硅钢资料

本发明公开了一种硅钢片漆，该硅钢片漆采用特定的聚酰胺酰亚胺乳液制备，通过使偏苯三酸酐与组合形式的双端氨基化合物反应，添加三乙胺进一步提升反应进行的程度，并赋予整体更好的柔性和韧性，而磷酸三丁酯能够进一步通过物理改性改善体系的韧性，之后蒸出全部的有机溶剂，并添加一定量的水溶性有机溶剂，然后加入组合形式的活化剂，混合，再滴入水，形成稳定的乳液，最后添加双马来酰亚胺封端剩余的活性基团，该硅钢片漆不仅可以采用水作为主体溶剂，提升了环保型，而且还兼具耐高温、高粘结强度、电气性能强等优点，并有好的环境抗性与施工性能。

利用OM,TEM,EDS与XRD技术,对Fe-3.15%Si低温取向硅钢热轧板不同常化处理后的显微组织、析出相及最终产品的磁性能进行了分析研究,并对热轧板和常化板经过冷轧后的冷轧板织构进行了对比分析.结果表明,采用1120℃保温3 min二段式冷却的常化处理工艺,常化板表层显微组织均匀,沿板厚方向的显微组织的不均匀性显著,对后续过程中形成高取向的Goss织构最有利,取向硅钢的磁性能最高;采用二段式冷却的常化冷却工艺最优,在此冷却工艺下析出的细小的析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利;热轧板、常化板经过冷轧后的冷轧板织构均主要由{111}〈110〉和{111}〈112〉织构组成,但常化板较热轧板冷轧后的冷轧板γ取向线织构密度明显增高,由此可以证实常化处理有助于取向硅钢最终获得高取向的Goss织构. The decreasing of slab heating temperature for grain-oriented silicon steel will reduce the amount of precipitates in hot rolled plate,and be disadvantage to the formation of ultimate Goss texture.The aim of normalizing is to control and adjust the amount,size and distribution of precipitates.Microstructures,precipitates and magnetic characteristics of finished products with different normalizing technologies for Fe-3.15%Si low temperature hot rolled grain-oriented silicon steel are researched,a... 

无取向硅钢特别是中牌号以上的无取向硅钢,随着含硅量的提高,常温下塑性较差,冷轧过程中轧制力明显提高,如果存在原料质量问题,极易发生断带事故,影响硅钢冷轧过程的成材率和生产效率。通过优化冷轧工艺参数,可提高冷轧稳定性。生产中通过合理分配冷轧各道次压下量和轧制速度,保证了轧制过程的稳定,很大程度减少了冷轧断带事故的发生。 Non-oriented silicon steel, especially in the low and middle grade, with the increase of silicon content, plasticity is poor at room temperature, rolling force in cold rolling process significantly improved .If there is the quality defect of raw materials , easily sheet is rolling off. Affect finished product rate and production efficiency in process of cold-rolled silicon steel. Through optimization of cold rolled process parameter , improve the stability of cold-rolling process. Through reason... 

取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}～{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot... 

在实验室试制了TSCR流程的低碳低硅无取向硅钢,研究了在850～1050℃不同温度常化对冷轧量0.5mm厚钢板再经950℃×7min退火后的组织、织构和磁性能的影响。结果表明:随常化温度的升高,使热轧板晶粒尺寸增大,晶界更清晰,组织均匀性更好;由于第二相AlN和MnS析出物尺寸比较大,使冷轧退火后钢板晶粒也随常化温度升高呈单调增大趋势;γ有利织构和{111}、{112}不利织构与常化温度升高同时增强,但前者增强更多;冷轧板退火后铁损随常化温度升高呈单调下降,磁感呈单调上升趋势。 The low-carbon and low-silicon non-oriented silicon steel was prepared by thin slab casting and rolling(TSCR) in lab.The effect of normalizing at different temperatures in 850-1 050℃on microstructure, texture and magnetic properties of 0.5 mm cold-rolled sheets after annealing at 950℃for 7 min was researched. The results show that with increasing the normalizing temperature,the grain size of hot-rolled sheets increased,the grain boundaries were more clear and the rnicrostructure uniformity was b... 

本实用新型公开了一种具有柔性压料机构的飞剪式硅钢剪床，压料机构包括对称设置的支板和侧板，两个侧板位于两个支板之间，且两个侧板位于传送系统传送带顶部的左右两侧，两个支板通过回位组件在底板的顶部进行转动，本实用新型涉及剪床技术领域。该具有柔性压料机构的飞剪式硅钢剪床，通过设置压料机构，当带状硅钢发生跑偏时，其侧边会对一侧的侧板施压，受压的侧板对其连接的弹簧进行压缩，弹簧弹力抵消硅钢跑偏的侧向力，通过侧板推动硅钢复位，且压辊会对硅钢进行平复压实，从而避免了带状硅钢因跑偏而造成剪切尺寸不合格，通过上述结构的组合解决了现有的硬性压料装置容易导致带状硅钢在传送时发生形变的问题。

