硅钢资料

采用双辊连铸工艺制备了硅的质量分数分别为0.5%,1.0%,3.0%,4.5%的硅钢薄带,用光学显微镜观察其组织,并研究了后处理工艺对薄带组织和性能的影响。结果表明:硅含量为0.5%和1.0%的薄带适合采用一次冷轧+850～950℃退火的后处理工艺,而硅含量在3.0%以上的薄带适合采用二次冷轧+950℃退火的后处理工艺;硅含量为3.0%和4.5%的薄带在冷轧并950℃退火后,其磁性能最佳,铁芯损耗约为4.30 W·kg^-1,磁感应强度约为1.68T。 Silicon steel thin strips with silicon content of 0.5wt%,1.0wt%,3.0wt%and 4.5wt%were prepared by twin-roll continuous casting process,and the microstructure of the strips were observed by means of optical microscopy,and on the basis,the effect of post-treatment process on microstructure and properties of the strips was studied.The results show that the post-treatment process of one-time cold rolling and annealing between 850—950℃was suitable for the strips with silicon content of 0.5wt%and 1.0wt... 

取向硅钢常化工序主要采用现场实测带钢温度的方式测定冷却速率，并通过稳定冷却水温、调整冷却水量及喷梁运行数量等方式保证合理的冷却速率，给常化工艺设计和生产带来诸多不便。通过对常化工艺水冷过程带钢的传热分析求解，在建立带钢水冷温度模型的基础上，研究了不同冷却工艺参数对带钢温度及冷却速率的影响规律以及冷却工艺的交互作用结果。结果表明：模型计算结果能够较好地反映取向硅钢在常化水冷过程中的温度及冷却速率的变化，其计算误差为0.80%～4.11%;在特定取向硅钢厚度规格和常化工艺下，随着常化冷却水量及有效冷却长度的增加，带钢水冷温度及冷却速率与呈非线性变化；常化水冷工艺主要通过调控带钢与冷却水之间热交换量和交换时间实现对带钢温度的控制，实际生产中需综合考虑机组速度、冷却水量及有效冷却长度之间的交互作用，选定喷梁投入数量和冷却水量以获得稳定的冷却速率。 The cooling rate of normalization process mainly determined by measuring the grain oriented silicon steel strip temperature on site, and ensures the cooling rate by stabilizing the cooling water temperature, adjusting the cooling water volume and the operation quantity of spray beam, which brings inconvenience to the normalization process design and production. Based on the heat transfer of strip in the water cooling section of normalization process, the water cooling temperature model for the n... 

综述了国内外大钢铁企业与研究机构采用获得抑制剂法生产低温高磁感取向硅钢的开发及应用情况,分析了以该法生产高磁感取向硅钢过程中抑制剂的控制技术,包括固有抑制剂组成方案、气态渗氮方式与工艺及高温退火工艺的制定.研究表明,固有抑制剂组成方案的设计思路大体一致,化合物抑制剂以AlN为主、硫化物为辅,同时添加少量Sn,Sb等单元素抑制剂,但组成元素含量存在一定差别;在脱碳退火后用NH3进行非平衡渗氮处理已成为气态渗氮的主要方式,但最佳方式仍未明确,具体选择需依据实际生产条件,相应脱碳及渗氮工艺的控制条件差别较大;高温退火工艺中升温制度差别不大,升温阶段退火气氛中N2含量的选择存在差别.此外,分析了抑制剂控制技术目前存在的关键问题,并指出了进一步的研究方向. The current application and exploitation on production of low-temperature high magnetic induction grain-oriented silicon steel with acquired inhibitor method at both iron and steel enterprises and research institutions in the world are reviewed. The control techniques of inhibitors, which include the composition design for inherent inhibitors, nitriding method and process, and secondary recrystallization annealing, are thoroughly analyzed and proposed. It is indicated that the design ideas for i... 

实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h... 

