硅钢资料

针对新能源汽车的发展，制备了含Ni固溶强化、含Cu析出强化以及含Ni+Cu复合强化3%Si无取向硅钢，研究了强化方式对无取向硅钢组织、织构和性能的影响。结果表明：固溶强化型无取向硅钢热轧板中形成了粗大{221}<221>晶粒，冷轧过程中剪切变形明显并在退火后形成良好再结晶织构。析出强化型无取向硅钢热轧板中心层形成γ取向粗大晶粒，在后续的加工中γ织构逐渐增强并最终得到相对细小的再结晶晶粒。复合强化型无取向硅钢热轧板中保留了强λ取向带状组织，退火后形成了有益的Goss织构和λ织构。固溶强化型与复合强化型无取向硅钢磁感应强度B₅₀分别达到1.742、1.688 T,高于析出强化型无取向硅钢的1.645 T。同时，复合强化型无取向硅钢高频铁损最低，其P_1.0/400和P_{1.0/1 000}分别低至20.97、82.69 W/kg,这与其较小的晶粒尺寸和织构改善有关。强度计算结果表明：Ni元素固溶强化对强度的提高有限，屈服强度为468 MPa,纳米Cu析出可显著提高屈服强度（强度增量约200 MPa）,且主要来自于模量强... For the development of new energy vehicles, 3%Si non-oriented silicon steel were processed by solid solution strengthening with Ni, precipitation strengthening with Cu, and composite strengthening with Ni and Cu. The effects of different strengthening methods on the microstructure, texture and properties of high-strength non oriented silicon steel were studied.The results show that coarse {221}<221> grains are formed in the hot rolled sheet of solution strengthened non-oriented silicon ste... 

本发明公开了一种硅钢轧制系统，包括：轧机组，所述轧机组包括M架轧机，用于轧制硅钢，所述M架轧机的前N架轧机的轧辊为高速钢轧辊，其中，M、N为正整数；硅钢检测装置，位于所述轧机组最后一架轧机的出口处，用于对出口硅钢的参数信息进行检测；控制器，与所述硅钢检测装置通信连接，用于在所述参数信息不满足预设参数条件时，控制所述轧机组停止工作；磨床，用于在所述轧机组停止工作后，对所述N架轧机中的每架轧机进行辊形精度检测，对不满足预设辊形精度范围的轧辊进行磨削。

本发明提供一种能够有效地抑制去应力退火中的渗碳、氮化的，实施了耐热型的磁畴细化处理的取向性电磁钢板。该取向性电磁钢板在一侧面具有多个槽，在所述钢板的表面至少具备镁橄榄石被膜，该多个槽是朝向横切轧制方向的方向线状地延伸且在该轧制方向隔着间隔地并列，并且，形成于所述槽的底部的所述镁橄榄石被膜厚度的平均值为0.45μm以上，并且该厚度的标准偏差σ为0.34μm以下。

一种高硅钢材料的制备方法，步骤包括靶材、金属基材表面清理；排除密闭容器内空气、通保护气；双辉光等离子预轰击靶材和基材，净化表面；等离子溅射、加热、保温；缓慢冷却取出。预轰击靶材、基材，去除表面吸附层、活化基材，交替升高基材电压、靶材电压，使靶材中的合金元素被离子轰击而溅射出来、扩散进入基材内部形成表面高硅钢层。“双辉光等离子表面冶金技术”制备高硅钢的工艺简单易行、可控性高、成本低、无污染且基体和表面的结合力高，适合大规模产业化生产；更重要的是该方法采用交替离子轰击、扩渗速度快，结合强度高，得到硅含量均匀分布或呈梯度分布的高硅钢材料，为制备更高品质的无噪音、低铁损的高硅钢产业化奠定基础。

【机构】 武钢研究院； ...

本发明一种焊接压力容器用碳锰硅钢钢板及其生产方法，钢板化学成分及其重量百分含量为：C：0.18‑0.26%，Si：0.18‑0.65%，Mn：0.92‑1.72%，P≤0.008%，S≤0.002%，Cu：0.30‑0.40%，Ni：0.25‑0.35%，Cr：0.25‑0.35%，Mo≤0.10%，V≤0.10%，B：0.003‑0.005%，余量为Fe及不可避免的杂质元素。本发明钢板中加入的贵合金元素含量相对较少，冶炼成本及后续的生产成本控制较低，市场潜力和竞争力很大。

通过热力学计算,分析了实验钢中主要析出物析出的可能性。结果表明:在液相和固液两相区中,AlN和MnS均不能析出;在奥氏体区,AlN和MnS具备热力学析出条件,平衡析出温度分别为1547、1582 K。成品退火板中的析出物主要为AlN和MnS。扫描电镜下观察到的AlN形貌多为长条状,MnS形貌多为棒状或近似球形。这两种析出物占了析出物总量的85%以上,尺寸集中分布在400~800nm;复合析出物主要是(Al2O3+MnS)和(AlN+MnS),形貌不规则,尺寸集中在0.7~1.5μm;透射电镜下观察到了少量100nm以下独立的AlN析出。 According to thermodynamic calculation, the precipitation probability of precipitates was analyzed, AlN and MnS can not precipitate in liquid phase area and solid-liquid two-phase area. In austenite area, both the AlN and MnS have precipitation condition in thermodynamics and precipitates at 1547 K and 1582 K, respectively. The precipitates in annealing plate are mainly AlN and MnS. The shape of AlN is mostly strip, and MnS is stick or near sphericity. They accounted for over 85% of the total qu... 

