硅钢资料

采用节能、环保、经济型的生产技术与工艺来制造高磁感取向硅钢目前已成为世界各大取向硅钢生产厂的研发热点。总结了国内外各大钢铁企业与研究机构采用低温板坯加热技术生产高磁感取向硅钢的开发及应用情况,概括了传统流程实现低温板坯加热技术的方法。介绍了薄板坯连铸连轧与双辊薄带连铸等短流程工艺生产高磁感取向硅钢的研发现状。在此基础上,探讨了高磁感取向硅钢生产技术与工艺的发展趋势及方向。 Utilizing energy-efficient,environmentally friendly,economic production processes and technologies to manufacture high magnetic induction grain-oriented silicon steel has become the focus of current research work.Based on using low-temperature slab reheating techniques to produce high magnetic induction grain-oriented silicon steel at both iron and steel enterprises and research institutions all over the world,the current application and exploitation was thoroughly generalized;the implementation... 

【作者】 刘彤； ...

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re... 

研究了无取向硅钢钙处理前后夹杂物的行为,重点考察了钙处理前后夹杂物的成分、类型、形貌和尺寸研究的变化情况,为实际生产中无取向硅钢的钙处理提供理论指导。试验发现:钙处理前夹杂物主要以Al2O3、Al2O3-MgO为主,且在夹杂物表面有AlN析出,钙处理后夹杂物以Al2O3-MgO-CaS-CaO系复合夹杂物为主,还含有少量的SiO2或AlN;钙处理前后,夹杂物形貌由多边形或不规则形逐渐向球形或近似球形转变,并且夹杂物尺寸不断增大;钙处理前后,含钙夹杂物的比例发生突变,由10%增大到74.5%,且随着钙处理时间的延长,含钙夹杂物比例下降,表明钙处理使夹杂物变性后易聚集长大并上浮去除。 Behavior of inclusions before and after calcium treatment in non-oriented silicon steel was researched by investigating changes of compositions,types,shapes and sizes of inclusions before and after calcium treatment,for the purpose of providing theoretical guidance for calcium treatment of non-oriented silicon steel in actual situation. Results indicated that Al2O3 and Al2O3-MgO were main types of inclusions before calcium treatment,sometimes AlN maybe precipitate in the outer of inclusions. Al2... 

针对新能源汽车的发展，制备了含Ni固溶强化、含Cu析出强化以及含Ni+Cu复合强化3%Si无取向硅钢，研究了强化方式对无取向硅钢组织、织构和性能的影响。结果表明：固溶强化型无取向硅钢热轧板中形成了粗大{221}<221>晶粒，冷轧过程中剪切变形明显并在退火后形成良好再结晶织构。析出强化型无取向硅钢热轧板中心层形成γ取向粗大晶粒，在后续的加工中γ织构逐渐增强并最终得到相对细小的再结晶晶粒。复合强化型无取向硅钢热轧板中保留了强λ取向带状组织，退火后形成了有益的Goss织构和λ织构。固溶强化型与复合强化型无取向硅钢磁感应强度B₅₀分别达到1.742、1.688 T,高于析出强化型无取向硅钢的1.645 T。同时，复合强化型无取向硅钢高频铁损最低，其P_1.0/400和P_{1.0/1 000}分别低至20.97、82.69 W/kg,这与其较小的晶粒尺寸和织构改善有关。强度计算结果表明：Ni元素固溶强化对强度的提高有限，屈服强度为468 MPa,纳米Cu析出可显著提高屈服强度（强度增量约200 MPa）,且主要来自于模量强... For the development of new energy vehicles, 3%Si non-oriented silicon steel were processed by solid solution strengthening with Ni, precipitation strengthening with Cu, and composite strengthening with Ni and Cu. The effects of different strengthening methods on the microstructure, texture and properties of high-strength non oriented silicon steel were studied.The results show that coarse {221}<221> grains are formed in the hot rolled sheet of solution strengthened non-oriented silicon ste... 

