硅钢资料

以不断增长的薄板坯流程为背景,与传统流程对比分析了薄板坯流程无取向电工钢热轧晶粒组织特征;以50W800和50W1300钢为典型实例,探讨了两种流程下成品板晶粒组织、织构、磁性能及其磁时效行为的基体差异和相关原理。研究表明,薄板坯流程热轧板组织较粗大,有利于在成品板中获得粗大的晶粒和有利的织构,从而得到较低的铁损和较高的磁感。然而,薄板坯流程会造成第二相粒子的细小弥散分布与不充分析出,容易因磁时效而使磁性能恶化。 Based on the rapid development of compact strip production(CSP) processing,the characteristics of hot band grain structure produced by CSP processing were analyzed in comparison with those of conventional technology.The basic differences in grain size,texture,magnetic properties and the magnetic aging behaviors of the final sheet products produced by the two processing technologies and the corresponding principles were discussed,while steel 50W800 and 50W1300 were taken as examples.It is indicat... 

采用CVD法制备6.5%Si高硅钢,介绍了具体的制备工艺过程,研究了温度对渗硅速率和试样质量减轻的影响,同时分析了扩散时间对高硅钢中硅分布的影响。结果表明:在CVD反应过程中,反应温度高于1050℃将大大提高渗硅速率,但当温度大于1200℃后,渗硅速率趋于稳定;渗硅后,试样会减轻、减薄,随着温度升高,试样质量减轻的速率逐渐增大,在1200℃左右趋于稳定;扩散时间越长,硅分布越均匀,结合制备效率进行考虑,满足Δw表-中/b≤5的时间为适宜的扩散时间。 6.5%Si high silicon steel was manufactured by using CVD method and the process was introduced,the influence of temperature on the siliconizing rate and quality reducing rate,diffusion time on silicon distribution were investigated.Results as follows: the siliconizing rate will increase quickly when the temperature is higher than 1050 ℃,but the siliconizing rate will become steadily as the temperature up to 1200 ℃;The quality reducing rate will increase with the elevating of temperature and the r... 

冷轧中中低牌号的无取向硅钢多采用万能凸度轧机(Universal crown mill,UCM)生产,其板形好坏受制于UCM轧机板形调节手段的协调使用。为掌握UCM轧机的板形控制特点,建立基于二维变厚度有限元的辊系弹性变形和基于三维差分的轧件塑性变形的六辊轧机耦合模型,对UCM轧机的板形调控性能进行详尽的分析,包括工作辊和中间辊弯辊、中间辊窜辊的调控功效、辊间接触压力分布等。在此基础上,提出可用指导生产的板形控制策略,指出UCM轧机在横向厚差控制方面的不足。针对工业生产中UCM轧机轧制无取向硅钢横向厚差大的问题,在大量仿真计算的基础上,开发具有高次曲线函数的边部变凸度(Edge variable crown,EVC)的工作辊。采用该工作辊后,各种品种的无取向硅钢的横向厚差不大于10μm的百分比由24%提高到99%,横向厚差的均值小于6μm,远小于之前的13μm。 Medium-low grade non-oriented silicon steel is rolled often by universal crown mill(UCM) during cold rolling.Its shape quality is dependent on the coordinated control of several shape adjustment devices of UCM.In order to understand the shape control characteristics of UCM,coupling model of six-high rolling mill,based on two-dimensional varying thickness finite element rolls elastic deformation model and three-dimensional finite difference strip plastic deformation model,is setup for the detaile... 

对低温法生产的以AlN为主抑制剂的Hi-B取向硅钢高温退火过程进行了中断实验,借助EBSD及TEM技术对高温退火连续升温过程中织构与析出物的演变进行了研究。实验结果表明,800℃时ODF图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;950~1 000℃时高斯晶粒异常长大,偏离角3~6°;高温退火过程析出物主要有球形、规则立方形及不规则多面体形3种形貌,由于渗N的影响,Zener因子先增大再减小,并且析出物在高斯晶界前沿优先粗化。 The annealing process at high temperature of Hi-B silicon steel using low slab reheat temperature and with AlN as the inhibitor has been studied by interrupting test,and the evolution of texture and precipitates during continuous heating-up in the annealing process at high temperature was analyzed by EBSD and TEM. The results showed that Goss texture appears in ODF at 800 ℃,but the intensity of Goss texture was very weak and the deviation angle was more than10°. Goss grains grow abnormally durin... 