本发明提供了一种强磁性取向高硅钢极薄带及其制备方法，属于电工钢制造领域，所述强磁性取向高硅钢极薄带包括以下质量百分比的元素：C：0.0045％～0.0060％、Si：4.5％～5.0％、Mn：0.23％～0.32％、S：0.02％～0.03％、Bi：0.03％～0.08％、Als：0.027％～0.035％、Cu：0.02％～0.03％，N：0.008％～0.010％，P＜0.005％，其余为铁，其中所述Cu、S、N元素在熔炼时以含硫氮和铜的多核配位化合物的方式加入所述高硅钢；本发明通过对取向高硅钢的原料组分进行设计，采用含硫氮和铜的多核配位化合物和Bi元素作为合金抑制剂，所制得的强磁性取向高硅钢极薄带晶粒细小，组织均匀，具有高磁感应强度，低铁损的优良磁性能。

本发明涉及一种常化后免酸洗生产取向硅钢的方法，取向硅钢的生产工艺路线为：冶炼→连铸→热轧→常化退火→拉伸矫直→抛丸→冷轧→脱碳退火→渗氮→涂MgO→高温退火→热拉伸平整及涂绝缘膜；本发明在常化退火后通过物理方法去除带钢表面的氧化铁皮，且效率高、效果好、操作简单、易于控制；与常规工艺相比，省去了酸洗及后续废酸处理工作，排除了酸雾对环境的污染，消除了取向硅钢带因酸洗而产生的潜在缺陷，产品质量更加稳定可靠。

本发明公开了一种利用取向硅钢氧化镁废弃物生产镁质球团的方法，采用取向硅钢生产过程中的废氧化镁污泥、废氧化镁粉等氧化镁废弃物，以及粗粒铁矿粉、镜像赤铁矿、磁铁精矿、膨润土和石灰石粉为原料，依次经预处理、配料、造球后，再在链箅机‑回转窑‑环冷机上进行干燥预热、焙烧和冷却，得到镁质球团。本发明利用氧化镁废弃物制备镁质球团，既有利于减少氧化镁废弃物带来的环保压力及其外运时产生的处置费用，也能显著降低镁质球团的制造成本，综合利用了钢铁厂的现有资源，生产出环境友好、低成本的镁质球团，为高炉提供优质原料，最终降低炼铁过程的污染物排放，减少环境污染。

以市场上购买的取向硅钢成品板为原料，经不同压下率冷轧至0.23～0.08 mm不等。借助X射线衍射仪(XRD)检测了冷轧后样品中的织构组分及其含量，利用电子背散射技术(EBSD)测量了试样的取向因子分布情况。观察了孪晶的形貌与晶体学特征，分析了硅钢超薄带的塑性变形行为。结果发现，在平面压缩应力下，{112}<111>滑移系的取向因子较大。随冷轧压下率的增加，Goss织构的含量逐渐减少，{212}<141>织构组分的含量先增加后减少，{111}<112>织构组分的含量逐渐增加，织构组分以{110}<001>→{212}<141>→{111}<112>顺序演变。冷轧后样品中出现了孪晶，其晶体取向为{001}<110>,冷轧过程中孪晶取向没有发生变化。 The commercial finished oriented silicon steel plate as the raw material were rolled to 0.23-0.08 mm. With the X-ray diffractometer(XRD), the texture components and their volume fractions in the cold-rolled samples were detected. And the orientation factor distribution of the cross-section of the samples was measured by the electron backscattering technique(EBSD). The morphology and crystallographic characteristics of twins were observed, and the plastic deformation behaviors of the ultra-thin o... 

在实验室模拟CSP工艺条件下制备了取向硅钢,研究了二次冷轧中间退火工艺对组织和织构的影响。结果表明,中间退火温度对取向硅钢脱碳,高温退火组织及织构均产生明显影响。经940℃中间退火后,取向硅钢脱碳再结晶晶粒较850℃中间退火的多,且再经高温退火处理后,晶粒粗化,最大晶粒尺寸达4.8 mm;高斯织构组分密度达27.00,较850℃中间退火试样高。 Grain-oriented silicon steel was prepared by simulated CSP technology in laboratory. Effects of secondary cold-rolled intermediate annealing on microstructure and texture were studied. The results show that intermediate annealing has obvious effects on the microstructure and texture of the steels after decarburization annealing and high temperature annealing. After intermediate annealing at 940 ℃,recrystallized grain of decarburization annealed steel is more than that of intermediate annealed at... 

以水氯镁石为原料,采用氨法沉镁-煅烧-添加剂的方法制备硅钢级氧化镁。考察了反应温度、反应pH值、陈化时间对中间体氢氧化镁纯度及转化率的影响;研究了煅烧温度和煅烧时间对氧化镁水化率的影响及添加剂的量对氧化镁悬浮性能的影响。控制实验条件为:反应温度55℃,pH值为9.5,陈化时间2h,煅烧温度1050℃,煅烧时间2h,添加剂量为0.8%,制得氧化镁的纯度为98.99%、水化率为2.92%、悬浮性能为3mm/h,达到硅钢级氧化镁的要求。 Using bischofite as raw material,the preparation of magnesium oxide with silico-steel grade was studied.The effects of reaction temperature,reaction pH value and aging time on the intermediate magnesium hydroxide purity and conversion rate were studied.Calcinations temperature,calcinations time relationship to the hydration rate of MgO and amount of additive to the suspension performance of MgO were investigated.The results indicated that the optimum technological conditions were as follows:reac...