钢厂
铝和铬在无取向电工钢晶粒长大过程中对晶界的作用
研究了铝和铬元素在无取向电工钢晶粒长大过程中对织构及晶界变化的影响规律。试验结果表明:电工钢在晶粒长大过程中的主要织构组分均为{111}<112>。在晶粒生长期间,不加铝的1号试样中,{111}<112>、{111}<110>织构组分强化,而{100}<001>织构组分弱化;与1号试样相比,在加入0.2%的铝(质量分数,下同)的2号试样中,{111}<112>、{111}<110>织构组分强化(增加)的速率下降,{100}<001>织构组分变化不明显,甚至稍有增加。在含铝的试样中再加入0.3 5%的铬之后(3号试样),{111}<112>{、111}<110>和{100}<001>织构组分的变化规律与1号试样相似,但当电工钢中加入0.72%的铬之后(4号试样),上述3种织构组分的变化规律与2号试样相似。对于在晶粒生长期间持续变化的3种织构组分而言,1号试样的{1 1 1}<112>和{111}<110>织构组分的高(低)取向差角度晶界频率下降(... The effect rule of Aluminm and Chromium on texture and grain boundary transformation in the nonoriented electrical steel during grain growth was investigated.The experimental result shows that the main texture component is {111}<112> in the electrical steel.The {111}<112> and {111}<110> components in specimen 1 without Alumium were strengthened during grain growth whereas {100}<001> component was weakened.But the growth rate of {111}<112> and {111}<110> compon...
免常化处理的耐酸蚀无取向电工钢的研制
在现普通冷轧无取向硅钢的基础上,降低Si含量,复合添加少量辅助元素,组合热轧板处理和成品退火加热技术,研制出了免常化处理的高磁感、低铁损并具有良好耐酸腐蚀性能的新系列无取向电工钢。 Based on existing common cold rolled non-oriented silicon steel,a new series of non-orientedelectrical steel with high induction,low core loss and excellent anti-corrosion property has been developed by reducing Si element,adding complexly a small amount of supplementary elements,and employing combined treatment of hot rolled sheet and finished product annealed heated technology.
提高热轧硅钢凸度精度的工艺措施
以太钢热连轧厂的硅钢为研究对象,利用凸度仪测量热轧带钢出口凸度值,采用矩阵和失效模式的分析方法了解影响带钢凸度变化的主次因素。研究结果表明:通过有效控制轧制过程中的加热温度、时间及采用合理的辊型,硅钢凸度精度提高了4.34%左右。 In this paper,we take the hot-rolled silicon steelsheet of Taigang as the research symbol,exit profile was measured by convex instrument,the primary and secondary factors that affect the strip profile were measured by using matrix and failure mode analysis methed.The results indicate that convexity accuracy has significantly improved by nearly 4.34% through the effective control of the heating temperature,heating time and the use of correct roller type in the process of hot rolling.
低温高磁感取向硅钢高温退火过程织构及析出物的演变行为
对低温法生产的以AlN为主抑制剂的Hi-B取向硅钢高温退火过程进行了中断实验,借助EBSD及TEM技术对高温退火连续升温过程中织构与析出物的演变进行了研究。实验结果表明,800℃时ODF图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;950~1 000℃时高斯晶粒异常长大,偏离角3~6°;高温退火过程析出物主要有球形、规则立方形及不规则多面体形3种形貌,由于渗N的影响,Zener因子先增大再减小,并且析出物在高斯晶界前沿优先粗化。 The annealing process at high temperature of Hi-B silicon steel using low slab reheat temperature and with AlN as the inhibitor has been studied by interrupting test,and the evolution of texture and precipitates during continuous heating-up in the annealing process at high temperature was analyzed by EBSD and TEM. The results showed that Goss texture appears in ODF at 800 ℃,but the intensity of Goss texture was very weak and the deviation angle was more than10°. Goss grains grow abnormally durin...
湿H_2气氛下CGO硅钢初次再结晶织构演变行为
通过对湿H2气氛下,相同退火温度、不同退火时间的CGO硅钢初次再结晶样品进行金相组织观察,并进行了EBSD微观织构分析,研究了CGO硅钢初次再结晶过程中的组织及再结晶织构演变行为。结果表明,在湿H2气氛下,820℃保温,CGO硅钢初次再结晶过程约在120 s时完成。随着退火时间的延长,γ面上{111}<112>织构含量逐渐减少,{111}<110>织构先减少后增多,随着再结晶的完成,部分{111}<112>取向晶粒向高斯{110}<001>取向转化的同时,也向{111}<110>取向转化,高斯{110}<001>织构含量逐渐增多。高斯取向晶粒较多是由{111}<112>取向晶粒转化而来,同时也证明了CGO硅钢高斯取向晶粒的二次再结晶异常长大生长机制为择优形核。 Microstructure development and texture evolution of conventional grain oriented silicon steel,which were annealed at same annealing temperature and different annealing time under wet H2 atmosphere,were investigated through metallographic observation and electron backscattered diffraction analyzing.The results show that the primary recrystallization finishes in 120 s at 820 ℃ under wet H2 atmosphere.With the extending of annealing time,{111}<112> texture decreases,{111}<110> texture d...
