硅钢资料

含铜抑制剂作为取向硅钢的主抑制剂或辅助抑制剂不仅可以抑制初次晶粒的长大,促进二次再结晶,还可以降低铸坯的加热温度。取向硅钢中主要抑制剂为10～50 nm Cu₂S,在钢的铸坯、热轧、冷轧、脱碳等工艺过程均可析出;（Cu,Mn）_1.8S、Cu_1.8S、ε-Cu等主要作为辅助抑制剂,尺寸一般为30～50 nm（或大于50 nm）,主要在热轧阶段析出。总结了国内外有关取向硅钢中含铜抑制剂析出行为的研究进展,当前主要研究不同生产流程和工序中含铜抑制剂的析出行为和作用机理。 As main inhibitor or auxiliary inhibitor for grain-oriented silicon steel,the particles of inhibitor bearing copper not only inhibit the primary crystal growing and promote the secondary recrystallization,but also decrease the heat temperature of casting slab.The main inhibitor for grain-oriented silicon steel is 10～50 nm Cu₂S,which precipitate in process and procedure including steel casting slab,hot rolling,cold rolling and decarburizing process,while the 30～50 nm or more than 50 nm... 

本实用新型涉及一种便捷型铁芯硅钢片组装系统。该便捷型铁芯硅钢片组装系统包括硅钢片叠放装置，硅钢片叠放装置包括固定座，固定座上通过轴承转动装配有齿圈，固定座上固定连接有与齿圈同轴的固定盘，固定盘的中心设有中心孔，固定盘上设有六个沿固定盘径向延伸的滑槽，六个滑槽沿固定盘周向均匀分布，每个滑槽内分别滑动装配有滑块，齿圈的上侧面设有上螺纹，滑槽的下侧面设有与上螺纹相匹配的下螺纹，滑块的内端设有定位板，定位板的外侧面上设有用于与硅钢片中心孔孔壁上的割槽相匹配的定位条。相比于现有技术，本实用新型能够对硅钢片进行定位，从而确保各片硅钢片的中心孔以及割槽相对应，提高了硅钢片叠放效率，从而提高了生产效率。

研究了硅钢铸坯再加热过程中夹杂物的析出行为。采用非水溶液电解提取+扫描电镜观察方法,观察了试样的显微组织,统计了夹杂物的尺寸、种类、数量、分布。结果表明,均热温度为1 523 K时,水淬试样的夹杂物尺寸绝大部分小于0.5μm,0.5～5.0μm的夹杂物数量很少,没有发现5.0μm以上的夹杂物。此外,均热时间为10、30、60、90、120、240 min时,对应试样中0.05～0.2μm的夹杂物数量分别为4.04×104、4.73×104、3.70×104、3.33×104、3.10×104、1.56×104个/mm3。绝大部分夹杂物以MnS、AlN、CuxS类为主,并以三类夹杂物中的两类复合或三类复合居多。三类复合夹杂物总量占每组试样夹杂物总量的90%或以上。随均热时间延长,典型的夹杂物组成会发生如下变化:MnS+AlN+CuxS MnS+AlN AlN。与此同时,MnS、AlN、CuxS三者复合比例从45.2%(均热10 min)降为9.7%(均热240 min)。 The methods of electrolysis extraction from nonaqueous solution and scanning electron microscope were adopted to study the precipitation behavior of non-metallic inclusions in Si steel slabs during reheating processes.The morphologies,chemical compositions,quantity and size distribution of non-metallic inclusions in these steel samples were analyzed.Results show that,when the soaking temperature is 1 523 K,almost all of the non-metallic inclusions are smaller than 0.5 μm,few are in the range of ... 

本发明提出了一种可修饰取向硅钢表面的无铬无机绝缘涂料及其制备方法，该涂料按照重量份计包括以下组份：磷‑硅溶胶40‑70份、钛改性增稠剂预溶胶25份、抑泡剂0.2‑1份、流平剂0.05‑0.2份和去离子水3.8‑34.75份。该涂料的制备方法为：先制备磷‑硅溶胶和钛改性增稠剂预溶胶；然后向磷‑硅溶胶中加入抑泡剂并搅拌均匀；再加入去离子水并搅拌均匀；再分次缓慢加入钛改性增稠剂预溶胶并搅拌均匀；最后加入流平剂并搅拌均匀。本发明所制备的无铬无机绝缘涂料可修饰取向硅钢表面瑕疵露晶等形貌缺陷；在取向硅钢表面形成的绝缘涂层具有良好的附着力和耐热性；涂料采用的原料均为无污染的环保材料，解决了含铬绝缘涂料带来的环境危害。

本实用新型公开了硅钢片生产用上料装置，属于硅钢片生产领域，包括本体，所述本体包括侧板和U型板，所述侧板固定连接在U型板的一侧，所述本体的顶部横向设置有平移机构，所述平移机构上安装有气缸，所述气缸的底部安装有吸盘，所述U型板内腔的底部竖向固定连接有弹簧，所述弹簧远离U型板的一端水平固定连接有升降板，所述平移机构包括电机、螺纹杆、限位板和移动块，所述电机安装在侧板的顶部，所述电机的输出轴与螺纹杆的一端固定连接，通过设置弹簧，在第一个物料从上料装置移出后弹簧的弹力推动剩余物料，使得剩余物料进行上升，避免吸盘触碰不到物料的问题，简化吸盘移动轨迹，加快上料速度。

通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination... 

