钢厂
低温高磁感取向硅钢高温退火过程高斯晶粒的演变
对低温加热工艺生产的以AlN为主抑制剂的高磁感取向硅钢高温退火过程进行中断实验,借助电子背散射衍射技术对高温退火过程中高斯晶粒的演变进行了研究.在升温过程中高斯晶粒平均尺寸先减小再增大.800℃时取向分布函数图出现高斯织构组分,但强度很弱,高斯晶粒偏离角在10°以上;900℃时高斯晶粒平均生长速率超过其他晶粒;950~1000℃时高斯晶粒异常长大,偏离角3°~6°;在1000℃之前高斯取向晶粒相比于其他晶粒没有尺寸优势. The high-temperature annealing process of high permeability grain-oriented silicon steel with AlN as an inhibitor was studied by interrupting test.The evolution of Goss texture in this process was analyzed by electron back-scattered diffraction.It is found that the Goss grain size first decreases and then increases with the rise of temperature.Goss texture appears in the orientation distribution function at 800 ℃,but the intensity is very weak and the deviation angle is more than 10°.The average...
低铁损高磁通密度无取向硅钢的应用与生产技术进展
分析了高转矩和高转速条件下高效驱动马达铁芯材料对无取向硅钢磁性能要求,讨论了无取向硅钢的高磁通密度和低铁损对电机转矩和效率的影响,介绍了国内外高磁感无取向硅钢发展情况。在生产工艺上,提高钢质纯净度,弱化夹杂物和第二相粒子对畴壁移动和再结晶晶粒长大的钉扎作用,添加微量晶界和带钢表面的偏析元素促使有利织构发展等技术可提高无取向硅钢的磁通密度。 The requirements of high efficient drive motor core materials under the conditions of high torque and high speed were analyzed.The effects of high magnetic flux density of non-oriented silicon steel on the torque and efficiency of the motor were discussed.The development of non-oriented silicon steel with high magnetic was introduced.The magnetic flux density of non-oriented silicon steel sheet can be obviously improved by some production technologies,such as purification steel,weakening the pin...
无取向硅钢夹杂物分析
采用非水溶液电解方法来提取无取向硅钢中夹杂物。通过扫描电镜(SEM)观察结果表明:无取向硅钢中主要夹杂物为六棱柱的AlN、不规则硅酸盐及球状的铁的硫化物和氧化物,其中AlN夹杂尺寸在1~5μm,数量较多,还有部分AlN的复合夹杂。进一步研究了AlN复合夹杂形成机理,采用了Thermo-Calc热力学计算软件计算出该钢样中AlN、MnS析出温度分别为1 240℃、1 200℃,而Al2O3析出温度大于1 800℃,从而为AlN复合夹杂形成机理提供了一个理论依据。 Extracting inclusions from non-oriented silicon steel in non-aqueous electrolysis is a nondestructive method to gain inclusions.Scanning electron microscopy shows that the main inclusions in non-oriented silicon steel were hexagonal AlN,which was of large quantity,irregular silicate,spherical iron sulfide and oxide.The size of AlN inclusions ranged from 1to 5μm,and there were some duplex inclusions of AlN.To further study the formation mechanism of AlN duplex inclusions,Thermo-Calc thermodynamic...
硅钢高温氧化铁皮的显微结构表征
利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy...
低硅钢冶炼过程硅质量分数控制
抑制回硅是低硅品种钢冶炼的重点和难点,南钢中厚板卷厂通过转炉出钢弱脱氧操作,精炼炉弱脱氧升温,脱氧、脱硫造渣,连铸严格的保护浇注及吹氩塞棒、吹氩浸入式上水口的应用等一系列工艺优化和操作的改进,使整个冶炼过程钢水回硅量稳定控制在200×10-6以内,钢水终点成分完全满足低硅钢要求。 Control of increasing silicon is the emphasis and difficulty in low silicon varieties steel smelting.The Nisco Wide Plate/Coil Plant can control the silicon content in molten steel keeping within 200×10-6 through whole steelmaking process by using oxygen residual operation in converter tapping,oxygen residual and increasing temperature,deoxidation,desulfurization,slag refining,protection cast,blowing argon by plugged nozzle,blowing argon by submerged entry nozzle in continuous casting,and other ...