系统研究了无取向硅钢用磷酸盐系涂层性能的影响因素。以氢氧化铝和磷酸为原料制备磷酸二氢铝,再添加适量的添加剂酒石酸铵、二氧化硅、环氧树脂,得到的涂液涂布于硅钢表面,并控制合适的烘干温度,通过耐盐雾实验考察各因素对涂液耐腐蚀性能的影响。实验结果表明,在磷酸与氢氧化铝物质的量比为3.4∶1、酒石酸铵用量为2%、二氧化硅用量为1%、环氧树脂用量为5%、烘干温度为300℃条件下,所得涂层材料的防(耐)腐蚀效果最佳。 The factors influencing the performance of phosphate anticorrosive coating for non-oriented silicon were systematically studied.Aluminum dihydrogen phosphate was prepared with aluminum hydroxide and phosphoric acid as raw materials.Then added the right amount of additives,such as ammonium tartrate,silicon dioxide,and epoxy resin to prepare the liquid coating,which was coated on the surface of the silicon steel,and finally controlled a suitable drying temperature.The influences of various factors... 

热卷箱位于热连轧带钢生产线粗轧与精轧机之间,是热连轧生产中比较理想的中间保温设备。由于取向硅钢变形温度区间较窄,在生产中易出现边裂现象,同时中间坯的边部温度难于得到保证,因此一般不采用热卷箱设备生产,限制了传统热连轧生产线产品开发的品种。通过合理优化热卷箱控制工艺参数,解决了某厂传统热连轧生产线用热卷箱生产取向硅钢的边部质量问题,成功地生产出取向硅钢带。 The hot coil-box is an ideal heat retaining apparatus for hot rolling,lined between roughing mill and finishing mill. But oriented silicon steel has a narrow deformation temperature range,so that the edge crack easily occurs and it is difficult to insure the temperature of the intermediate blank. Therefore,the hot coil-box is rarely used in producing oriented silicon steel,which restricts the product development of the traditional hot rolling line. The article reasonable optimized process parame... 

【作者】 康凌晨； 王丽娜； ...

以取向电工钢成分为基础,制备了含C或Mn和S的4种实验钢。观察了接近平衡析出状态实验钢经60%冷轧后在600～1000℃范围再结晶退火过程中微观组织演变,统计分析了再结晶体积分数随退火时间的变化规律,进而计算了各实验钢静态再结晶的激活能。观察了高含C实验钢退火初期再结晶晶粒优先出现的部位。结果表明900～1000℃范围内各实验钢铁素体的化学成分相似,因而其再结晶激活能基本一致。在600～800℃范围内铁素体内会有阻碍再结晶进程的三次渗碳体析出,从而使再结晶激活能明显提高。高C含量实验钢中还会有从奥氏体转变而来的粗大珠光体或渗碳体,轧制过程中其附近形成的变形区会促进600～800℃加热时该区域附近率先发生再结晶形核、降低再结晶激活能。固溶的Mn、S元素可微弱提高再结晶激活能,但高Mn、S含量会改变粗渗碳体从奥氏体析出时的形态。 Four experimental steels based on grain oriented electrical steel containing C,or Mn and S were prepared.Microstructure evolution of the steels close to a state of equilibrium precipitation were observed during annealing processes at 600-1000 ℃after 60% cold rolling,the changes of recrystallization volume fraction were analyzed statistically as the annealing was prolonged,and the activation energy for static recrystallization of the steels were calculated.The locations,where the recrystallizatio... 

根据相关的取向电工钢典型专利技术,概述了日本高磁感低铁损取向电工钢低温板坯加热、抑制剂合理调节、关键成分Mn、C、Sn和Sb调节与利用、新型退火剂和绝缘溶液的制备及细化磁畴等生产工艺最新动态和进展情况,并提出了国内企业申请取向电工钢专利时应当借鉴之处。 According to related typical patent technology for grain-oriented electrical steel sheets,the recent trends and progress situation for production process of grain-oriented electrical steel sheets with high magnetic flux density and low core loss in Japan are summarized including low temperature slab heating,suitably regulating inhibitors,adjusting and utilizing key element Mn,C,Sn and Sb,manufacturing for new annealing agent and insulating solutions,and fining magnetic domain,and some suggestion...