钢厂
双辊连铸法制备硅钢薄带的组织和性能
采用双辊连铸工艺制备了硅的质量分数分别为0.5%,1.0%,3.0%,4.5%的硅钢薄带,用光学显微镜观察其组织,并研究了后处理工艺对薄带组织和性能的影响。结果表明:硅含量为0.5%和1.0%的薄带适合采用一次冷轧+850~950℃退火的后处理工艺,而硅含量在3.0%以上的薄带适合采用二次冷轧+950℃退火的后处理工艺;硅含量为3.0%和4.5%的薄带在冷轧并950℃退火后,其磁性能最佳,铁芯损耗约为4.30 W·kg-1,磁感应强度约为1.68T。 Silicon steel thin strips with silicon content of 0.5wt%,1.0wt%,3.0wt%and 4.5wt%were prepared by twin-roll continuous casting process,and the microstructure of the strips were observed by means of optical microscopy,and on the basis,the effect of post-treatment process on microstructure and properties of the strips was studied.The results show that the post-treatment process of one-time cold rolling and annealing between 850—950℃was suitable for the strips with silicon content of 0.5wt%and 1.0wt...
Sn含量对高磁感取向硅钢热轧板织构的影响
实验室模拟薄板坯连铸连轧(TSCR)流程制造高磁感取向硅钢,借助电子背散射衍射(EBSD)技术对不同Sn含量的热轧板织构进行了研究。研究结果表明:不同Sn含量热轧板表层及次表层均为高斯织构、铜型织构及黄铜织构的混合织构,中心层为{100}面织构;Sn含量为0.1%时,热轧板表层及次表层高斯织构组分最多,取向密度最大,成品磁感最高,达到1.875 T。 Texture of grain oriented silicon steel hot rolled by thin slab casting and rolling process(TSCR) in laboratory with different Sn contents was analyzed by electron back-scattered diffraction(EBSD).The results show that the hot rolled slabs with different Sn contents have the same texture,i.e.,Goss,Copper and Brass.Specifically,the texture of core layer is {100};While the hot rolled slab with 0.10% Sn,the surface layer and subsurface layer have a sharpness Goss texture and the finished products h...
轧制裂纹及热处理工艺对高硅电工钢复合板磁性能的影响
对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后,采用正火、退火两种热处理方式处理,并观察轧制过程中产生的裂纹,研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理,研究复合板中裂纹变化及其对磁性能的影响。结果表明:不同热处理工艺下合金内部的裂纹尺寸差异明显,裂纹尺寸对复合板的磁性能影响显著,相对于深裂纹,其他因素的影响较小;温轧变形加工后,复合板内层出现有序组织,但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能;扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹,但不能消除尺寸较大的裂纹,故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff...
硼酸对无铬无取向硅钢涂层性能的影响
研究了硼酸对以Al(H2PO4)3为基料的无铬无取向硅钢绝缘涂层各项性能的影响。用盐雾实验、动电位极化及交流阻抗等试验手段研究了不同硼酸含量对硅钢绝缘涂层的耐蚀性和电化学行为的影响,同时采用SEM对涂层的表面形貌进行了研究。结果表明,硼酸含量为9.7%时,涂层的耐盐雾性及电化学性能最好;硼酸含量过少或过多时,涂层的耐蚀性和电化学性能都较差。 Influence of boric acid on the performance of chromium-free non-oriented silicon steel insulating coating based on aluminum dihydrogen phosphate was investigated.Salt spray experiment,potentiodynamic polarization and electrochemical impedance spectroscopy were used to study the influence of boric acid content on the corrosion resistance and electrochemical behavior of the insulation coating of silicon steel.Surface morphologies of the coatings were tested by SEM.Result shows that when the boric ...
