硅钢资料

研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ... 

通过热力学计算及实验室研究,对钙处理前后50W600无取向硅钢退火冷轧板中夹杂物的类型、数量及尺寸进行了系统分析。结果表明,50W600无取向硅钢经钙处理后(w(Ca)=0.002 6%),钙在1 600℃的钢液中主要以固态的CaO·2Al2O3、CaO·6Al2O3及溶解钙的形式存在。在钢液的凝固过程中,钢中的溶解钙和硫反应生成了CaS和CaS-MnS复合夹杂,有效抑制了MnS的弥散析出,减少了钢中微细夹杂物的数量。同时钙处理促进了钢中微细夹杂物的聚合长大,导致显微夹杂物的数量增加。 Based on thermodynamic calculation and laboratory experiment,the type,quantity and size of inclusions in annealed cold-rolled steel sheets of 50W600 non-oriented silicon steel before and after calcium treatment were systematically studied.Results showed that after calcium treatment(w(Ca) = 0.002 6%),calcium was mainly in the form of CaO·2Al2O3,CaO·6Al2O3 and dissolved calcium in steel at 1 600 ℃.Dissolved calcium could combine with sulfur to form CaS inclusions and compound CaS-MnS inclusions du... 

通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo... 

试验研究了球刻痕法对高磁感取向硅钢的铁损、矫顽力、相对磁导率、巴克豪森噪声等磁学性能的影响.研究结果表明:经过球刻痕处理后,高磁感取向硅钢的铁损明显降低,矫顽力下降,8 mm球刻痕过后铁损值与矫顽力分别下降16.2%和14.7%,且铁损和矫顽力均随刻痕间距降低而减少.刻痕后的高磁感取向硅钢磁导率在高磁感应强度下明显上升,刻痕后巴克豪森噪声值明显降低,经过对比分析确定8 mm为球刻痕的最佳刻痕间距.从磁畴观察、细化磁畴的原理等方面解释了细化磁畴对高磁感取向硅钢性能的影响原因. The effects of the ball scribing on magnetic properties of high permeability grain-oriented silicon steels,including the iron loss,coercive force,relative permeability,and Barkhausen noise were investigated. The results showed that the iron loss and coercive force of the high permeability grain-oriented silicon steels apparently decreased 16. 2% and 14. 7% respectively after 8 mm ball scribing and they both decreased with the decrease of the scribing spacing at the same magnetic flux density. At... 

对取向硅钢在不同气氛下的高温退火工艺进行实验室模拟，利用X射线衍射仪（XRD）分析了硅钢退火至900℃和1170℃时的样品表面氧化层和底层的物相组成，采用场发射扫描电镜（SEM）观察了样品表面氧化层和底层在截面方向上的微观形貌特征，并计算了高温退火一次升温阶段氧化反应的吉布斯自由能以及900℃时退火气氛的氧分压。结果表明：当退火气氛的露点温度保持一定时，较高的氢气含量有利于生成完整连续的底层；当退火气氛的水氢分压比保持一定时，在露点温度与氢气含量两者较低的条件下，底层附着性不佳易脱落，较高条件下，底层中夹杂着较多的铁单质；当氧化层中无FeO时，底层完整连续但易脱落，当FeO层较薄时，底层下方存在部分未反应的SiO₂,当FeO层较厚时，底层不完整连续且有分层。 The high temperature annealing process of grain-oriented silicon steel in different atmospheres was simulated in the laboratory. X-ray diffractometer（XRD） was used to analyze the phase compositions of the surface oxide layer and forsterite film of the silicon steel annealed to 900 ℃ and 1170 ℃. Field-emission scanning electron microscopy（SEM） was used to observe the micro morphology characteristics of the surface oxide layer and forsterite film of the samples in the cross section direction. The ... 

