硅钢资料

采用ZMLMC超高梯度定向凝固装置,研究了5种凝固速率(10、35、80、150和450μm/s)对定向凝固50W600无取向硅钢的固液界面稳定性转变规律和一次、二次枝晶间距的影响。研究结果表明,在特定的温度梯度下,随着凝固速率的增加,定向凝固的固液界面由胞状晶转变为胞状枝晶,再转变为细小的树枝晶。随着凝固速率的增加,定向凝固组织的枝晶形貌逐渐细化,一次和二次枝晶间距逐渐减小,且与冷却速率之间都符合指数关系:λ1=151.73×(G L·R)-0.31,λ2=22.07×(G L·R)-0.44。当冷却速率达到4.275℃/s时,一次、二次枝晶间距分别为112μm、14.1μm。 Under the conditions of certain temperature gradient and different solidification rate,the directional solidification experiment of non-oriented electrical steel 50W600 was carried out.The microstructure of 50W600 steel was also analyzed in different solidification rate.The result shows that the solid/liquid interface of the steel undergoes an evolution from cellular,cellular dendrite and finally to fine dendrite morphologies.The dendrite refines gradually and the distance between dendrites decr... 

采用扫描电镜、场发射扫描电镜、能谱仪等对50SW1300冷轧无取向硅钢中的夹杂物分不同尺寸区间进行数量统计,利用主成分回归分析法,即数据的标准化处理—主成分分析—回归分析—标准化的变量还原成原始变量—确定显著影响因素,综合分析夹杂物总量及各尺寸区间的夹杂物数量对无取向硅钢磁性能的影响。结果表明:主成分回归分析能够从夹杂物尺寸区间及数量的多个影响因素中提取主要的因素,定量研究其对磁性能的影响。分析表明,显著影响无取向硅钢铁损的夹杂物为100~500nm的AlN、AlN+MnS、MnS、Al2O3、AlN+Al2O3,而劣化磁感最明显的夹杂物尺寸区间为100~200nm。 Different size intervals of inclusions in cold rolled non-oriented silicon steel 50SW1300 were counted by scanning electron microscope(SEM),field emission scanning electron microscope(FESEM)and energy disperse spectroscopy(EDS).With principal component regression method:standardization for experimental data,principal component analysis,regression analysis,transform standardized variables into original variables,determination of significant factor,effects of the total number of inclusions and the... 

研究了采用高温卷取热轧态原料和常化态原料生产高牌号冷轧无取向电工钢组织、织构和磁性能。研究发现钢卷采用750℃高温卷取,下线后立即采用\"保温罩\"对钢卷进行保温,时间96h,然后空冷至100℃时上线生产的工艺可取代常化工艺生产高牌号冷轧无取向电工钢。冷轧上线前,热轧态原料的表层为大量的再结晶组织,这部分组织包括了热轧轧制时保留下来的动态再结晶组织,钢卷本身高温回复后产生再结晶晶粒,以及在保温罩内保温时形成的再结晶组织。高温卷取的热轧态和常化态的热轧卷作为原料时,试样织构类型相似,取向分布密度接近,再结晶后织构类型仍然相似,取向分布密度仍然接近。Goss织构对磁性能增加有促进作用。实验钢中较好的磁性能对应的织构[{100}+Goss]/{111}的比值较高,体现了织构的遗传性。 Microstructure,texture and magnetic properties of high grade cold rolled nonoriented electrical steel which made of hot rolled material with high temperature coiling and with normalization were studied.Steels coiled in high temperature(at 750 ℃),stacked with insulation cover for 96hand air cooled to 100 ℃ were using to manufacture high grade nonoriented electrical steel.The process can replace the normalization process.There are a lot of recrystallized grains in the surface layer of the coil wit... 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

本文研究了丙烯酸树脂含量对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同树脂含量对硅钢绝缘涂层的耐盐雾性能和电化学行为的影响,同时采用SEM对涂层的表面形貌和附着性进行研究.结果表明,树脂含量为19.9~29.4%时,涂层的耐蚀性和附着性最好;树脂含量过多时,涂层的耐蚀性和附着性均较差. This paper studies the influence of acrylic resin on the performance of insulating coating of aluminum dihydrogen phosphate on chromium-free non-oriented silicon steel.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of acrylic resin content on the salt spray resistance and electrochemical behavior of the insulation coating of nonoriented silicon steel.The surface morphologys and adhesion of coating were tested by SEM.... 

为了确保硅钢铬酸盐涂料的环保性,需要严格控制涂料的固化工艺,保证涂料固化过程中涂料中的六价铬充分转化为三价铬。对涂料及原料进行热重分析(TG)及差示扫描量热法分析(DSC)。结果表明,MgO与铬酐混合转化为MgCrO4,使六价铬稳定性增强,其中大部分Cr6+转变为Cr3+发生在620~700℃,在450~500℃高于铬酐发生大量失重,因此必须加入还原剂保证涂料中六价铬被充分还原;超过360℃后树脂会发生分解,因此实际板温不能超过360℃;加入了还原剂的整体涂料的失重温度区间主要在260~320℃,因此涂料固化时钢板的实际温度最佳区间为320~360℃。 Because of the silicon steel chromate coating’s environmental requirements,the paint curing process must be controlled strictly to ensure all Cr( Ⅵ) transforms to Cr( Ⅲ). The TG and DSC analyses of the paint are studied. The reaction of MgO and CrO3 would generate MgCrO4,enhancing the stability of Cr( Ⅵ). The most r( Ⅵ) in MgCrO4 changes to Cr( Ⅲ) at 620-700 ℃,while the CrO3 has a large weight loss at 450-500 ℃. The reductant must be added in the paint to make sure the Cr( Ⅵ) could transform suf... 

