硅钢资料

采用非水溶液电解方法来提取无取向硅钢中夹杂物。通过扫描电镜(SEM)观察结果表明:无取向硅钢中主要夹杂物为六棱柱的AlN、不规则硅酸盐及球状的铁的硫化物和氧化物,其中AlN夹杂尺寸在1~5μm,数量较多,还有部分AlN的复合夹杂。进一步研究了AlN复合夹杂形成机理,采用了Thermo-Calc热力学计算软件计算出该钢样中AlN、MnS析出温度分别为1 240℃、1 200℃,而Al2O3析出温度大于1 800℃,从而为AlN复合夹杂形成机理提供了一个理论依据。 Extracting inclusions from non-oriented silicon steel in non-aqueous electrolysis is a nondestructive method to gain inclusions.Scanning electron microscopy shows that the main inclusions in non-oriented silicon steel were hexagonal AlN,which was of large quantity,irregular silicate,spherical iron sulfide and oxide.The size of AlN inclusions ranged from 1to 5μm,and there were some duplex inclusions of AlN.To further study the formation mechanism of AlN duplex inclusions,Thermo-Calc thermodynamic... 

利用热模拟试验机、光学显微镜和X射线衍射仪对Fe-3.2%Si低温取向硅钢热轧工艺参数对组织及织构的影响进行了研究。结果表明,Fe-3.2%Si硅钢在1110℃粗轧、880℃终轧,轧后以10℃/s的速度冷却到550℃卷取,然后空冷到室温,热轧硅钢板沿板厚方向的显微组织不均匀性显著,对后续发展完善的二次再结晶有重要作用。无论是热轧板,常化板还是冷轧板,它们的织构集中分布在γ取向线上,γ取向线的织构除取向密度不同外,织构种类是一致的,这说明γ取向线上织构是有继承性的。从热轧到常化,织构取向密度显著减小,经二次冷轧后,织构密度又显著升高,可见,轧制变形有助于织构的形成并使织构强度升高。 The influence of hot-rolled process parameters on the microstructure and texture of Fe-3.2%Si low temperature hot rolled grain-oriented silicon steel were researched by hot simulation experiment machine,light microscope and X-ray diffractometer.The results show that,Fe-3.2%Si silicon steel is rolled by the technology with a temperature of rough rolling of1110℃,finish rolling of 880℃,coiling with the speed of 10℃ /s,and then cooled to room temperature with air.The microstructure of hot-rolled sil... 

选用国内外无取向硅钢标杆企业A、B、C的产品,采用非水溶液电解提取+SEM(EDS)方法,分析了其典型牌号对应成品试样中的夹杂物。结果表明,从磁性能控制角度而言,受钢的化学成分及生产工艺影响,A、B、C企业成品试样的夹杂物尺寸、种类、数量存在差异,这些差异对其磁性能产生显著影响;从夹杂物控制角度而言,A、B、C企业对应成品试样的夹杂物,以MnS、CuxS复合或者AlN、MnS、CuxS复合为主,其中1.0μm以下的夹杂物数量分别为2.34×107个/mm3、2.98×107个/mm3和11.98×107个/mm3,1.0μm以上夹杂物数量均很少,夹杂物的平均尺寸从大到小依次为A企业、B企业、C企业。 According to the production of three benchmarking manufacture enterprises A,B and C of non-oriented silicon steel at home and abroad,the inclusions in finished steel samples with typical grades were investigated by electrolytic extraction from non-aqueous solution and SEM(EDS).Results show that,from the viewpoint of improving the magnetic properties,affected by chemical composition and production technique,the size,type and amount of inclusions in finished steel samples are various,which will af... 

无取向硅钢的磁性能主要取决于铁素体的晶粒尺寸、晶体织构和钢中的夹杂物。通过合适的化学成分设计以及采用适宜的夹杂物控制技术,可以获得最佳的夹杂物控制效果,使其纯净度大幅度提高或者无害,最终获得磁性能优良的高级别无取向硅钢。同时,为满足节能、环保、高效需求,无取向硅钢正朝着节能降耗、环境友好以及多功能、高效率、易加工等方向发展。 The magnetic properties of non-oriented silicon steel mainly depend on the grain size of ferrite,the crystallographic texture,and the inclusions in the steel.The optimum inclusion control effects can be obtained through a suitable chemical composition design and an appropriate inclusion control technique,and then the liquid steel will get be clean or the inclusion will get be harmless,finally the excellent magnetic property of the non-oriented silicon steel can be obtained.Meanwhile,in order to ... 

