硅钢资料

为了更好的解决电力系统防污闪涂料RTV-Ⅰ长期应用暴露出来的问题以及目前RTV-Ⅱ防污闪涂料存在的一些不足,结合具体实际需求,在电力系统外绝缘领域,应用新型防污闪硬质涂层——防污闪纳米硅钢涂层,并对分别喷涂了防污闪纳米硅钢涂层以及RTV涂料的绝缘子进行对比运行情况研究分析。研究结果表明,防污闪纳米硅钢涂层是一种同时具有优异憎水性迁移性能和自洁性能的新型涂层,具有良好的应用前景。 In order to solve the problem exposed of anti-pollution flashover coating RTV-Ⅰwhich has been used long-term in power system,as well as to better solve some shortcomings of the current anti-pollution flashover coating RTV-Ⅱ,in this paper,a new anti-pollution flashover hard coating — anti-pollution flashover nanometer silicon hard coating(NSHC) is applied in the field of power system insulation for the specific practical needs.At the same time insulators which are separately sprayed by the NSHC a... 

利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy... 

采用EBSD技术研究了有、无拉应力作用下无取向硅钢在晶粒长大过程中织构转变及晶界变化的规律。结果表明:在晶粒生长期间,无应力作用下的硅钢中,{111}〈112〉,{111}〈110〉织构组分强化,而{100}〈001〉织构组分弱化;与无拉应力作用下的情况相比,施加5MPa的拉应力时,{111}〈112〉,{111}〈110〉织构组分强化的速率下降,{100}〈001〉织构组分变化不明显。对于在晶粒生长期间持续变化的{111}〈112〉,{111}〈110〉和{100}〈001〉织构组分而言,虽然有、无拉应力作用下硅钢的{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率均下降,而{100}〈001〉织构组分的高取向差角度晶界频率则上升,但当有拉应力作用后,{111}〈112〉和{111}〈110〉织构组分的高取向差角度晶界频率下降的速率变小,{100}〈001〉织构组分的高取向差角度晶界频率上升的速率稍有变小。通过对无取向硅钢在晶粒长大过程中织构转变及晶界变化规律的研究,分析了合金原子在晶界的偏聚行为。 The rules of texture and grain boundary transformation in the nonoriented silicon steel under applied stress or without applied stress during grain growth were investigated by EBSD.The results show that the {111}〈112〉 and {111}〈110〉 components in the nonoriented silicon steel without stress are strengthened during grain growth whereas {100}〈001〉 component is weakened,but the growth rate of {111}〈112〉 and {111}〈110〉 component decreases,while the area fraction of {100}〈001〉 component doesn’t chang... 

通过对取向硅钢进行脉冲磁场退火实验,发现在相同的退火时间(6.0 min)内,低于1 T的脉冲磁场可以在一定程度上提高取向硅钢的磁感(B8),而高于1 T的脉冲磁场则会使取向硅钢的磁性能急剧恶化.同时发现,脉冲直流电加热方式会使取向硅钢的磁性能恶化.研究表明,脉冲磁场退火有望成为一种调控材料微观结构的有效手段. We have carried out experiments of annealing by pulse magnetic field.The results show that a pulse magnetic field with intensity lower than 1 T can promote magnetic induction density(B8) of grain-oriented silicon steel,while the magnetic properties deteriorate sharply when intensity is higher than 1 T.It has also been found that heating by using pulse direct current can cause the magnetic properties to deteriorate,in contrast to the traditional heating using resistance furnace.Our research shows... 

针对硅钢连续退火机组的主要能源介质消耗现状,对现有生产工艺和设备研究采取机组循环用水、增加清洗段漂洗级数等措施可节约大概27 m3/h的过滤水量,并可减少78%的弱碱处理量;将炉子烟气换热系统增加一级余热回收,每年回收的余热相当于583 t标煤消耗,可节约蒸汽5 368 t。 The present situation of energy consumption for silicon steel annealing line is analyzed in this paper.In existing process and equipment conditions,increasing the number of cleaning series will lead to a saving of about 27 m3/h of filter water and reduce 78 % of weak base processing volume.For the flue gas heat-exchange system,adding a waste heat recovery device will recover waste heat equivalent to 583 tons of standard coal per year,corresponding to a saving of steam 5 368 t per year. 