双辊连铸技术是冶金及材料领域内的一项前沿技术,对于生产高品质硅钢具有独特优势.本实验研究了一种双辊铸轧w[Si]=4.5%的无取向硅钢,考察其铸态和常化处理后样品的组织、织构及析出相尺寸特征.结果表明:铸带组织以与铸带法向成5~20(°)倾角的柱状晶为主,晶内存在少量0.3~0.4μm的AlN析出相,铸带织构以λ(<001>//ND)织构为主,表层织构漫散.950℃/10 min常化处理后,析出相尺寸增大,表层λ织构增强. As an advanced technique of metallurgy and material science,twin- roll strip casting has unique advantages for producing high quality silicon steel. The present study was aimed at a 4. 5% Si non- oriented electrical steel for analyzing the structure,texture and the size of precipitates at the initial and normalized state. The results revealed that the initial structure mainly consisted of columnar grains with 5 ~ 20( °) angle to the normal of cast strip,and some AlN precipitates of 0. 3 ~ 0. 4 μ... 

以青海盐湖水氯镁石为初级原料,采用喷雾热解法制备原料氧化镁,原料氧化镁通过水化制备硅钢级氧化镁前驱体氢氧化镁。原料氧化镁水化实验中对水化剂、水化温度、水化时间、液固比、搅拌速度及陈化时间对水化率、过滤速度和纯度的影响进行系统研究。采用均匀实验设计和DPS数据处理,(依次)通过建模分析、二次多项式模型回归建立数学模型,再通过各因素方差分析和总方差分析,确定了理论最优实验条件,再用理论最优条件作重复实验进行验证,最终确定了原料氧化镁的最佳水化条件。在水化温度60℃,水化时间105 min,液固比4,陈化时间4 h,水化剂1含量4.0%,水化剂2含量3.15%,洗水量4倍,搅拌速度120 r/min时,原料氧化镁的水化率达99.50%以上,得到的硅钢级氧化镁前驱体氢氧化镁纯度高、过滤性能良好。 By spray pyrolysis method,bischofite in Qinghai salt Lake,as primary raw material,was used to prepare precursor raw material MgO for silicon-steel MgO.The precursor raw material MgO was used for preparing Mg(OH)2 which was the precursor of silicon-steel MgO,by hydration method.In the hydration experiment of precursor raw material MgO,some experiment parameters were investigated systematically.such as the hydrated agent,the temperature and time of hydration,liquid/solid ratio that affected the hy... 

【作者】 杨得草； ...

根据现场实际的生产控制情况,指出了热轧原料断面轮廓缺陷以一定的比列遗传给了冷轧带钢,分析了不同热轧原料断面轮廓对冷轧电工钢尺寸精度的具体影响,提出了相应的规律。并阐明了严格控制热轧原料断面轮廓形貌,对保证冷轧电工钢尺寸精度具有重大意义,对于中国现行的冷轧电工钢生产具有指导意义。 Based on the actual situation of production control,it was pointed out that the section profile defects of hot-rolled raw materials were geneticed to the cold-rolled strip.The specific impact analysis for the profile of different hot-rolled raw materials to the dimensional accuracy of cold-rolled silicon steel was analyzed.As a result, the corresponding orderliness are given;And the strict control to section profile of the hot-rolled material is of great significance to ensure the dimensional ac... 

【摘要】 <正>2012年3月29日中国钢铁工业协会在上...

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

【作者】 马芳； 张春红； ...

研究了CSP流程试制50W270高牌号无取向硅钢热轧→常化→冷轧→退火过程中织构的演变.利用电子背散射衍射技术对全流程织构进行测量和分析.发现热轧板织构在厚度方向上存在较大差异,表层主要为铜型、黄铜和高斯织构,1/4层存在微弱的高斯织构和旋转立方织构,中心层以γ纤维织构和旋转立方织构为主,还含有较弱的α纤维织构.与热轧板相比,常化板表层和1/4层织构变化不大,中心层旋转立方织构和α纤维织构增强.冷轧板各层均具有α纤维织构和γ纤维织构.与冷轧板相比,成品板各层中α纤维织构基本消失,还出现了立方织构和高斯织构. This article focuses on texture evolution in 50W270 high-brand non-oriented silicon steel produced by CSP in hot rolling,normalizing,cold rolling,and annealing processes.The texture in the whole process was measured and analyzed by electron back-scatter diffraction.It is found that the texture along the thickness direction in hot-rolled strips changes obviously;there are mainly copper,brass,and Goss textures in the surface layer;the 1/4 layer has weak Goss texture and rotating cube texture;γ-fib...