CSP工艺生产无取向电工钢
介绍了CSP工艺生产无取向电工钢各工序的设备特点、采用的工艺控制手段和电工钢产品质量情况,结合生产实践证明了马钢CSP工艺开发的无取向电工钢产品丰富了薄板坯连铸连轧的品种结构,发挥了薄板坯连铸连轧生产无取向电工钢性能均一、稳定的特点。 The equipment characteristic,the process control method and the quality of non-orientated silicon steel by CSP process were introduced.Combined with the production situation,it is proved that production of non-orientated silicon steel developed on Masteel CSP line would enrich product structure of thin slab continuous casting and rolling,and it exerts stable performance of non-orientated silicon steel.
热处理工艺对含Mn高硅钢热轧带的组织及硬度的影响
研究了热处理工艺(退火温度、保温时间、冷却方式)对含Mn的Fe-6.5wt%Si高硅钢热轧带的显微组织及硬度的影响。结果表明,退火温度对Fe-6.5wt%Si合金的组织和显微硬度均有较大影响,随退火温度升高,平均晶粒尺寸和显微硬度均明显增大。小于1 h退火时,晶粒长大缓慢,而长时间(>1 h)退火时,一些次表层晶粒将发生异常长大。水冷组织比空冷组织略细小,但水冷显著降低了显微硬度。Mn含量提高能抑制850℃退火时晶粒的长大,并且促进退火后高硅钢的软化。 The influences of heat treatment process(annealing temperature,heating time,cooling methods) on the microstructure and microhardness of Fe-6.5wt%Si high silicon steel containing manganese for hot rolled strip were studied.The results show that the annealing temperature has a great effect on the microstructure and microhardness of Fe-6.5wt%Si alloy,and as the annealing temperature increases,the average grain sizes and microhardness will significantly increase.When annealing time for less than 1 h...
TSCR试制高强度无取向电工钢
采用固溶强化、细晶强化和位错强化方法,模拟TSCR流程试开发高强度无取向电工钢,试开发钢的主要合金成分为3%Si、0.83%Al和2.99%Mn。分析热轧、常化、退火后的钢板组织,并针对不同的成品板组织,详尽地分析了相应的力学性能和磁性能。试验电工钢平均晶粒直径为12.37μm时,R p0.2为530 MPa,R m为618 MPa;当退火制度为700℃×4 min,成品组织完全为未再结晶的回复组织时,R p0.2为853.5 MPa,R m为895.5 MPa。该成分的电工钢P15/50或P10/400最小时,对应的平均晶粒直径都大于59.67μm;P10/800或P10/1000最小时,对应的平均晶粒直径都处于12.37~59.67μm尺寸区间。 TSCR was simulated to develop high-strength non-oriented electrical steel with 3% of Si,0.83% of Al and 2.99% of Mn by solution strengthening,grain refinement strengthening and dislocation strengthening.The microstructures of hot rolled plates,normalized plates and annealed plates were analyzed.Furthermore,the mechanical properties and magnetic properties of products with different microstructures were detailedly studied.As the average grain diameter of the steel was 12.37 μm,the yield strength ...
制备硅钢级氧化镁前驱体的原料水化研究
以青海盐湖水氯镁石为初级原料,采用喷雾热解法制备原料氧化镁,原料氧化镁通过水化制备硅钢级氧化镁前驱体氢氧化镁。原料氧化镁水化实验中对水化剂、水化温度、水化时间、液固比、搅拌速度及陈化时间对水化率、过滤速度和纯度的影响进行系统研究。采用均匀实验设计和DPS数据处理,(依次)通过建模分析、二次多项式模型回归建立数学模型,再通过各因素方差分析和总方差分析,确定了理论最优实验条件,再用理论最优条件作重复实验进行验证,最终确定了原料氧化镁的最佳水化条件。在水化温度60℃,水化时间105 min,液固比4,陈化时间4 h,水化剂1含量4.0%,水化剂2含量3.15%,洗水量4倍,搅拌速度120 r/min时,原料氧化镁的水化率达99.50%以上,得到的硅钢级氧化镁前驱体氢氧化镁纯度高、过滤性能良好。 By spray pyrolysis method,bischofite in Qinghai salt Lake,as primary raw material,was used to prepare precursor raw material MgO for silicon-steel MgO.The precursor raw material MgO was used for preparing Mg(OH)2 which was the precursor of silicon-steel MgO,by hydration method.In the hydration experiment of precursor raw material MgO,some experiment parameters were investigated systematically.such as the hydrated agent,the temperature and time of hydration,liquid/solid ratio that affected the hy...