介绍了烟气余热利用系统的工艺流程及控制思想,结合该系统在钢厂硅钢连续退火机组中的应用实践,估算出烟气余热利用系统每年可节约蒸汽5 040 t,经济效益良好,同时分析了该系统存在的问题及对策。 Introduced a method about the process and control of the application of waste heat system, which had been used into a silicon steel continuous annealing line and profiting a good economic benefit by saving a large number of steam every year, which has been estimated about 5 040 tons, and analyzed the problems and solutions existed in this system. 

针对薄板坯连铸连轧流程结合\"获得抑制剂法\"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。 The precipitation behavior of MnS and AlN in low-temperature high magnetic induction grain-oriented silicon steel produced by thin slab casting and rolling process with\"acquired inhibitor method\"during continuous casting and soaking was studied by thermodynamic calculation.The calculated results show that AlN is likely to precipitate in ferrite after solidification.However,MnS can precipitate only in the two phase region of ferrite and austenite.Meanwhile,MnS and AlN in the steel can not be comp... 

通过固溶度积公式计算及热模拟实验,对不同热装和加热温度条件下的无取向硅钢铸坯中析出相进行了研究.在低于950℃热装时,铸坯中AlN的析出量和尺寸不再变化,但MnS和AlN-MnS的数量及平均尺寸随着热装温度降低而进一步增加,并在温度低于600℃时达到最大值后保持不变.与1200℃相比,1100℃加热的铸坯中AlN、MnS的总固溶量相对更少.相比850℃热装,600℃热装再加热到1100℃的铸坯中AlN和MnS的总固溶量更少,且AlN和MnS尺寸更大.合适的热装温度和加热温度分别为600℃和1100℃. Based on solubility product calculation and thermal simulation experiments,precipitated phases in continuous casting slabs of non-oriented silicon steel were systematically studied at different hot charging and heating temperatures.When the hot charging temperature is below 950 ℃,the content and size of AlN remain unchanged,but the quantity and size of MnS and AlN-MnS increase when the hot charging temperature decreases,reach maximum and remain unchanged when the hot charging temperature is belo... 

针对宝钢集团、日本新日铁住金和JFE公司公开的相关专利等资料,总结了国内外高强度无取向电工钢的研究进展,分析了不同电工钢的化学成分、生产工艺及产品性能,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度,并阐述了四种强化方式的优缺点;指出在高强度无取向电工钢的研发过程中,需根据其具体用途确定目标性能,再采用合适的强化手段,最终实现力学性能、磁性能和生产性能之间的平衡。 The research progress of high strength non-oriented electrical steels at home and abroad is summarized according to related patents brought into the public by Baosteel,Nippon Steel & Sumitomo Metal corporation and JFE corporation.The characteristics of chemical composition,production technology and properties of products in the patents are analyzed.Each of solution strengthening method,fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method ma... 

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc... 

针对马钢无取向电工钢孔洞缺陷的分布规律及形貌特征,对缺陷样进行了显微分析,并利用生产实绩数据分析了该缺陷产生的原因。结合热轧生产过程,主要通过避免带钢撞击导卫以及降低导卫结瘤的产生等措施,可有效抑制热卷异物压入产生,从而降低冷轧工序孔洞的产生。 In viewing of the distribution and morphology characteristics of the hole defect of non-oriented electrical steel in Maanshan Iron and Steel Co.,Ltd.,the causes of the defect were analyzed by micro analysis of the defect sample and the production data.Combined with the production process of hot rolling,by avoiding the impact of strip steel on the guide and reducing the nodule formation on the guide,the pressing of foreign bodies in hot coiling could be effectively suppressed,thus reducing the fo...