钢厂
火花源原子发射光谱法测定取向硅钢中碳硅锰磷硫
通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination...
加热温度对W470高硅钢连铸坯氧化铁皮的影响
采用SEM、EDS和XRD对不同加热温度下W470连铸坯氧化铁皮的微观形貌及相结构进行研究。结果表明,W470氧化铁皮难以除去的原因是氧化铁皮熔化,液相包裹着FeO,凝固时发生共晶反应,生成FeO/Fe2SiO4共晶混合物,并深嵌入基体。降低加热炉的加热温度,使连铸坯全程在FeO/Fe2SiO4共晶混合物熔点(1177℃)以下加热,可降低氧化铁皮与基体的结合力,能够有效解决W470除鳞困难问题。 The microstructure and phase structure of iron scale of W470 continuous casting billet at different heating temperatures were investigated by SEM,EDS,and XRD.The results show that the reason why the iron scale of W470 removes hardly is that iron scale is melted and the FeO is surrounded by the liquid phase,which forms FeO / Fe2SiO4eutectic mixture and is embedded into the matrix after solidification.Lowering the heating temperature and keeping the continuous casting billet heating under the melt...
脉冲电场对取向硅钢磁性能及织构的影响
采用硅钢自动测量装置及X射线衍射仪检测出样品在实验前后的磁性能参数和织构强度.结果表明:较低的电压、9 Hz、较长的处理时间以及退火温度为650℃有利于增高铁损降低比例;较低的电压、较高的频率以及退火温度为650℃有利于增加磁感应强度增高比例.最佳的提高磁性能的实验参数是:频率为9 Hz,电压为500 V,处理时间为6 min,退火温度为650℃.通过织构分析可以验证:取向硅钢磁感应强度的变化取决于{110}<001>晶粒取向度值,而{110}<001>取向度值可看成是一个反映总体平均偏离角大小情况的综合值. An automatic measurement system for silicon steel and an X-ray diffraction meter were used for measuring the magnetic property parameters and texture of ex-processed samples and processed samples.It is shown that under the condition of a lower voltage,9Hz,a longer processed time and an annealing temperature of 650℃,the decrease rate of iron loss can be increased;a lower voltage,a higher frequency and an annealing temperature of 650℃ are in favor of improving the increase rate of magnetic inducti...
无取向电工钢中夹杂物的分析
对无取向电工钢中的夹杂进行了系统的分析。利用小样电解,采取不同电解液,不同的分离方法对无取向电工钢中稳定和不稳定夹杂物进行了提取、分离和收集。利用扫描电镜(SEM)、X-射线衍射、ICP等对电解分离收集的夹杂物进行了定性和定量分析。 The inclusion analysis of the non-oriented electrical steel has been investigated.By using small sample electrolytic analysis,with different electrolytes and different separation ways,the stable inclusions and unstable inclusions was drew,separated,and collected.With utilizing the methods of SEM,X-ray and ICP,the qualitative and quantitative analysis of inclusions in the non-oriented electrical steel was obtained.
退火温度对双辊连铸无取向硅钢组织的影响
利用光学显微镜、TEM和EBSD研究了退火温度对双辊连铸无取向硅钢再结晶组织的影响。结果表明,900℃退火后组织分布不均匀,有大量带状组织,平均晶粒尺寸29.5μm。提高退火温度,晶粒尺寸增大,组织均匀化程度增加,1050℃退火时,带状组织基本消失,平均晶粒尺寸42.2μm。 Effect of annealing temperature on recrystallization microstructure of non-oriented electrical steel produced by twin-roll casting process was investigated using OM,TEM and EBSD.The results show that the recrystallization microstructure is uneven because of many banded grains existing,average grain size is 29.5 μm.With annealing temperature increasing,the recrystallization grain size increases,microstructure becomes more homogeneous.When 1050 ℃ annealing,the banded structure almost disappear and...
电工钢RH脱硫渣系研究
针对攀枝花钢钒有限公司难以稳定生产w(S)≤0.006%高级别电工钢的问题,通过开发RH脱硫剂、钢包渣改性及工艺参数控制,形成了RH脱硫系统工艺技术。经工业试验表明,采用该工艺技术后,钢水脱硫率最高达到42%,成品w(S)控制在0.005%以下,全氧、氮含量也得到了较好的控制,且脱硫剂没有引起钢水增碳,满足高级别电工钢的生产要求。 In light of the difficulty of production of high level electrical steel w(S)≤0.006 % steadily in Panzhihua steel & vanadium Co.,Ltd.the process technology of RH desulfurization system has been formed by developing the RH desulfurizer,modifying the ladle slag and controlling the process parameters.Industrial experiments show that the desulfurization rate of hot metal rises to 42 % and the w(S) of the finished products is controlled in below 0.005 % and total oxygen and nitrogen contents are a...
RH精炼喂CaSi线去除无取向硅钢中的非金属夹杂物
结合工业化生产的无取向硅钢,进行了RH精炼喂CaSi线去除钢中的非金属夹杂物试验研究。针对不同的钙处理条件,分析了CaS夹杂生成热力学,观察了夹杂物的形貌和尺寸分布,确定了夹杂物的类型、数量,探讨了钙处理后钢中夹杂物的变化规律。结果表明,本试验条件下,钙处理可以有效抑制MnS、AlN夹杂物的生成,有效促进钢中微细夹杂物的聚合、上浮、去除,钢质纯净度明显提高。经过合适的钙处理后,钢中的夹杂物以独立存在的CaO为主,同时有少量含CaO、SiO2、MgO的复合夹杂,没有发现CaS夹杂存在。这部分夹杂物的尺寸集中分布在2～20μm,数量约为1.8×105个/mm3。 Experimental study on removal of non-metallic inclusions in non-oriented silicon steel obtained from industrial production by CaSi wire feeding during RH refining process was carried out.The thermodynamics of CaS inclusion formation was analyzed,the morphology and the size distribution of inclusions were observed,and the numbers and types of inclusions were also determined for the steel specimens treated under different calcium treatment conditions.Furthermore,the variation of inclusion characte...
还原分离-原子荧光光谱法分析硅钢中痕量汞的不确定度评定
用还原分离-原子荧光光谱法分析了硅钢中的痕量汞.分析方法的不确定度主要来自测量重复性,样品溶液浓度,工作曲线变动性,标准溶液,移取、配制标准溶液,仪器变动性等.文章分别对上述构成合成不确定度大小的分量进行了计算讨论. Trace mercury in silicon steel and galvanized sheet was analyzed by adopting reduced separation-atomic fluorescence spectrometry.The uncertainty of the analysis method mainly comes from measurement repeatability,sample concentration,working curve volatility,standard solution,pipetting and preparation of standard solution,and instrument variability,etc.The essay conducted all calculations and discussions on the above components that determine uncertainty.
