硅钢资料

对低温加热工艺生产的普通取向(common grain-oriented,CGO)硅钢的高温退火过程进行了中断实验,材料为含3.0%Si、0.5%Cu、0.009 8%S(均为质量分数)的以Cu2S为主抑制剂的普通取向CGO钢。原始板坯厚度为230 mm,于1 200℃均热后经4道次粗轧、7道次精轧至2.3mm;热轧板采用两次冷轧法轧至0.3mm,中间完全脱碳退火,最后于1 200℃高温退火。最后样品的磁性能:铁损P17/50为1.182W/kg,磁感应强度B8为1.897T。借助配有EDAX OIM电子背散射衍射(EBSD)系统的ZEISS SUPRA 55VP扫描电子显微镜,对高温退火过程中高斯晶粒的演变进行了研究,结果表明:升温过程中晶粒尺寸增长缓慢,650℃时取向分布函数(ODF)图出现高斯织构组分,但强度很弱,高斯晶粒偏离角小于9°;950℃时高斯晶粒平均生长速度超过其他晶粒;950~1 000℃时高斯晶粒异常长大,偏离角降至约3°;在950℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势。 The high-temperature annealing process of common grain-oriented(CGO)silicon steel was investigated by interrupting test.The samples were rolled from CGO silicon steel slab under low reheating temperature.The CGO silicon steel,taking Cu2S as the main inhibitor,contains3.0%Si,0.5%Cu,and 0.0098%S.The original casting slab is 230mm in thickness.After 1 200℃reheating,four-pass rough rolling and seven-pass finish rolling were conducted to make the thickness of the slab get to 2.3mm.Then the hot rolled... 

通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows... 

【作者】 周威； 刘侃； ...

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

研究了冷轧95%变形量无取向硅钢不同退火温度(710～1 050℃)下再结晶织构特征.再结晶刚完成时(710℃退火),呈现强γ({111<112>～<134>)与弱{114}<481>织构特征;随退火温度升高至900℃,γ明显减弱,{114}<481>组分持续增强,形成典型的{h,1,1}<1/h,1,2>织构;进一步升温至1 050℃,再结晶织构不再发生明显变化.基于EBSD分析,{114}<481>组分的持续强化可归因于其明显的尺寸优势以及较高频率的高能晶界(取向差角为20°～45°). A non-oriented silicon steel was heavily rolled to 95% reduction and subsequently annealed at 710~1 050 ℃ to investigate recrystallization texture evolution.When annealed at 710 ℃ with complete recrystallization,the texture is characterized by a strong partial γ fiber spreading from {111}<112> to {111}<134> and a weak {114}<481> component.As annealing at 900 ℃,γ fiber is decreased significantly while {114}<481> is increased consistently,producing a typical {h,1,1}<1/h,... 

主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t... 

研究了罩式炉常化工艺对50W350硅钢热轧板组织、夹杂物和性能的影响。研究结果显示，罩式炉常化工艺在温度一定的情况下，随着保温时间延长，硅钢晶粒逐步再结晶并长大，同时析出物也在聚集长大。通过制定合理的罩式炉常化工艺，可以实现硅钢晶粒的再结晶和长大，从而达到连续退火炉常化工艺产品技术要求。 The influence of normalization process with a bell furnace on the structure,inclusions and properties of 50W350electrical steel hot-rolled sheet was studied.The research results showed that:when the steel was normalized at a certain temperature in the bell furnace,the silicon steel grains gradually recrystallized and grew up with the extension of the annealing holding time,and at the same time,the precipitates also gathered and grew up.The recrystallization and growth of the silicon steel grains... 

晶界和{100}柱状晶在硅钢生产过程中对织构的遗传和演变有关键作用,因此本文利用晶体塑性有限元方法进行立方和旋转立方取向双晶在晶界不同位向时晶体取向演变的全场模拟。模拟显示,三种晶界位向下,晶界都具有诱发晶内产生S形状形变不均匀和缓解局部形变不均匀区取向转动的特点,立方和旋转立方取向双晶在带有剪切作用的轧制条件下都显示明显的取向稳定性。GB⊥RD(表示晶界垂直于轧向)晶界位向时,旋转立方取向晶粒优先在晶界中心位置发生取向转动,而立方取向则优先在远离晶界的端部发生取向转动。GB⊥TD(表示晶界垂直于横向)的晶界位向下,其晶界阻碍作用最小,双晶内产生的取向漫散度大,织构强度较低;除绕TD转动外,也具有复杂的绕RD、ND的取向转动。GB⊥ND(表示晶界垂直于法向)的晶界位向下,取向转动与GB⊥RD时相近,但有少量取向绕ND转动。 Grain boundaries and initial{100}columnar grains play a key role in the inheritance and evolution of texture in the production of electrical steels.In this paper,the crystal plasticity finite element method was used to simulate the grain orientation evolution of cube and rotated-cube oriented bicrystals when grain boundary was set to different orientations.It was shown that the grain boundary in three grain boundary orientations demonstrated the characteristics of inducing Sshape deformation inh... 