双辊连铸无取向硅钢铸带特征及常化作用研究
双辊连铸技术是冶金及材料领域内的一项前沿技术,对于生产高品质硅钢具有独特优势.本实验研究了一种双辊铸轧w[Si]=4.5%的无取向硅钢,考察其铸态和常化处理后样品的组织、织构及析出相尺寸特征.结果表明:铸带组织以与铸带法向成5~20(°)倾角的柱状晶为主,晶内存在少量0.3~0.4μm的AlN析出相,铸带织构以λ(<001>//ND)织构为主,表层织构漫散.950℃/10 min常化处理后,析出相尺寸增大,表层λ织构增强. As an advanced technique of metallurgy and material science,twin- roll strip casting has unique advantages for producing high quality silicon steel. The present study was aimed at a 4. 5% Si non- oriented electrical steel for analyzing the structure,texture and the size of precipitates at the initial and normalized state. The results revealed that the initial structure mainly consisted of columnar grains with 5 ~ 20( °) angle to the normal of cast strip,and some AlN precipitates of 0. 3 ~ 0. 4 μ...
两段式正火对含Sb冷轧无取向电工钢磁性能的影响
利用OM、EBSD等手段研究了热轧板两段式正火时在700℃保温不同时间(0、10、30、60 min)对含Sb冷轧无取向电工钢磁性能的影响。结果表明,700℃保温10 min处理的样品铁损最小,磁感最高。对成品板的组织分析结果表明,试样的晶粒尺寸随700℃保温时间的延长先增大后减小,保温10 min时晶粒尺寸达到最大;分析成品试样织构发现,有利织构组分随700℃保温时间的延长先增加后减少,保温10 min时有利织构组分所占百分比最高。因此,含Sb冷轧无取向电工钢两段式正火时在700℃保温10 min时磁性能最好。 Effect of two-stage normalization on magnetic property of non-oriented electrical steel containing antimony was investigated by using optical microscope(OM) and electron back-scattered diffraction technology(EBSD).The experimental results show that the iron loss and magnetic permeability of the specimen insulated at 700 ℃ for 10 min are lowest and highest respectively.The grain size of the finish specimens increases first and then decreases with the increase of holding time.Similarly,the advanta...
50W600无取向硅钢在轧制与退火工序间的织构演变
运用电子背散射衍射(EBSD)技术,研究了50W600无取向硅钢在热轧→冷轧→退火工序间织构的演变。结果表明:由于热轧板沿板厚方向的应力场和温度场存在差异,导致热轧板不同层织构类型和强度存在差异;热轧板表层主要存在铜型、黄铜和高斯织构,1/4层织构主要为α纤维织构和较弱的高斯织构,中心层织构较单一,主要为α纤维织构;和热轧板相比,冷轧板各层织构差异较小,为典型的轧制织构(α纤维织构和γ纤维织构);退火板各层都表现为γ纤维织构增强、α纤维织构减弱,旋转立方织构基本消失。 The texture evolution of 50W600non-oriented silicon steel in hot rolling,cold rolling and annealing process was investigated by electron back-scatter diffraction(EBSD)technology.Results show that the hot rolled plate texture types and intensities along thickness direction were different because of the different stress fields and temperature fields.The major texture types in the surface of hot rolled plate were copper,brass and Gauss texture.The texture was composed ofαfibre texture and weaker Ga...
B元素对高牌号无取向硅钢热轧板组织和性能的影响
借助实验室设备研究了B元素对高牌号无取向硅钢热轧板组织和磁性能的影响。结果表明,与无硼钢相比,含硼钢的热轧板晶粒尺寸略小,析出物的类型和尺寸没有区别,主要是AlN和(AlN+MnS)复合析出物,少量的MnS析出物,尺寸集中在1.0~2.5μm范围内。未发现BN析出物。在力学性能方面,B对钢的软化作用不明显。在磁性能方面,含硼钢的铁损为3.215W/kg,磁感为1.710T,综合磁性能比无硼钢差。 Influences of boron on microstructure and properties of hot rolled band in high-grade non-oriented silicon steel are researched in this paper by experimental equipments.Compared with boron-free steel,the result shows that boron-bearing steel has smaller grain size,but the type and size of precipitations have no differences.The main precipitates are AlN,(MnS + AlN) composite precipitate and few MnS,the range of which are between 1.0 μm and 2.5 μm.BN precipitation is not found.With reward to mecha...
