硅钢资料

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the... 

采用中、厚板坯生产技术对取向硅钢进行了研制和开发,对热轧及后工序样品进行了金相组织观察和EBSD分析,探讨了两种组织及织构的差异性,研究结果表明:除高温退火样品外,中板坯生产的取向硅钢各工序样品平均晶粒尺寸大;厚板坯生产的取向硅钢热轧和常化样品亚表层Goss织构强;中板坯和厚板坯的脱碳退火板织构没有明显区别。中板坯生产的取向硅钢成本低,产品磁性能和质量与厚板坯相当。 Grain oriented silicon steel was researched and developed by medium thickness slab and thick slab.Microstructures observation and EBSD analysis to the samples of hot rolling and following processes were carried out,respectively.The differences between the two kinds of microstructures and textures were discussed.The results show that the average grain sizes of every process samples are larger except that of high temperature annealing samples of grain oriented silicon steel produced by medium thic... 

采用轧制法制备出具有低铁损高磁感0.23mm厚6.4%(质量分数)Si高硅钢。沿轧制方向的最终磁性能为B8=1.474 T,B50=1.714 T;P10/50=0.30W/kg,P15/50=0.88W/kg。利用X射线衍射及背散射电子衍射(EBSD)技术分析了高硅钢在轧制及退火过程中的织构演变过程。结果表明,通过采用大压下率热轧,确保热轧板次表层中产生更多的高斯织构,随后进行遗传;温轧板中粗大的晶粒有利于冷轧剪切带的形成;冷轧板经脱碳退火后生成强{210}〈001〉织构及次表层较强的高斯织构是在轧向上获得高磁感的原因,归因于其在{111}〈112〉冷轧形变晶粒内的剪切带优先形核并长大;最终退火后虽出现了随机取向,但以{310}〈001〉织构为代表的η织构得以保留并且增强,进一步提高了磁感。随着退火温度的升高及保温时间的延长,高硅钢薄板晶粒尺寸不断增大,铁损明显降低。 6.4wt%Si high silicon steel sheets(0.23mm thick)with low iron loss and high magnetic induction were successfully produced by rolling process.The final magnetic properties along the rolling direction(RD) were:B8=1.474T,B50=1.714T;P10/50=0.30 W/kg,P15/50=0.88 W/kg.The texture evolution during rolling and annealing was investigated by means of X-ray diffraction and electron backscatter diffraction(EBSD).It was found that more Goss textures formed in the subsurface of hot rolled plates by using larg... 

【摘要】 <正>3月15日,随着第5754卷HiB钢下线,武钢...

运用EBSD和光学显微镜,研究了0.25%~0.45%Cu对无取向电工钢热轧板显微组织,成品板显微组织、织构和磁性能的影响。实验结果表明:卷取过程中Cu元素在热轧板表层的偏聚作用显著阻碍了热轧板表层再结晶晶粒长大,导致热轧板表层晶粒尺寸随着Cu含量增加而逐渐较小,但热轧板中间晶粒尺寸变化不大。同时发现Cu元素能够明显改善织构类型,使有利织构组分增加,不利织构组分减少,同时减弱织构强度。从实验结果可知0.35%Cu能够显著改善电工钢的磁性能,铁损P15/50最低达到4.1 W/kg,磁感B50最高值达到1.8 T。 Effects of high content Cu on microstructure of hot rolled plates and microstructure,texture and magnetic properties of annealed finish product plates of non-oriented electrical steel were examined by means of EBSD technique and optical microscope. The results show that surface segregation of Cu significantly hindered recrystallized grain growth of surface layer in hot rolled plate during the coiling,as a result,the surface grain sizes of the hot-rohed plates decrease with the increase of Cu con... 

【作者】 凌健； ...