利用DSC、XRD,结合热焓分析对硅钢级氧化镁和二氧化硅的固相反应行为进行了研究。比较了不同二氧化硅原料及混合方法对硅钢级氧化镁反应性的影响,找到了一种更为有效的硅钢级氧化镁反应性的评估方法,克服了传统柠檬酸活性法在比较不同厂家生产的氧化镁的反应性上的局限性。进一步研究了Na₂B₄O₇添加剂、TiO₂添加剂对氧化镁和二氧化硅反应行为的影响,结果表明,Na₂B₄O₇添加剂含量的增加对反应有利,而TiO₂添加剂对反应有阻碍作用。 The solid-state reaction behavior between silicon-steel grade MgO and SiO₂ was investigated by DSC and XRD combined with enthalpimetric analysis.The influence of different kinds of SiO₂ and different preparation methods were studied and a specifical measurement that is more reliable was proposed to evaluate reactivity of silicon steel grade MgO.It overcomes the limitation of the traditional citric acid activity（CAA） method,which can not be used to evaluate the reactivity of... 

从影响高牌号无取向硅钢退火工艺的主要参数入手,介绍高牌号无取向硅钢退火炉在加热、气氛控制、冷却、涂层烘烤方面的新技术,并展望无取向硅钢退火炉的发展方向。 Based on the technology parameters of high-grade non-oriented silicon steel annealing,the new technology of the annealing line,which includes heating,atmosphere control,cooling,coating baking,is introduced,and the development direction of non-oriented silicon steel annealing furnace is pointed out. 

【作者】 朱一知； 陈山； ...

【作者】 陶永根； ...

采用双辊薄带连铸工艺制备了厚度为2.4mm的3.98%Si-0.71%Al无取向硅钢带,经常化、冷轧、不同温度退火后,对其显微组织、析出物、织构和磁性能进行了检测分析。结果表明:随着退火温度的提高,退火板晶粒尺寸增大,组织均匀性提高;退火板析出物主要是AlN和MnS与AlN复合析出物,尺寸较粗大,达0.5~2.5μm;退火板织构沿厚度方向变化明显,表层和1/2层存在较强的{100}织构,1/2层还存在较强的{111}织构,1/4层主要是{112}织构;随退火温度的升高相应的铁损和磁感应强度均降低。 Using twin roll thin strip continuous casting technique,the 3.98%Si-0.71%Al no-oriented silicon steel strip in thickness of 2.4mm was produced.The microstructure,precipitates,texture,and magnetic properties of the sheet after normalizing,cold rolling and annealing at different temperatures were studied.The results show that with annealing temperature increase,the grain size and uniformity of annealed sheet increased.The main precipitates in coarse size of 0.5-2.5μm in annealed sheet were AlN and... 

采用磁控溅射方法,分别在纯Fe以及低硅钢基片上沉积富Si膜,并对其进行真空扩散热处理.通过能谱分析及X射线衍射研究了Si在纯Fe与低硅钢基体中的扩散特征,运用DICTRA软件建立了扩散模型.研究发现Si在纯Fe基体中扩散时发生γ-Fe(Si)→α-Fe(Si)相转变,扩散速率受控于相界面的迁移.当沿截面Si含量梯度不足以驱动相界面正向迁移时,延长扩散时间会发生相界面回迁现象,最终趋于单一相内均匀化扩散过程.Si在低硅钢基体中的扩散符合Fick扩散第二定律. Si-rich films were deposited on pure iron and low-Si steel substrates by direct current magnetron sputtering,and then were subjected to vacuum annealing.The distribution characteristics of Si across Fe and low-Si steel substrates were studied by energy spectrum analysis(EDS) and X-ray diffraction(XRD).DICTRA software was used to simulate the diffusion models.It is found that the diffusion behavior of Si in the Fe substrate is from γ-Fe(Si) phase to α-Fe(Si) phase and the rate of diffusion is con... 

通过对激光粒度分析仪测量硅钢级氧化镁(MgO)的分析条件进行优化,如分散介质、分散方式、样品预处理、仪器暗淡度等,探讨了硅钢级MgO粒度范围测量重现性较好的试验方法,满足硅钢生产过程控制对MgO粒度的要求。 The analysis condition of the laser particle size analyzer on grain oriented silicon-steel grade magnesium oxide is optimized,including the dispersion medium,dispersion methods,sample preparation,and instrument obscuration,etc.Therefore,particle size measurement with good reproducibility for silicon-steel magnesium oxide is discussed,which may meet the requirement of MgO particle size for silicon-steel process control.