采用XRD、SEM和激光粒度仪等手段,观察并研究了不同特性氧化镁在硅钢表面形成硅酸镁底层形貌特点,并结合热力学和差热-失重分析了MgO-SiO2的反应机理。研究结果表明:粒度小,活性值高的特种氧化镁在高温退火过程中与基体表面氧化物生成的硅酸镁底层,界面中硅酸镁底层嵌入基体较多,表面致密,颗粒细小,有利于形成附着性能优良的硅酸镁底层。 Surface microstructure of Mg2SiO4 coatings formed on the surface of oriented silicon steel coated with different kinds of MgO was investigated by XRD and SEM.The reaction mechanism between MgO and SiO2 was analyzed by TG-DSC and thermodynamic calculation.Results revealed that when the MgO with finer microstructure size and higher activity is employed,a dense Mg2SiO4 layer with finer microstructure and good binding to the steel substrate can be obtained.The results are very helpful for the prepar... 

采用经验设计法初步确定了取向硅钢铸坯感应加热线圈设计参数,应用Ansoft仿真软件分别对36组不同线圈高度、线圈内径的感应加热炉在不同频率下的三维整体磁场和铸坯的温度场进行了数值仿真。通过对比仿真结果,确定电磁场分布最佳的一组感应加热炉设计参数为线圈高度h=1.50 m、线圈内径D1=0.575 m、电流频率f=110 Hz。在该参数下应用Ansoft仿真软件对取向硅钢铸坯感应加热炉的温度场进行了仿真,结果发现温度场分布均匀,可满足取向硅钢铸坯加热要求。 The induction heating coil design parameters for the oriented silicon steel casting blank were determined preliminary by experience design method,and 36 groups three-dimensional electromagnetic field with different height and inside diameter of coil under different frequencies of the induction heating furnace and the temperature field of the casting blank were investigated by numerical simulation using Ansoft simulation software. By comparing the simulation results of electromagnetic field distr... 

冷轧无取向硅钢是高技术含量、高附加值产品,工艺复杂,生产周期长,过程控制难度大,被誉为钢铁产品中的\"工艺品\"。热轧生产工艺又是无取向硅钢生产的重中之重,直接决定了硅钢的铁损和电磁性等多项指标。 Cold rolled non-oriented silicon steel is high technology content、high addedvalue product. Its process is complex, Its production cycle is of Length, and Its Process control is difficult. Which is known as the iron and steel products \" Arts and crafts\". Hot rolling production process is the top priority of non-oriented silicon steel, Which Directly determines iron loss of the silicon steel and electromagnetic property, etc many index. 

在现普通冷轧无取向硅钢的基础上,降低Si含量,复合添加少量辅助元素,组合热轧板处理和成品退火加热技术,研制出了免常化处理的高磁感、低铁损并具有良好耐酸腐蚀性能的新系列无取向电工钢。 Based on existing common cold rolled non-oriented silicon steel,a new series of non-orientedelectrical steel with high induction,low core loss and excellent anti-corrosion property has been developed by reducing Si element,adding complexly a small amount of supplementary elements,and employing combined treatment of hot rolled sheet and finished product annealed heated technology. 

介绍了EB5325涂层液的主要性能和中冶新材生产冷轧无取向电工钢所用的涂层设备,通过多次试验摸索出使用EB5325涂层液的工艺,对涂层出现的缺陷进行分析研究,并提出解决方法,使中冶新材生产的冷轧无取向电工钢的涂层质量满足了用户的要求。 This article introduces the main properties of EB5325 and the coating equipments for cold-rolled non-oriented electrical steel. A process using EB5325 coating liquid is made through many time experiments and exploration. The appeared defects in the coating are studied and analyzed,and the solutions are proposed. The coating quality meets clients’ requirements of cold rolled non-oriented electrical steel. 