本发明公开了一种可替代高磁感取向硅钢常化退火的热处理方法。该方法包括对所述取向硅钢的铸坯依次进行热轧、酸洗和冷轧，省去了常化酸洗工序中的常化退火工艺。所述热轧工序包括加热、粗轧和精轧过程，所述精轧过程中，热轧板离开精轧机最后一个机架时的温度达到1000～1050℃；或者，所述酸洗工序后，对热轧板进行通电加热至1000～1050℃；然后，对热轧板采用短时通电加热控制冷却速度，通电加热2‑5s使热轧板的温度降至940～960℃。采用该热处理方法得到高磁感取向硅钢常化板等效织构，满足生产高磁感取向硅钢的织构组分条件，其简化了高磁感取向硅钢的制造工艺，降低了生产成本和能耗，提高了生产效率。

采用火花源原子发射光谱分析测定电工钢中超低C,研究试样制备方法、Ar纯度和压力等条件对分析结果的影响,并对工作曲线进行了优化,实现了一次分析同时测定电工钢的多种元素,满足炉前和精炼在线分析的要求。 Ultra-low carbon in electrical steel is determined with spark-source atom emission spectrum.It is researched the influence of sample making method,purity of Ar,and pressure on analysis result.The work curve is optimized.The determination of many elements in electrical steel only in one analysis is realized.It meets demands of on-line analysis for blast furnace and refining. 

针对新能源汽车的发展，制备了含Ni固溶强化、含Cu析出强化以及含Ni+Cu复合强化3%Si无取向硅钢，研究了强化方式对无取向硅钢组织、织构和性能的影响。结果表明：固溶强化型无取向硅钢热轧板中形成了粗大{221}<221>晶粒，冷轧过程中剪切变形明显并在退火后形成良好再结晶织构。析出强化型无取向硅钢热轧板中心层形成γ取向粗大晶粒，在后续的加工中γ织构逐渐增强并最终得到相对细小的再结晶晶粒。复合强化型无取向硅钢热轧板中保留了强λ取向带状组织，退火后形成了有益的Goss织构和λ织构。固溶强化型与复合强化型无取向硅钢磁感应强度B₅₀分别达到1.742、1.688 T,高于析出强化型无取向硅钢的1.645 T。同时，复合强化型无取向硅钢高频铁损最低，其P_1.0/400和P_{1.0/1 000}分别低至20.97、82.69 W/kg,这与其较小的晶粒尺寸和织构改善有关。强度计算结果表明：Ni元素固溶强化对强度的提高有限，屈服强度为468 MPa,纳米Cu析出可显著提高屈服强度（强度增量约200 MPa）,且主要来自于模量强... For the development of new energy vehicles, 3%Si non-oriented silicon steel were processed by solid solution strengthening with Ni, precipitation strengthening with Cu, and composite strengthening with Ni and Cu. The effects of different strengthening methods on the microstructure, texture and properties of high-strength non oriented silicon steel were studied.The results show that coarse {221}<221> grains are formed in the hot rolled sheet of solution strengthened non-oriented silicon ste... 

采用双辊薄带连铸工艺制备了厚度为2.4mm的3.98%Si-0.71%Al无取向硅钢带,经常化、冷轧、不同温度退火后,对其显微组织、析出物、织构和磁性能进行了检测分析。结果表明:随着退火温度的提高,退火板晶粒尺寸增大,组织均匀性提高;退火板析出物主要是AlN和MnS与AlN复合析出物,尺寸较粗大,达0.5~2.5μm;退火板织构沿厚度方向变化明显,表层和1/2层存在较强的{100}织构,1/2层还存在较强的{111}织构,1/4层主要是{112}织构;随退火温度的升高相应的铁损和磁感应强度均降低。 Using twin roll thin strip continuous casting technique,the 3.98%Si-0.71%Al no-oriented silicon steel strip in thickness of 2.4mm was produced.The microstructure,precipitates,texture,and magnetic properties of the sheet after normalizing,cold rolling and annealing at different temperatures were studied.The results show that with annealing temperature increase,the grain size and uniformity of annealed sheet increased.The main precipitates in coarse size of 0.5-2.5μm in annealed sheet were AlN and... 

对新能源汽车以及驱动电机的现有市场和未来市场规模进行梳理分析，通过自建计算公式推导出我国2021年1-11月份驱动电机用电工钢的总量，进而预测未来10年中国新能源汽车驱动电机用电工钢情况，为无取向电工钢的生产和在电机中的应用提供有价值的参考。 The current market and future market size of new energy vehicles and traction motors were analyzed,and the total amount of electrical steels used in traction motors in China from January to November 2021 was derived by using self-built calculation formulas,and then the situation in the next ten years of electrical steel used in traction motors of new energy vehicles in China was predicted.It will provide a valuable reference for the production of non-grain oriented electrical steel and its appli... 

综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i...