通过热力学计算与模拟试验研究了含钒钛取向硅钢中氮化物析出相的析出规律与析出行为,并探讨了含钒钛元素的氮化物析出相作为薄板坯连铸连轧流程制备取向硅钢中辅助抑制剂的可行性.研究表明,在所冶炼的含钒钛取向硅钢的成分范围内,Ti N在钢液凝固末期便具备析出的热力学条件,而Al N与VN只可能在凝固后的α+γ或α+Fe3C两相区内析出.含钒钛取向硅钢中氮化物析出相以成分复杂的复合析出相为主,且随着钒钛加入量的增加,钢中抑制剂析出相总的分布密度由于含钒钛元素的氮化物析出相的增加而明显提高,使抑制剂抑制初次再结晶晶粒正常长大的能力得以加强,最终成品的磁感应强度值B8由1.857 T提升至1.898 T.同时,加入不高于0.007%的Ti与不高于0.005%的V不会影响中间脱碳退火工序的脱碳效果以及高温退火净化阶段硫、氮的脱除效果,其形成的含钒钛元素的纳米级氮化物析出相适合作为薄板坯连铸连轧流程制备取向硅钢的辅助抑制剂. The precipitation behavior of nitride precipitates in grain-oriented silicon steel containing vanadium and titanium elements produced by thin slab casting and rolling process was studied by thermodynamic calculation and simulation experiment. The feasibility of nitride precipitates containing V and Ti elements as auxiliary inhibitors was also investigated. It is found that Ti N is likely to precipitate at the final stage of solidification in the grain-oriented silicon steel,but VN and Al N can p... 

采用X-射线衍射分析技术测定了取向硅钢热轧板在不同压下率下不同厚度处的织构。结果表明,在压下率低于80%的情况下,几乎所有试样的不同厚度处的织构均为旋转立方织构类型{100}<011>,但不同压下率、不同厚度处的织构强度存在很大差异;在压下率大于80%的情况下,不同试样的不同厚度处的织构类型发生了变化,其织构类型为旋转立方织构或高斯织构{011}<100>,且当织构类型为旋转立方织构时,织构强度存在很大差异,而当织构类型为高斯织构时,织构强度差异相对较小。 The texture of the grain oriented silicon steel hot rolled plate at different compressibility has been measured.The experimental results have shown that the texture of all samples at different thickness is {100}<011> when the compressibility is below 80%,and its intensity at different compressibility and thickness is difference.The texture of all samples at different thickness is variable when the compressibility is above 80%,it is {100}<011> or {011}<100>,and the intensity of ... 

采用双辊薄带连铸工艺制备了厚度为2.4mm的3.98%Si-0.71%Al无取向硅钢带,经常化、冷轧、不同温度退火后,对其显微组织、析出物、织构和磁性能进行了检测分析。结果表明:随着退火温度的提高,退火板晶粒尺寸增大,组织均匀性提高;退火板析出物主要是AlN和MnS与AlN复合析出物,尺寸较粗大,达0.5~2.5μm;退火板织构沿厚度方向变化明显,表层和1/2层存在较强的{100}织构,1/2层还存在较强的{111}织构,1/4层主要是{112}织构;随退火温度的升高相应的铁损和磁感应强度均降低。 Using twin roll thin strip continuous casting technique,the 3.98%Si-0.71%Al no-oriented silicon steel strip in thickness of 2.4mm was produced.The microstructure,precipitates,texture,and magnetic properties of the sheet after normalizing,cold rolling and annealing at different temperatures were studied.The results show that with annealing temperature increase,the grain size and uniformity of annealed sheet increased.The main precipitates in coarse size of 0.5-2.5μm in annealed sheet were AlN and... 

【机构】 武汉钢铁学院轧钢七二级电工钢结业小组； ...