硅钢资料

本发明公开了一种高磁感取向硅钢高效脱碳退火工艺，主要工艺流程为：炼钢连铸→热轧→酸洗常化→冷轧→脱碳和初次再结晶退火→渗氮处理(低温Hi‑B)→涂覆氧化镁隔离剂→高温退火→拉伸平整退火→涂覆绝缘涂层→精整，低温HiB不同于高温Hi‑B的工艺流程主要是在脱碳退火后增加了渗氮段。本发明在保证产品实物质量不低于现有水平(国内领先水平)的前提下，使Hi‑B钢退火效率达到世界领先，制造成本大幅降低。

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

介绍了国内、外电工钢极薄带的生产现状及市场应用的情况,以及典型生产企业的生产规模、产品性能和应用领域,指出扩大高牌号无取向电工钢生产、提高产品质量是目前电工钢发展的迫切要求。 The production situation and market application of ultra thin electrical steel strip at home and abroad were described.The production capability,product property and application area of typical corporation were introduced.The results indicate that the urgency needed of electrical steel development is expanding high-grade non-oriented electrical steel production and improving products quality at present. 

【作者】 谌剑； ...

研究了铝和铬元素在无取向电工钢晶粒长大过程中对织构及晶界变化的影响规律。试验结果表明:电工钢在晶粒长大过程中的主要织构组分均为{111}<112>。在晶粒生长期间,不加铝的1号试样中,{111}<112>、{111}<110>织构组分强化,而{100}<001>织构组分弱化;与1号试样相比,在加入0.2%的铝(质量分数,下同)的2号试样中,{111}<112>、{111}<110>织构组分强化(增加)的速率下降,{100}<001>织构组分变化不明显,甚至稍有增加。在含铝的试样中再加入0.3 5%的铬之后(3号试样),{111}<112>{、111}<110>和{100}<001>织构组分的变化规律与1号试样相似,但当电工钢中加入0.72%的铬之后(4号试样),上述3种织构组分的变化规律与2号试样相似。对于在晶粒生长期间持续变化的3种织构组分而言,1号试样的{1 1 1}<112>和{111}<110>织构组分的高(低)取向差角度晶界频率下降(... The effect rule of Aluminm and Chromium on texture and grain boundary transformation in the nonoriented electrical steel during grain growth was investigated.The experimental result shows that the main texture component is {111}<112> in the electrical steel.The {111}<112> and {111}<110> components in specimen 1 without Alumium were strengthened during grain growth whereas {100}<001> component was weakened.But the growth rate of {111}<112> and {111}<110> compon... 

本发明公开了一种消除取向硅钢单边浪缺陷的方法，其包括如下步骤：1)、制作专用盖板；所述专用盖板包括环形板，所述环形板外边缘设有多个剪开处；2)、将待装炉的取向硅钢钢卷吊运至高温退火炉炉台；3)、将专用盖板铺于取向硅钢钢卷上端面外圈；4)、将专用盖板上的各剪开处向下弯折，勾住取向硅钢钢卷外沿；5)、扣上内罩，内罩底边砂封；6)、钢卷进炉，完成高温退火过程。本发明能有效保护钢卷边部，防止钢卷上端面翻边；该方法还能将钢卷内部水分排出，避免钢带表面氧化。

本发明公开了一种高硅钢的冷轧生产工艺。该生产工艺属于机械制造技术领域，其中的处理工序的加热工序通过电磁感应加热装置加热，待处理钢经过加热工序的速度为30‑200mpm，加热工序的加热温度为70‑120℃。本发明具有生产效率高和生产质量高的特点，特别是在加热工序中对待处理钢采用电磁感应加热装置进行加热，使其可以快速有效地提升温度，以满足高硅钢的冷轧生产工艺要求，减少断带事故，具有很好的实用性和创新性。