研究了激光加热辅助圆盘剪高速切割技术,以解决现有冷轧生产线硅钢切边技术存在的微裂纹、应力、毛刺和边浪等问题。建立了激光加热温度场有限元分析模型,根据生产线上圆盘剪加工的实际过程,探讨了数值模拟中热源的加载形式,研究了激光对板材进行辅助加热时各个工艺参数如激光功率、光斑尺寸以及激光入射角度对切割工艺的影响,并通过实验对工艺参数进行了优化。最后,进了验证实验。实验结果显示:当激光加热点运动至圆盘剪刃口位置时,温度为100℃左右,此时材料硬度降低到原有硬度的70%~80%,降低了切削力,减少了圆盘剪的磨损,可有效提高圆盘剪的寿命。 Laser assisted trimmer side cutting technology was studied to overcome the problems such as micro cracks,stress,burrs and edge waves existing in a cold rolling production line of silicon steel side cutting.A finite element analysis model for the laser hearting temperature field was established, the loading form of a heating source was determined and influences of various processing parameters like laser powers,spot sizes,and laser incident angles on laser assisted heating sheet materials were di... 

分析了高转矩和高转速条件下高效驱动马达铁芯材料对无取向硅钢磁性能要求,讨论了无取向硅钢的高磁通密度和低铁损对电机转矩和效率的影响,介绍了国内外高磁感无取向硅钢发展情况。在生产工艺上,提高钢质纯净度,弱化夹杂物和第二相粒子对畴壁移动和再结晶晶粒长大的钉扎作用,添加微量晶界和带钢表面的偏析元素促使有利织构发展等技术可提高无取向硅钢的磁通密度。 The requirements of high efficient drive motor core materials under the conditions of high torque and high speed were analyzed.The effects of high magnetic flux density of non-oriented silicon steel on the torque and efficiency of the motor were discussed.The development of non-oriented silicon steel with high magnetic was introduced.The magnetic flux density of non-oriented silicon steel sheet can be obviously improved by some production technologies,such as purification steel,weakening the pin... 

【作者】 严伟明； ...

通过后天抑制剂获得法制备了取向硅钢,对渗氮前后和高温退火升温阶段析出物的析出和转化规律进行了研究。研究结果表明,渗氮前脱碳退火态基体中存在少量的粗大AlN颗粒和细小AlN颗粒,渗氮处理后新析出大量的Si3N4析出物,高温退火升温阶段Si3N4将转化为(Al,Si)N,随着温度的继续升高(Al,Si)N颗粒将发生粗化,(Al,Si)N是后天抑制剂获得法制备取向硅钢的主要抑制剂。 Grain-oriented silicon steels were produced by acquired inhibitor method.The rule of precipitate transformation was studied after nitriding treatment and high-temperature finishing annealing.The results show that a small amount of large AlN and fine AlN are found in matrix before nitriding treatment,and a large amount of Si3N4 is precipitated in matrix after nitriding treatment.During the temperature rising period of high-temperature finishing annealing,Si3N4 would transform into(Al,Si)N,and(Al,... 

【作者】 朱一知； 陈山； ...

承钢采用铁水预处理(脱硫)→转炉提钒→转炉冶炼→RH精炼→连铸→轧制工艺,成功研发了无取向电工钢CGW800。试制的CGW800钢碳含量≤0.006 0%、氮含量<0.004 0%,热轧后的金相组织为铁素体和少量渗碳体,晶粒度5.5级,获得了较粗大、均匀的晶粒,钢板的成分和力学性能达到了标准要求。 In Cheng Steel,the CGW800 non- oriented electrical steel is successfully developed with process of hot metal pre- treating,vanadium extracting with converter,smelting with converter,RH refining,continuous casting and rolling. In the steel,the carbon content is not higher than 0. 006 0%,nitrogen less than0. 004 0%,the metallographic structure after hot rolling is ferrite and a little amount of cementite,grain size is 5. 5 degree,relative large and even grain got. The composition and mechanical pr... 

高强无取向硅钢主要应用于高速电机，要求其具备高强度和优异磁性能，但目前无取向硅钢的磁性能和强度难以兼顾。因此，设计并制备了添加微量Cr的含Nb高强无取向硅钢，通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明，添加质量分数为0.5%的Cr抑制了热轧组织的回复，使常化和退火组织再结晶减弱，常化和退火后有利织构面积分数增加，不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大，磁感略升高，但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用，另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强；而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成，使得织构因子增大；添加Cr使无取向硅钢的电阻率增加从而使铁损降低，同时Cr促进了Nb的析出，而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高，在两方面因素的综合作用下，添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此，... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren...