硅钢资料

本发明公开了一种低铁损高磁导率无取向电工钢及其生产方法，所述生产方法包括以下步骤：钢水连续浇铸成板坯，板坯经加热炉加热，再经热轧得到热轧板，然后经空冷和水冷后在500～650℃进行卷取；热轧板经常化处理、盐酸酸洗；酸洗后在可逆轧机上进行冷轧；最后经成品退火，退火温度为840～900℃，加热时间为240～500s；然后以不超过3℃/s的冷却速度冷却至500℃以下；涂覆绝缘涂层、固化，后经二次退火，即可得到低铁损高磁导率无取向电工钢，其磁性能满足P1.5/50≤3.50W/kg，μ1.5≥3800Gs/Oe，B5000≥1.76T的要求。

对冷轧无取向硅钢在冶炼过程中各个工序的顶渣进行了检测,分析了顶渣变化原因,并得出结论:硅钢生产宜采用复吹转炉,以降低吹炼终点渣中TFe含量,进而减轻对精炼的压力;使用低S、低Al2O3含量中间包覆盖剂;RH脱氧及合金化顺序采用先加硅铁后加铝;首罐宜经LF提温并降低渣中TFe。 The top-surface slag used for the various production processes in smelting coldrolled non-oriented electrical steel is tested and based on tested results the cause of the top surface slag change is analyzed.So it is concluded that the combined blown converter is more suitable to be used for smelting electrical steel in order to reduce the content of TFe in slag at blow end point and then much better results can be achieved during the period of refining.Secondly the tundish flux contenting low co... 

一种增大压下率的电工钢冷轧装置及冷轧方法，属于电工钢冷轧技术领域，该电工钢冷轧装置，包括单机架可逆轧机，单机架可逆轧机的两侧均设置有电磁感应加热装置和氮气风冷装置，氮气风冷装置靠近单机架可逆轧机的轧制进口或入口设置，本发明的有益效果是，本发明通过在单机架可逆轧机两侧增设电磁感应加热装置和氮气风冷装置，对每道次轧制过程中可在线调节电磁感应加热温度，实现了边去应力退火边轧制，保证了正常的轧制工作，达到了高效轧制更薄规格电工钢产品的目的和消化生产CSP热轧超厚过渡坯的目的。

研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

本发明涉及无取向硅钢技术领域，尤其涉及一种改善高牌号无取向硅钢冷轧断带的控制方法。按重量百分比计：[Si+Al]≥4.0％；Mn、S含量满足：S≤0.0015，[Mn]/[S]:200～400；1)热轧过程中使用保温罩，热轧轧制时投入边部加热，头尾100米内卷曲温度提高15～30℃；2)常化机组圆盘剪进行边部剪边前增加加热装置，剪切后增加毛刺打磨装置，采用煤气明火加热，保证钢板温度在韧脆转变温度以上；3)圆盘剪间隙满足关系式：ds＝(0.15～0.45)d0ds:圆盘剪间隙，μm；d0:常化板板厚，mm；4)常化采用快速加热，控制钢带的预热段升温速度320～380℃/min，机组速度20～30m/min；5)常化工艺后，控制边部小于20μm的晶粒占比在5％以内。有效的减少了冷轧断带的发生，提高成材率1.30％以上，降低了生产成本。

研究了CSP工艺生产≤0.005%C-1.1%Si的2.2mm无取向电工钢热轧板在800～1000℃常化对0.5mm冷轧板840℃退火后组织和磁性能的影响。结果表明,热轧板常化温度升高,冷轧板退火后的再结晶晶粒增大,铁损降低,磁感增加;热轧板常化温度超过900℃,因第二相固溶而后弥散析出,退火后冷轧晶粒细化,铁损增加,因此该无取向电工钢热轧板最佳常化温度为900℃。 The effect of normalizing at 800-1000℃ of CSP produced plate(≤0.005%C-1.1%Si) on the microstructure and magnetic properties of downstream cold-rolled non-oriented electrical steel annealed at 840℃ was studied.Results show that with increasing normalizing temperature of hot-rolled material the recrystallized grain size of annealed sheet increases,iron loss reduced and magnetic induction increases.As normalizing temperature excesses 900℃,grain is refined and iron loss increases after annealing due... 

取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}～{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot... 

本发明公开了一种无取向电工钢清洗工艺，包括以下步骤：1)在脱脂剂箱体中添加脱脂剂溶剂，通过喷射泵将脱脂剂分别从上下两路管道喷出，经过流量控制电磁阀进入喷射梁，通过喷嘴喷洒在带钢表面；2)带钢轧制后温度为100～150℃，速度为600～1000m/min，带钢表面高温确保脱脂剂与带钢表面残留油脂反应充分，且在高速下喷射的脱脂剂与带钢相向而行，使带钢表面反应后残留硅泥、铁粉被迅速带走；3)喷射后的脱脂剂流入收集槽中，通过泵重新打入脱脂剂箱体中，实现脱脂剂的循环利用。其利用轧制时产生的高温及高速对带钢表面残留乳化液斑迹、铁粉、硅泥进行清洗，清洗彻底高效。

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali... 

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

本发明一种解决取向硅钢热轧板晶粒粗大的方法，在取向硅钢的成分设计中减少固溶温度较高的MnS的含量，降低铸坯加热温度，同时计算实际取向硅钢成分中γ‑相含量与温度之间的关系，依据计算结果设计取向硅钢的热轧工艺，可以保证20％～30％的γ‑相数量，成功解决取向硅钢热轧板晶粒粗大的问题。