高强度无取向电工钢的研究进展
针对宝钢集团、日本新日铁住金和JFE公司公开的相关专利等资料,总结了国内外高强度无取向电工钢的研究进展,分析了不同电工钢的化学成分、生产工艺及产品性能,指出固溶强化、细晶强化、析出强化、位错强化都有可能被用来提高无取向电工钢的强度,并阐述了四种强化方式的优缺点;指出在高强度无取向电工钢的研发过程中,需根据其具体用途确定目标性能,再采用合适的强化手段,最终实现力学性能、磁性能和生产性能之间的平衡。 The research progress of high strength non-oriented electrical steels at home and abroad is summarized according to related patents brought into the public by Baosteel,Nippon Steel & Sumitomo Metal corporation and JFE corporation.The characteristics of chemical composition,production technology and properties of products in the patents are analyzed.Each of solution strengthening method,fine-grain strengthening method, precipitation strengthening method or dislocations strengthening method ma...
Cr对含Nb高强无取向硅钢组织、织构及性能的影响
高强无取向硅钢主要应用于高速电机,要求其具备高强度和优异磁性能,但目前无取向硅钢的磁性能和强度难以兼顾。因此,设计并制备了添加微量Cr的含Nb高强无取向硅钢,通过光学显微镜、EBSD、万能拉伸试验机、四探针测试仪和磁性能测量仪等研究了Cr对含Nb高强无取向硅钢微观组织、织构、力学性能及磁性能的影响。结果表明,添加质量分数为0.5%的Cr抑制了热轧组织的回复,使常化和退火组织再结晶减弱,常化和退火后有利织构面积分数增加,不利织构面积分数减小。添加质量分数为0.5%的Cr使含Nb无取向硅钢的屈服强度显著增大,磁感略升高,但对铁损几乎没有影响。Cr对屈服强度的影响一方面是由于Cr的固溶强化作用,另一方面Cr促进了Nb的析出而使Nb的析出强化效果增强;而Cr提高含Nb高强无取向硅钢的磁感主要是由于促进有利织构形成的同时抑制了不利织构的形成,使得织构因子增大;添加Cr使无取向硅钢的电阻率增加从而使铁损降低,同时Cr促进了Nb的析出,而这种富Nb析出相不仅抑制晶粒长大且会阻碍磁畴移动而使铁损增高,在两方面因素的综合作用下,添加质量分数为0.5%的Cr对含Nb高强无取向硅钢的铁损几乎没有影响。因此,... High strength non-oriented silicon steel is mainly used in high-speed motors, which requires good mechanical and magnetic properties. However, it is difficult for non-oriented silicon steel to obtain high strength and good magnetic properties at the same time. In this paper, the Cr-microalloyed Nb-containing high strength non-oriented silicon steel was designed and prepared. The effect of Cr on the microstructure, texture, mechanical properties and magnetic properties of Nb-containing high stren...
6.5%Si高硅钢铸锭凝固组织的CAFE法模拟研究
应用CAFE法对6.5%Si高硅钢铸锭凝固组织进行了模拟研究,确定出了适合高硅钢组织模拟的模型。进一步用该模型研究了过热度及冷却条件对凝固组织的影响,结果表明,随着过热度的降低,凝固组织中柱状晶比例和晶粒平均面积均减小。水冷条件下,高硅钢铸锭凝固组织几乎全是柱状晶,而且晶粒粗大。空冷条件下,等轴晶区扩大,但柱状晶仍占主要部分。缓冷条件下,等轴晶区占主要部分,晶粒平均面积和空冷条件下相当。 The solidification structure of 6. 5% Si steel ingot was simulated based on CAFE method and the model suitable for simulating the structure of high silicon steel wad ascertained. The influence of superheat and cooling condition on the solidification structure were studied. It was shown that with the superheat decreasing,the proportion of columnar crystals decrease,and the average grain size become smaller. Under water cooling condition,the solidification structure of casting was composed of almo...

