钢厂
硅钢RH处理过程碳和硫行为分析
分析了太原钢铁(集团)有限公司第二炼钢厂80 t RH生产冷轧硅钢脱碳、脱硫原理及影响因素,认为通过合理控制RH到站钢水碳和氧含量、加大插入管内径、采用快速抽真空度等可提高脱碳效果。降低顶渣中FeO和MnO含量,保证脱硫剂加入后的循环时间可以提高RH脱硫率。 The present article analyzes the principle of decarburization and desulfurization in refining the cold rolled silicon steel in the 80 t RH in No.2 Steelmaking Plant of Taiyuan Iron & Steel(Group) Corp.,and its influencing factors.It’s determined that the decarburization effect can be achieved by properly controlling the cabon and oxygen contents in the hot metal coming into the RH station,enlarging the inner diameter of snorkel and adopting the fast evacuation method.In the meanwhile the des...
碳化法制备硅钢氧化镁过程中杂质脱除研究
以轻烧氧化镁粉为原料,经消化、碳化制得重镁水,在热解反应前采用络合剂对重镁水中的杂质钙、铁进行络合掩蔽,再经热解得到碱式碳酸镁,碱式碳酸镁经煅烧可制得钙、铁杂质含量较低的氧化镁。在重镁水络合除杂过程中,考察了络合剂三乙醇胺、柠檬酸、草酸单独和复合使用的除铁、除钙效果。以三乙醇胺为络合剂时,在200 mL重镁水中加10 mL三乙醇胺(1∶1),氧化镁产品中w(氧化镁)=99.3%、w(氧化钙)=0.31%、w(氧化铁)=0.042%;使用草酸和柠檬酸作为复合络合剂时,在200 mL重镁水中加入1.0 g柠檬酸和2.0 g草酸,氧化镁产品中w(氧化镁)=98.2%、w(氧化钙)=0.24%、w(氧化铁)=0.030%。 Light-burned magnesia as a raw material was hydrated and carbonated to obtain magnesium bicarbonate liquor.Before the pyrolyzing of magnesium bicarbonate liquor,complexants were used to cover Fe and Ca impurities.Then the treated liquid was pyrolyzed to obtain basic magnesium carbonate which was calcined to magnesium oxide with low calcium and iron content.During the complexing purification of magnesium bicarbonate liquor,the Fe and Ca removing effects of single or compound complexing agents,suc...
剪切方式对冷轧无取向硅钢边部磁畴的影响
为提高无取向硅钢导磁性能,研究了不同剪切方式对无取向硅钢剪切处磁畴结构的影响。利用纳米磁流体观测无取向硅钢剪切后边部磁畴结构。结果表明,硅钢无论在机械剪切还是线切割后的边部磁畴都会发生不同程度的改变:线切割对边部磁畴结构改变较小,边部磁畴分布均匀且连续,在距边缘0~20μm范围内出现磁畴宽度变小现象;机械剪切对磁畴的改变较为严重,剪切处磁畴零乱且不连续,在距边缘20μm处仍难以观察到完整的磁畴结构。 The effects of different shearing modes on magnetic domain structure of cold rolled non-oriented silicon steel are studied in this paper.The magnetic domain of cold rolled non-oriented silicon steel is observed by nanometer magnetic fluid pattern method.The results show that the edge magnetic domain structure will be changed by mechanical shear and wire-electrode cutting,the variation of edge magnetic domain structure wire-electrode cutting edge is very small,the magnetic domain structure is wel...
ZnO对硅钢绝缘涂层组织与性能的影响
通过制备磷酸二氢铝硅钢涂层,研究了氧化锌对无铬涂层耐盐雾性能、电化学性能和附着性的影响。结果表明,硅钢表面涂层含有4.0%的氧化锌时,涂层具有最高的耐腐蚀性能和电化学性能,而且其致密表面最为平整,没有裂纹出现。 The effects of ZnO on the salt spray resistance property, electrochemical performance and adhesiveness of silicon steel insulating coating were studied. The results show that the best corrosion resistance and electrochemical properties can be obtained when the coating contains 4.0% oxide zinc, and the dense surface is smooth without cracks.
6.5%Si硅钢的制备技术和发展前景
6.5%Si硅钢具有优异的磁学性能和广泛的应用前景。本文综述了6.5%Si硅钢的物理、机械及磁学特性,讨论了传统轧制、温轧、薄带连铸、快速凝固、CVD、粉末轧制等不同制备工艺的关键技术及特点,概括了6.5%Si硅钢在高效节能电机、汽车马达及磁屏蔽等领域中的主要应用,介绍了硅钢的制备技术取得的研究进展,并指出了其广阔的发展前景。 6.5% Si silicon steel has good magnetic properties and wide applications.In this paper physical and mechanical magnetic properties were summarized,and key technology and characteristic of several preparation methods,such as traditional rolling,warm rolling,thin strip continuous casting,rapid solidification,CVD and powder rolling,were discussed.Main applications of 6.5% Si steel in the fields of high-efficiency electrical motors,automobile motors,transformer cores and magnetic shielding were gene...
稀土处理无取向硅钢中的夹杂物与电磁性能变化
结合工业化生产的无取向硅钢,进行了RH精炼添加稀土合金实验。结果表明,1.15%(质量分数)Si钢的脱硫反应,主要发生在添加稀土合金之后的前5min。最佳的稀土合金添加量为0.6~0.9kg/t钢。钢液经过稀土处理后,加入的稀土总量越多,稀土氧硫化物夹杂物的尺寸就越大,但热轧带钢再结晶效果会逐渐变差,成品带钢晶粒尺寸先是快速长大,而后逐渐减小。最佳的钢中存留稀土含量与钢的化学成分有关,应严格控制在2.0×10-3%~6.0×10-3%(质量分数)。在此范围内,钢的铁损先是快速降低,而后缓慢升高,钢的磁感应强度则单调降低。 Based on the industrial production of non-oriented electrical steel,rare earth(RE) alloy treatment during the RH refining process was studied.The results showed that the effects of desulfurization and total concentration of RE remained in steel mainly depended on the chemical compositions of different steel grades.For 1.15wt% Si steel grade,the desulfurization reaction mainly focused on the initial 5min after RE alloy added during the RH refining process.The suitable RE alloy addition was 0.6-0....
试样剪切应力对冷轧无取向电工钢磁性能的影响
电工钢试样加工产生的剪切应力会恶化钢板的磁性,对不同牌号硅钢片的横向、纵向试样退火前后磁性能的变化进行研究,结果表明:无取向硅钢片在剪切过程中横向、纵向的磁性受到剪切应力影响是不一样的。 The electrical steel sample processing magnetic of electrical steel will worsen due to the shear stress of sample. In this paper,the magnetic change of transverse,longitudinal specimens of different type of silicon steel sheet before and after annealing are studied. The results show that the magnetic of non- oriented silicon steel sheet affected in the process of shear is not the same in horizontal and vertical direction.
电力变压器用高磁感取向硅钢的发展及应用
阐述了国内外高磁感取向硅钢的生产研究水平与发展趋势,包括通过提高高斯晶粒取向度、细化磁畴、涂覆张力涂层、减薄钢片厚度进一步降低铁损以及低温加热技术和短流程技术新工艺。分析高磁感取向硅钢在我国大型电力变压器上的应用情况,结果表明,发展更薄规格高磁感、低铁损、低磁致伸缩取向硅钢可为大型变压器的安全性、节能性及环保性提供有效保障。 The research progress and development trend of high magnetic induction grain-oriented silicon steel at home and abroad are summarized,including the technology of improving the Goss alignment,refining domain wall,adding stress coating,decreasing thickness of sheet,and the new technique of reducing heating temperature of casting slab and shortening operational.Moreover,the application of high magnetic induction grain-oriented silicon in power transformer is presented.Developing grain-oriented sili...
ZnO对无铬无取向硅钢绝缘涂层性能的影响研究
主要研究了氧化锌对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响.用盐雾实验和动电位极化研究了不同氧化锌含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响.采用SEM和体视显微镜对涂层的表面形貌和附着性能进行研究.结果表明,氧化锌含量为4.0%时,氧化锌能完全中和涂层表面的游离磷酸,涂层的耐蚀性和附着性最好;氧化锌含量过少或过多时,涂层的耐蚀性和附着性都较差. This paper studies the influence of zinc oxide on the performance of chromium-free non-oriented silicon steel insulating coating which based on aluminum dihydrogen phosphate.Salt spray experiment and potentiodynamic polarization were used to study the influence of zinc oxide content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.The surface morphology and adhesion of coating were tested by SEM and stereo microscope.The results show that when t...
冷轧压下量对取向硅钢极薄带显微组织的影响
观察了取向硅钢极薄带经冷轧至不同厚度,并经过不同工艺热处理后的显微组织及亚结构。结果表明:冷轧压下量越大,显微组织中位错密度越高,冷变形组织越多,等轴晶粒越少;增加冷轧压下量可以使试样的再结晶温度降低,当钢带厚度为0.08 mm时,在650℃退火时就能发生明显的再结晶。 Microstructure and substructure of the grain oriented ultra-thin silicon steel sheets is analyzed,which are rolled down to different thickness and treated with different heat treatment process.The result shows that there are higher dislocation density,more cold deformation structure and less equiaxed crystal grain in microstructure of the steel sheets with more cold rolled reduction.Increase of cold rolled reduction will decrease recrystallization temperature,and when thickness of the steel shee...
一次再结晶法取向硅钢超薄带的冷轧塑性变形行为
以市场上购买的取向硅钢成品板为原料,经不同压下率冷轧至0.23~0.08 mm不等。借助X射线衍射仪(XRD)检测了冷轧后样品中的织构组分及其含量,利用电子背散射技术(EBSD)测量了试样的取向因子分布情况。观察了孪晶的形貌与晶体学特征,分析了硅钢超薄带的塑性变形行为。结果发现,在平面压缩应力下,{112}<111>滑移系的取向因子较大。随冷轧压下率的增加,Goss织构的含量逐渐减少,{212}<141>织构组分的含量先增加后减少,{111}<112>织构组分的含量逐渐增加,织构组分以{110}<001>→{212}<141>→{111}<112>顺序演变。冷轧后样品中出现了孪晶,其晶体取向为{001}<110>,冷轧过程中孪晶取向没有发生变化。 The commercial finished oriented silicon steel plate as the raw material were rolled to 0.23-0.08 mm. With the X-ray diffractometer(XRD), the texture components and their volume fractions in the cold-rolled samples were detected. And the orientation factor distribution of the cross-section of the samples was measured by the electron backscattering technique(EBSD). The morphology and crystallographic characteristics of twins were observed, and the plastic deformation behaviors of the ultra-thin o...