为了更好的解决电力系统防污闪涂料RTV-Ⅰ长期应用暴露出来的问题以及目前RTV-Ⅱ防污闪涂料存在的一些不足,结合具体实际需求,在电力系统外绝缘领域,应用新型防污闪硬质涂层——防污闪纳米硅钢涂层,并对分别喷涂了防污闪纳米硅钢涂层以及RTV涂料的绝缘子进行对比运行情况研究分析。研究结果表明,防污闪纳米硅钢涂层是一种同时具有优异憎水性迁移性能和自洁性能的新型涂层,具有良好的应用前景。 In order to solve the problem exposed of anti-pollution flashover coating RTV-Ⅰwhich has been used long-term in power system,as well as to better solve some shortcomings of the current anti-pollution flashover coating RTV-Ⅱ,in this paper,a new anti-pollution flashover hard coating — anti-pollution flashover nanometer silicon hard coating(NSHC) is applied in the field of power system insulation for the specific practical needs.At the same time insulators which are separately sprayed by the NSHC a... 

研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce... 

针对传统工艺生产硅钢周期长、能耗大等缺点,采用双辊连铸工艺制备3%Si无取向硅钢连铸薄带,利用MEM,SEM和TEM观察了铸带的组织、织构及析出物,同时对比了Al的质量分数为0.6%和0.9%的连铸薄带在组织、织构及析出物特征方面的异同.结果表明:双辊连铸工艺生产的3%Si无取向硅钢铸带的组织为均匀等轴晶粒,平均晶粒尺寸约为300μm;织构组成随Al质量分数的不同具有明显差别,Al质量分数为0.9%的铸带中{100}织构强度是随机织构的7倍;铸带中的析出物为AlN和MnS,最大尺寸分别为500和50 nm左右. Given the lengthy production cycle,high energy consumption,and other shortcomings of the traditional process for producing silicon steel,a twin-roll casting process was used to produce 3%Si non-oriented silicon steel casting strips. MEM,SEM,and TEM were used to compare micro-structure,texture,and precipitate characteristics of a casting strip containing 0.6%Al with another containing 0.9%Al.The structure of 3%Si non-oriented silicon steel produced by the twin-roll casting process was a uniform i... 

为满足用户对无取向电工钢中硫含量的要求,采用CaO-CaF2复合渣系为脱硫剂,利用RH投入法对无取向电工钢进行深脱硫试验。试验结果表明,RH精炼渣成分控制在w CaO43%~51%、w Al2O325%~31%、w MgO4%~6%、w SiO29%~12%、w(FeO+MnO)3%~6%,在脱硫剂加入量为6~8 kg/t时,钢中平均硫含量从32×10-6降低到18×10-6,RH平均脱硫率为43.3%,最高达47.1%。利用KTH模型计算精炼终渣平均硫容量为0.003 1,RH精炼结束时渣-钢间实际平均硫分配比从14增加到52。 In order to satisfy the requirements of consumers on sulfur content in non-oriented electrical steel,taking( CaO-CaF 2) based flux as desulfurizer,industrial experiments on deep desulphurization of non-oriented electrical steel were carried out during RH process. The results show that as the compositions of refining slag are appropriately controlled with w CaO of 43% ~ 51%,w Al2O3 of 25% ~ 31%,w MgO of 4% ~ 6%,w SiO2 of 9% ~ 12%,and w( FeO + MnO) of 3% ~ 6%,and the desulfurizer added are at 6 ~ ... 

取向硅钢成品的晶粒尺寸非常大,其易磁化方向[001]晶向对于轧向的偏差角度对其磁性能影响极大。本文介绍了取向硅钢二次再结晶后成品晶粒位向的几种测定方法,包括侵蚀法、劳厄法、OIM法、极图法和非对称X射线衍射法等,并对这几种测量方法进行了比较。 The finished product of grain-oriented silicon steel has immense grain size ranging from millimeters to centimeters and the deviation angles of easy magnetization direction from rolling direction plays a remarkable role in magnetic properties of grain-oriented silicon steel.The methods in common use for determining the deviation angles of crystal direction are introduced,which include the etch-figure method,the Laue method,the OIM method,the pole figure method and the asymmetrical X-Ray diffract... 

阐述了影响硅钢卷材下料利用率的因素,并结合具体事例利用计算机排样系统进行了详细分析,对提高硅钢卷材的利用率具有一定的指导作用。 It describes the factors influenceing the the utilization ratio of the roll of Silicon steel,and analyzes it in detail combined with concrete examples by a computer arrangement system,which can give a guide for increasing the utilization ratio of the roll of Silicon steel.