硅钢资料

稀土元素在许多钢中发挥着独特而且不可替代的重要作用。半个世纪以来,它的作用已经在各种低合金和特殊合金钢中的研究及应用中得到充分的证明;然而,作为具有稀土资源优势的中国,在属于重要功能材料的无取向电工钢中稀土的应用却落后于国外,本文就中国稀土在无取向电工钢中的应用研究作简要的评述,希望能够进一步推进此领域的研究,并且促进中国稀土在无取向电工钢中应用技术的发展,缩短与国外差距,并提出了在此应用领域今后需深入开展的研究方向。 Rare earth elements play a unique and irreplaceable role in a lot of steels,it has given the full proof by the practice of various low alloy steels and special alloy steels since half century.However,as our country has the advantage of rare earth resources,RE application technology in non-oriented electrical steels has lagged behind abroad.The application researches of rare earth in non-oriented electrical steel in our country are briefly reviewed in this paper,which hope to promote the research... 

【摘要】 <正>3月底,宝钢\"低温高磁感取向硅钢制造...

采用取向分布函数和取向线分析方法对低温板坯加热取向硅钢从热轧到初次再结晶工艺阶段的织构进行了研究。研究表明:一次冷轧后各层的织构组分与热轧板各层面的织构组分存在着继承关系,次表层存在很强的{001}<110>织构,中心层的织构和热轧板的中心层相似,存在强的{001}<110>和{112}<110>织构;中间退火后发生再结晶,各织构组分的强度有所减弱,Goss织构组分再次出现;二次冷轧后沿厚度方向上的织构不均匀性不明显,{111}<112>织构强度最高,几乎是其他织构组分的1倍,{001}<110>织构大幅降低;初次再结晶后织构沿厚度方向没有明显的不均匀性,{111}<110>为最强的织构组分,并且具有一定强度的Goss位向。 The texture from the first cold rolling to the primary recrystallization of low temperature slab reheating grain-oriented electrical steel were researched by orientation distribution function and orientation distribution intensity technique.The results show that after the first stage of cold rolling,there is a strong {001}<110> texture in the subsurface and the texture in center layer is very similar to the center layer of hot band which has strong {001}<110> and {112}<110> tex... 

研究了组织和析出物对高效电机用无取向硅钢退火板磁性能的影响。结果表明:随着退火温度升高,退火板平均晶粒尺寸增加,P15/50明显降低,B50略有升高。退火温度在1 000℃时,退火板的综合性能较好。析出物主要是AlN、(MnS+AlN)和(MnS+Al2O3)复合析出物,尺寸较粗大,主要集中在1.0～2.5μm,还发现少量百纳米以下的细小AlN和TiN。实验室模拟TSCR流程试制的高效电机用无取向硅钢,铁损平均值小于4.00 W/kg,磁感应强度大于1.75 T,适合作中小型高效电机铁芯材料。 Effects of microstructure and precipitation on magnetic property of non-oriented silicon steel sheets after annealing for high-efficiency motor are studied in the paper by experiments.The annealed sheet exhibits a larger average grain size,obviously decreasing iron loss and slightly raising magnetic induction with increasing temperature.The annealed sheet has better comprehensive properties at a annealing temperature of 1 000 ℃.The main precipitates are compounds of AlN、(MnS+AlN)and(MnS+Al2O3) w... 

【作者】 朱凤泉； 黄生银； ...

以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc... 

取向硅钢热轧板中组织、织构梯度对发展完善的二次再结晶十分关键,通过对2种不同热轧工艺生产取向硅钢的组织、织构进行研究,结果表明:采用后道次大压下热轧工艺时热轧板表层再结区晶粒平均尺寸增加,再结晶区厚度增加,高温退火后二次晶粒尺寸减小;采用后道次大压下热轧工艺热轧时,热轧板中平均等效应变高,热轧板厚度心部{100}〈011〉和{100}〈001〉位向取向强度降低,({111}～{113})〈110〉位向取向强度提高,高温退火后{110}〈001〉位向偏离角降低,磁性能提高。 The texture and microstructure gradient in hot rolled grain oriented silicon steel strip was one of the essential factors to achieve a perfect secondary recrystallization.The texture and microstructure of grain oriented silicon steel strip as-rolled with two different hot rolling parameters was investigated.The results show that with big reduction at the end rolling process,the intensity of {100}〈011〉 and {100}〈001〉 orientation reduces with({111}-{113})〈110〉 orientation intensity enhanced in hot... 

无取向硅钢特别是中牌号以上的无取向硅钢,随着含硅量的提高,常温下塑性较差,冷轧过程中轧制力明显提高,如果存在原料质量问题,极易发生断带事故,影响硅钢冷轧过程的成材率和生产效率。通过优化冷轧工艺参数,可提高冷轧稳定性。生产中通过合理分配冷轧各道次压下量和轧制速度,保证了轧制过程的稳定,很大程度减少了冷轧断带事故的发生。 Non-oriented silicon steel, especially in the low and middle grade, with the increase of silicon content, plasticity is poor at room temperature, rolling force in cold rolling process significantly improved .If there is the quality defect of raw materials , easily sheet is rolling off. Affect finished product rate and production efficiency in process of cold-rolled silicon steel. Through optimization of cold rolled process parameter , improve the stability of cold-rolling process. Through reason... 

【作者】 刘彤； ...

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

对西昌钢钒炼钢厂200 t BOF(顶底复吹)-RH-CC工艺生产50PRW800无取向硅钢RH精炼过程中主要成份进行了分析。找出了目前工艺中影响钢液质量的主要因素是钢水脱氧处理不彻底,造成加入的部分硅元素烧损。操作工艺改为铝的脱氧即合金化操作一步完成,保证了钢水中氧处于一个较低的范围,从而减少对硅元素的烧损,提高合金收得率。 The factors of BOF-RH-CC process affecting the compositions of liquid steel were systematically investigated and studied of Xichang Steel and Vanadium Company. The main factors affecting the steel cleanliness were picked out. All results showed that the loss of silicon elements resulting from the deoxidization of liquid steel was not completely. It was suggested that the addition of aluminum for deoxidizing and alloying of molten steel was executed as one step in order to lower the oxygen potent... 

采用取向分布函数分析了无取向电工钢不同再结晶退火温度下的织构变化及织构对磁感应强度和铁损的影响,并计算了无取向电工钢的磁晶各向异性能。结果表明,随着实验钢的再结晶退火温度升高,Goss织构和立方织构组分显著增强,而{111}面织构强度却减弱。较高的退火温度有利于减小织构因子,提高磁感应强度。磁晶各向异性能计算结果显示,随着再结晶退火温度升高,无取向电工钢板的磁晶各向异性能降低。 The recrystallization texture and the relationship of texture to magnetic induction intensity and core loss of a non-oriented electrical steel were investigated by orientation distribution function analysis. The magnetic anisotropy energy of the steel was calculated also. The results show that,the intensity of Goss texture and cubic texture increases,but the intensity of { 111} texture decreases with increasing recrystallization annealing temperatures of the steel. The higher annealing temperatu...