两炉次无取向硅钢XG800WR（/%:0.003～0.004C、0.71～0.75Si、0.32～0.33Mn、0.004～0.007S、0.016P）的炼钢流程为铁水预处理（KR）-210 t顶底复吹转炉-钢包吹氩-RH脱碳精炼-230mm×1220 mm板坯连铸。53 t中间包钢水过热度为25～30℃,钢包到中间包采用长水口全程吹氩保护浇铸,中间包至结晶器采用浸入式水口浇铸。结果表明,在RH、中间包、结晶器过程中钢中总氧以及夹杂物数量和尺寸均明显降低;但在钢包到中间包过程T[O]、[N]和钢中夹杂物数量增加,说明长水口浇铸过程存在二次氧化。连铸坯中T[O]、[N]平均他分别为11×10^-6和30×10^-6,显微夹杂物数量平均为4个/mm²。铸坯中的显微夹杂物主要为3～5μm的AlN,同时存在少量的MnS、Al₂O₃·AlN和Al₂O₃·MgO·MnS。 The steelmaking flow sheet for two heats non-oriented silicon steel XG800WR（/%:0.003～0.004C. 0.71～0.75Si,0.32～0.33Mn,0.004～0.007S,0.016P） is hot metal pretreatment（KR）-210 t top and bottom combined blown converter-ladle argon blowing-RH decarburization refining-230 mm×1 220 mm slab casting.The superheating extent of liquid in 53 t tundish is 25～30℃,whole casting is shielded by blowing argon with long nozzle from ladle to tundish and the submerged nozzle is adopted in casting from tundish to mold... 

以质量分数为25%的丙烯酸乳液MC-102、15%Al(H2PO4)3溶液、0.01%H3BO3、0.01%Zn(Ac)2·2H2O和2%二乙二醇丁醚组分,在不同固化工艺下制备涂层。极化曲线和电导率测试发现300℃处理60 s得到的涂层具有良好的耐腐蚀性和绝缘性;水煮实验证明该涂层具有良好的耐水性;断口线扫描发现涂层具有良好的附着性。 A formula comprising MC-102 acrylic emulsion 25%,aluminium dihydrogen phosphate15%,boric acid 0. 01%,zinc acetate dihydrate 0. 01% and diethylene glycol monobutyl ether 2% was used to prepare coatings via different treatment process. The conductivity test and polarization curves revealed that a coating cured at 300 ℃ for 60 s showed good insulative and anticorrosive properties. The water boiling test indicated that the said coating had good water resistance. A cross section of the coating was in... 

对无取向电工钢中的夹杂进行了系统的分析。利用小样电解,采取不同电解液,不同的分离方法对无取向电工钢中稳定和不稳定夹杂物进行了提取、分离和收集。利用扫描电镜(SEM)、X-射线衍射、ICP等对电解分离收集的夹杂物进行了定性和定量分析。 The inclusion analysis of the non-oriented electrical steel has been investigated.By using small sample electrolytic analysis,with different electrolytes and different separation ways,the stable inclusions and unstable inclusions was drew,separated,and collected.With utilizing the methods of SEM,X-ray and ICP,the qualitative and quantitative analysis of inclusions in the non-oriented electrical steel was obtained. 

