是影响成品钢卷磁性能的重要因素。夹杂物是造成同卷带钢头、尾铁损差异的主要原因。夹杂物数量越多,尤其是小尺寸的夹杂物数量越多,对成品带钢的磁性能影响越大,对于本试验而言,AlN和MnS是影响成品带钢磁性能的主要夹杂物。晶体织构是造成同卷带钢头、尾磁感应强度差异的主要原因。有益的{100}和Goss织构含量越大,有害的{111}<110>和{111}<112>织构含量越小,即有益织构与有害织构含量比越大,成品带钢的磁感应强度越大。 Based on the industrial manufacture of non-oriented silicon steel sheets 50SW1300, the magnetic property variation of head and tail of the same finished steel sheets was discussed by analyzing non-metallic inclusion, crystal texture, and microstructure. Results show that, both of the non-metallic inclusion and the crystal texture will affect the magnetic properties significantly. The non-metallic inclusion is the key factor of the core loss variation of head and tail of the same finished steel s...