无取向硅钢铬酸镁绝缘涂层结构与耐蚀性能研究
采用扫描电镜、原子力显微镜研究了铬酸镁半无机绝缘涂层的微观结构。结果表明,涂层厚度为数微米,涂层中的有机树脂乳液颗粒均匀分布在无机涂层的表面,从而保证了涂层具有良好的冲片性能。采用极化曲线研究了涂层的耐蚀性能,发现铬酸镁与铬酸锌绝缘涂层的耐蚀性能相当。 In this paper,the microstructure and anti-corrosion property of magnesium chromate coating on non-oriented silicon steel were studied.The microstructure was observed by SEM and AFM.The anti-corrosion properties were evaluated by polarization curves.The results show that the thickness of coating is several microns and the polymer particles were scattered on the surface of inorganic coating,which is the guarantee for lamination property.The corrosion resistance of the magnesium chromate film was e...
火花源原子发射光谱法在线测定电工钢中的超低碳
采用火花源原子发射光谱分析测定电工钢中超低C,研究试样制备方法、Ar纯度和压力等条件对分析结果的影响,并对工作曲线进行了优化,实现了一次分析同时测定电工钢的多种元素,满足炉前和精炼在线分析的要求。 Ultra-low carbon in electrical steel is determined with spark-source atom emission spectrum.It is researched the influence of sample making method,purity of Ar,and pressure on analysis result.The work curve is optimized.The determination of many elements in electrical steel only in one analysis is realized.It meets demands of on-line analysis for blast furnace and refining.
400mm硅钢自动轧制试验轧机
西安重型机械研究所为武钢开发了目前国内第一台自动化水平较高的先进可靠的硅钢热轧试验轧机。本文介绍了该轧机的工艺参数、设备组成,技术特点及轧制流程,该轧机在规定的终轧温度范围内,实现了2.5 m/s的快速轧制速度,保证了控制系统准确及时的采集到轧件进出轧辊时的信号,缩短道次间隙时间,实现了自动控制,保证了产品板形及精度的高水平要求,对于硅钢尤其是对其取向硅钢新产品、新工艺的开发具有深远意义。 An experimental prototype of 400 mm silicon steel hot rolling mill was developed by Xi’an Heavy Machinery Research Institue for Wu Gang.The technological parameters,configuration and characteristic of advanced control system in the experimental prototype are introduced in detail.The experimental prototype was realized the fast rolling of 2.5 m/s in the range of specified rolling temperature.Its automatic rolling control system can acquisite the signals that a rolled piece enters in and exits fro...
硅钢连续退火炉无氧化加热段辐射换热研究
以能量平衡和辐射换热理论为基础,通过合理假定,建立了硅钢无氧化加热炉数学模型。采用数值计算的方法,通过自编程序,完成对带钢加热过程温度场的仿真。结果显示:数学模型能够反映带钢在无氧化炉内的加热过程,其升温曲线能够与工艺曲线相吻合;现行炉温分布并非最优,数学模型能够为炉温分布的优化、炉段的设计提供理论依据。 Mathematical model of NOF Section of Continuous Annealing Furnace is established based on energy balance and radiation heat exchange. The temperature field of steel is simulated by mathematical computation. The simulating results show that the mathematical model can reflect the heating process of silicon steel in NOF section, and the heat-up curve is coincide with the processing curve. From the results,it is known that the current furnace temperature gradient is not the best, and the mathematica...
无取向硅钢热轧卷结疤缺陷产生的原因及控制
针对不同牌号的无取向硅钢产生结疤缺陷的难易程度和表面结疤缺陷的外形特征及分布规律,分析了该缺陷产生的原因。通过调整剪前导板的对中度,设置精轧侧导板开度余量及短行程数值,及时修补与更换侧导板,减少带坯与侧导板挤撞程度,有效地降低了结疤缺陷发生率。 This article analyses the cause of the scab defects according to the defects appearance characters and distribution law,degree of difficulty to form scar of non-oriented silicon steel. It can effectively decrease the scabs by different methods,such as adjusting the center line of guide plate,setting the opening margin and short stroke value of the side guide on finishing mill,timely repairing and replacing of side guide,decreasing the collision between the strip and side guide.