提出了一种基于爱泼斯坦方圈族(包括标准25cm爱泼斯坦方圈、缩比的17.5cm和20cm爱泼斯坦方圈)和二级加权处理方法对爱泼斯坦测试数据,包括有效磁路长度、比损耗、励磁功率,进行处理的晶粒取向电工钢磁性能扩展模拟方法。详细地考察了励磁频率、试样剪切角度和环境温度对爱泼斯坦方圈测量结果的影响。研究结果表明,利用本文提出的爱泼斯坦方圈组合以及二级加权处理技术,可以有效地建立取向电工钢损耗模拟模型,从而更加准确地确定了取向电工钢的损耗,改善并提高了爱泼斯坦磁性能测试数据的应用价值。 The extended modeling of the magnetic properties of GO(grain oriented) electrical steel is presented in this paper which is based on a set of standard and scaled-down Epstein frames and a proposed two-level weighted processing of Epstein data, including the mean magnetic path length, specific magnetization loss and exciting power. The effects of excitation frequency, strip angle and ambient temperature on the results obtained from the Epstein frames are investigated. It is shown that using the p... 

通过试验确定氩气分析流量为3.5L/min,静态流量为0.75L/min,冲洗时间为3s,预燃时间为12s,积分时间为5s的激发条件,采用火花源原子发射光谱法测定取向硅钢中碳、硅、锰、磷、硫。分别采用铣床铣样、砂轮磨样两种制样方式进行了精密度考察,发现制样方式对结果影响不大;讨论了取向硅钢样品中碳、硅、锰、磷、硫测定时可能存在的共存元素干扰,发现硅对锰元素的干扰不可忽略,采用干扰系数法进行了校正,据此拟合得到各元素校准曲线的相关系数均在0.999 0以上。精密度考察结果表明,碳、硅、锰、磷、硫的相对标准偏差(n=10)在0.71%~9.4%之间。对两块取向硅钢生产样品进行分析,并与钢铁研究总院进行比对分析,结果一致,且偏差均在允许范围内。 Carbon,silicon,manganese,phosphorus and sulfur in oriented silicon steel were determined by spark source atomic emission spectrometry.The selected excitation conditions were as follows:the analytical flow rate of argon was 3.5L/min,the static flow rate was 0.75L/min,the flush time was3s,the precombustion time was 12sand the integration time was 5s.Two sample preparation methods,including milling machine and grinding wheel,were investigated.The precision test results showed that,the determination... 

实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h... 

采用RH精炼添加钙合金方式对硅钢进行钙处理。结果表明,钙合金添加量为0.67、1.00、1.67kg/t钢时,钢中钙含量分别为0、2×10-6、4×10-6;随着钙合金添加量增大,钢中夹杂物粒度逐渐由0～2μm向2～4、4～6μm偏移;不同钙处理条件下,钢中均存在粒径小于1μm和粒径为1～5μm的MnS、CuxS夹杂物,后者或单独存在,或同AlN、CaS夹杂复合;粒径为5～10μm区间,钢中的夹杂物基本以钙的氧、硫化物为主。与钙处理前相比,钙合金添加量为0.67、1.00、1.67kg/t钢时,粒径小于1.0μm的微细夹杂物减少幅度分别为68.06%、87.50%、94.94%。钙合金添加量为1.67kg/t钢时,可以去除钢中绝大部分的微细夹杂物。 Ca alloy was added into the liquid steel during RH refining,and the results show that Ca concentration in final Si steel sheets is insignificant,about 0,2×10-6 and 4×10-6 when the added amount of Ca is 0.67,1.00 and 1.67 kg/t steel,respectively.With the increase in the added Ca alloy amount,the inclusions in the steel gradually change from those of 0～2 μm to those of 2～4 and 4～6 μm.Under different Ca treatments,there exist MnS and CuxS inclusions whose size is below 1 μm as well as MnS and CuxS ... 

对高牌号无取向电工钢35W300的成品进行了第二次退火,对第二次退火后的成品性能、纵横向磁性能差异和组织变化进行了分析。结果表明,随着第二次退火温度的升高,晶粒长大,磁性能优化。铁损平均值下降0.087 5W/kg,磁感平均值升高0.008T。第二次退火温度为820℃的产品的磁性能能够满足用户使用要求。 The product of high grade non-oriented electrical steel 35W300 was annealed at the second time.Microstructure,the difference of magnetic properties in the vertical and horizontal and were studied.The results show that the grain grew up and magnetic properties optimized with the increase of annealing temperature for the second time.Iron loss average declines in 0.0875 W/kg,magnetic induction average increases 0.008 T.The magnetic properties can meet the requirements of users at the second anneali...