对西昌钢钒炼钢厂200 t BOF(顶底复吹)-RH-CC工艺生产50PRW800无取向硅钢RH精炼过程中主要成份进行了分析。找出了目前工艺中影响钢液质量的主要因素是钢水脱氧处理不彻底,造成加入的部分硅元素烧损。操作工艺改为铝的脱氧即合金化操作一步完成,保证了钢水中氧处于一个较低的范围,从而减少对硅元素的烧损,提高合金收得率。 The factors of BOF-RH-CC process affecting the compositions of liquid steel were systematically investigated and studied of Xichang Steel and Vanadium Company. The main factors affecting the steel cleanliness were picked out. All results showed that the loss of silicon elements resulting from the deoxidization of liquid steel was not completely. It was suggested that the addition of aluminum for deoxidizing and alloying of molten steel was executed as one step in order to lower the oxygen potent... 

运用EBSD和光学显微镜,研究了0.25%~0.45%Cu对无取向电工钢热轧板显微组织,成品板显微组织、织构和磁性能的影响。实验结果表明:卷取过程中Cu元素在热轧板表层的偏聚作用显著阻碍了热轧板表层再结晶晶粒长大,导致热轧板表层晶粒尺寸随着Cu含量增加而逐渐较小,但热轧板中间晶粒尺寸变化不大。同时发现Cu元素能够明显改善织构类型,使有利织构组分增加,不利织构组分减少,同时减弱织构强度。从实验结果可知0.35%Cu能够显著改善电工钢的磁性能,铁损P15/50最低达到4.1 W/kg,磁感B50最高值达到1.8 T。 Effects of high content Cu on microstructure of hot rolled plates and microstructure,texture and magnetic properties of annealed finish product plates of non-oriented electrical steel were examined by means of EBSD technique and optical microscope. The results show that surface segregation of Cu significantly hindered recrystallized grain growth of surface layer in hot rolled plate during the coiling,as a result,the surface grain sizes of the hot-rohed plates decrease with the increase of Cu con... 

随着中国电工钢产量的增加,硅钢级氧化镁需求量不断增加,传统的以白云石为原料制备氧化镁的工艺已经无法满足市场需求。中国是一个卤水资源丰富的国家,因此,研究如何资源化综合利用盐湖资源变得越来越重要。硅钢级氧化镁是一种制备取向硅钢的涂层材料,主要用于取向硅钢高温退火处理阶段,起到隔离剂、绝缘膜层、脱硫、脱磷等作用。综述了制备硅钢级氧化镁的方法、工艺流程、研究进展及存在的问题,指出了硅钢级氧化镁制备技术的发展方向,并对中国卤水资源的利用提出了建议。 With the increasing output of electric steel,the demand for silicon steel grade magnesium oxide(MgO) is larger and larger in China,and the traditional MgO production process with dolomite as raw material has been unable to meet market demand.China is a brine resource-rich country,the study of how to comprehensively utilize salt lake resources has become increasingly important.As a coating material used for preparing oriented silicon steel,silicon steel grade MgO is mainly used in the process of ... 

【作者】 汤婧； ...

冷轧无取向硅钢（/%:0.003C,2.35Si,0.22Mn,0.011P,0.002S,0.36A1,0.003 0N）经890℃或940℃3 min常化的2.3 mm热轧板冷轧成0.35 mm薄板。研究了常化温度和800⁹20℃3 min退火对该钢高频（400Hz）磁性能和抗拉强度的影响。结果表明,830⁹20℃退火时高频铁损P_10/400值最低,随退火温度增加,晶粒尺寸增大,钢的抗拉强度降低;该钢的最佳热处理工艺为常化温度940℃,退火温度830℃,其抗拉强度R_m、高频铁损P_10/400和磁感应强度J₅₀分别为565 MPa,21.5 W/kg和1.69 T。 The cold-rolled non-oriented silicon steel（/%:0.003C,2.35Si,0.22Mn,0.011P,0.002S,0.36A1,0.003 0N） is cold-rolled to 0.35 mm sheet from 2.3 mm hot-rolled plate normalized at 890 ℃ or 940℃ for 3 min.The effect of normalizing temperature and annealing process at 800 ⁹20 °C for 3 min on high frequency（400 Hz） magnetic properties and tensile strength of the steel has been tested and studied.Results show that with annealing at 830 920 ℃the high frequency iron loss value P_10... 

对RH法(真空循环脱气法)生产的冷轧硅钢的脱硫原理及影响因素进行了分析研究。研究表明:降低顶渣中FeO、MnO的含量,提高钢液温度,增加脱硫剂的加入量并延长其循环时间有利于提高脱硫效率。 The principles of desulfurization and its influence factors of cold rolling silicon steel during RH process have been studied in this paper.The result indicated that reducing contents of FeO and MnO,rising temperature of the liquid steel,increasing quantity of desulfurizer,lengthening cycle time of desulfurzer are benefit for desulfurization.