研究了应用电感耦合等离子体质谱(ICP-MS)同时测定硅钢中痕量铝、钼、钒、钛、铌元素的分析方法。通过条件试验对测量参数进行了优化,确定RF功率1 400 W,泵速30rpm,采样深度140,雾化压力0.90。样品采用硝酸分解,以Be、Y混合内标校正了测量过程中高基体引起的信号漂移。根据测量时存在的质谱干扰情况,选择同位素27 Al、98 Mo、51 V、47 Ti和93 Nb作为测定同位素,同时通过调节仪器参数使得双电荷离子和氧化物离子的产率最低,以减少其带来的干扰。采用基体匹配法配制校准溶液,以标准加入法建立工作曲线,并扣除试剂空白。该方法各元素的测定下限均可达到1μg/g。用于硅钢标准样品的测定,所得结果与参考值完全吻合,各元素的RSD小于5.2%。 A method for the determination of trace aluminum,molybdenum,vanadium,titanium and niobium in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was described.A series of single parameter condition experiment was conducted.The optimized operation parameters with RF power 1 400 W,turbo pump rate 30 rpm,sampling depth 140 and nebulizer pressure 0.90 were obtained.The samples were dissolved by HNO3,and the Be and Y mixing internal standard were used to eliminate the signal drift c... 

一种提高有效氮和底层质量的高磁感取向硅钢制造方法：冶炼后连铸成坯；对铸坯加热；热轧、常化及酸洗后时效冷轧；在湿式气氛下脱碳退火；在湿式混合气氛下均热；在湿式混合气氛下渗氮退火；进行后工序。本发明与现有技术相比，通过合理控制渗氮过程，提高渗氮后钢板基体内氮含量与总氮量之间的比例达到80%以上，使无点状露晶产生，最终获得产品的底层质量优异。

某厂对电工钢的轧制策略进行了优化，粗轧道次由“1+5”改为“1+3”。在优化后的生产过程中，每次变换钢种，烫辊材就会出现窄尺现象，而紧随其后的电工钢板则出现超宽现象。文中针对该问题，介绍了宽度设定模型和宽度自适应模型的原理，阐述了该问题出现的原因及解决方案，并通过对宽度自适应模型的应用研究及优化攻关，有效地解决了问题，大幅提升了实物质量，降低了宽度封锁率。 The rolling strategy of electrical steel was optimized in a factory,and the rough rolling pass was changed from “1+5”to“1+3”.Subsequently,the following problems were occurred in the production process:when the steel grade changed,the roasting roller steel before the electrical steel appeared the narrow width phenomenon,and then the electrical steel appeared the ultra-wide phenomenon.This paper introduced the principle of width setting model and width adaptive model,and expounded the causes and s... 

分析了电感耦合等离子体发射光谱法(ICP-AES)测定硅钢中铌的检测过程,讨论了该检测过程中不确定度的主要来源,建立了该方法的定量的数学模型,并根据这一模型计算出了检测结果的合成标准不确定度和扩展不确定度。 The measurement of niobium content in silicon steel by inductively coupled plasma atomic emission spectrometry(ICP-AES) was analyzed,by which the main factors affecting the uncertainty of the measurement were ascertained and the calculation formula was given.Finally,according to the formula the combined uncertainty and expanded uncertainty were obtained. 

本发明涉及一种提高低温高磁感取向硅钢附着性的方法，该方法在现有低温高磁感取向硅钢连续式脱碳退火炉中，通过在脱碳退火前区通入氮气、氢气干式混合气，在脱碳退火后区通入氮气、氢气湿式混合气进行脱碳，在渗氮区通入氮气、氢气湿式混合气及氨气进行渗氮，解决了低温高磁感取向硅钢附着性不好的难题。本发明方法提高了钢中总氧量、增加了氧化层厚度、改善了氧化层结构，经高温退火后生成了致密的硅酸镁底层，附着性大幅提高，测试结果均在C级以上，大部分样品在B级以上。