对低温加热工艺生产的普通取向(common grain-oriented,CGO)硅钢的高温退火过程进行了中断实验,材料为含3.0%Si、0.5%Cu、0.009 8%S(均为质量分数)的以Cu2S为主抑制剂的普通取向CGO钢。原始板坯厚度为230 mm,于1 200℃均热后经4道次粗轧、7道次精轧至2.3mm;热轧板采用两次冷轧法轧至0.3mm,中间完全脱碳退火,最后于1 200℃高温退火。最后样品的磁性能:铁损P17/50为1.182W/kg,磁感应强度B8为1.897T。借助配有EDAX OIM电子背散射衍射(EBSD)系统的ZEISS SUPRA 55VP扫描电子显微镜,对高温退火过程中高斯晶粒的演变进行了研究,结果表明:升温过程中晶粒尺寸增长缓慢,650℃时取向分布函数(ODF)图出现高斯织构组分,但强度很弱,高斯晶粒偏离角小于9°;950℃时高斯晶粒平均生长速度超过其他晶粒;950~1 000℃时高斯晶粒异常长大,偏离角降至约3°;在950℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势。 The high-temperature annealing process of common grain-oriented(CGO)silicon steel was investigated by interrupting test.The samples were rolled from CGO silicon steel slab under low reheating temperature.The CGO silicon steel,taking Cu2S as the main inhibitor,contains3.0%Si,0.5%Cu,and 0.0098%S.The original casting slab is 230mm in thickness.After 1 200℃reheating,four-pass rough rolling and seven-pass finish rolling were conducted to make the thickness of the slab get to 2.3mm.Then the hot rolled... 

采用磁控溅射方法,分别在纯Fe以及低硅钢基片上沉积富Si膜,并对其进行真空扩散热处理.通过能谱分析及X射线衍射研究了Si在纯Fe与低硅钢基体中的扩散特征,运用DICTRA软件建立了扩散模型.研究发现Si在纯Fe基体中扩散时发生γ-Fe(Si)→α-Fe(Si)相转变,扩散速率受控于相界面的迁移.当沿截面Si含量梯度不足以驱动相界面正向迁移时,延长扩散时间会发生相界面回迁现象,最终趋于单一相内均匀化扩散过程.Si在低硅钢基体中的扩散符合Fick扩散第二定律. Si-rich films were deposited on pure iron and low-Si steel substrates by direct current magnetron sputtering,and then were subjected to vacuum annealing.The distribution characteristics of Si across Fe and low-Si steel substrates were studied by energy spectrum analysis(EDS) and X-ray diffraction(XRD).DICTRA software was used to simulate the diffusion models.It is found that the diffusion behavior of Si in the Fe substrate is from γ-Fe(Si) phase to α-Fe(Si) phase and the rate of diffusion is con... 

为提高无取向硅钢导磁性能,研究了不同剪切方式对无取向硅钢剪切处磁畴结构的影响。利用纳米磁流体观测无取向硅钢剪切后边部磁畴结构。结果表明,硅钢无论在机械剪切还是线切割后的边部磁畴都会发生不同程度的改变:线切割对边部磁畴结构改变较小,边部磁畴分布均匀且连续,在距边缘0～20μm范围内出现磁畴宽度变小现象;机械剪切对磁畴的改变较为严重,剪切处磁畴零乱且不连续,在距边缘20μm处仍难以观察到完整的磁畴结构。 The effects of different shearing modes on magnetic domain structure of cold rolled non-oriented silicon steel are studied in this paper.The magnetic domain of cold rolled non-oriented silicon steel is observed by nanometer magnetic fluid pattern method.The results show that the edge magnetic domain structure will be changed by mechanical shear and wire-electrode cutting,the variation of edge magnetic domain structure wire-electrode cutting edge is very small,the magnetic domain structure is wel...