硅钢资料

取向硅钢常化工序主要采用现场实测带钢温度的方式测定冷却速率，并通过稳定冷却水温、调整冷却水量及喷梁运行数量等方式保证合理的冷却速率，给常化工艺设计和生产带来诸多不便。通过对常化工艺水冷过程带钢的传热分析求解，在建立带钢水冷温度模型的基础上，研究了不同冷却工艺参数对带钢温度及冷却速率的影响规律以及冷却工艺的交互作用结果。结果表明：模型计算结果能够较好地反映取向硅钢在常化水冷过程中的温度及冷却速率的变化，其计算误差为0.80%～4.11%;在特定取向硅钢厚度规格和常化工艺下，随着常化冷却水量及有效冷却长度的增加，带钢水冷温度及冷却速率与呈非线性变化；常化水冷工艺主要通过调控带钢与冷却水之间热交换量和交换时间实现对带钢温度的控制，实际生产中需综合考虑机组速度、冷却水量及有效冷却长度之间的交互作用，选定喷梁投入数量和冷却水量以获得稳定的冷却速率。 The cooling rate of normalization process mainly determined by measuring the grain oriented silicon steel strip temperature on site, and ensures the cooling rate by stabilizing the cooling water temperature, adjusting the cooling water volume and the operation quantity of spray beam, which brings inconvenience to the normalization process design and production. Based on the heat transfer of strip in the water cooling section of normalization process, the water cooling temperature model for the n... 

选用国内外无取向硅钢标杆企业A、B、C的产品,采用非水溶液电解提取+SEM(EDS)方法,分析了其典型牌号对应成品试样中的夹杂物。结果表明,从磁性能控制角度而言,受钢的化学成分及生产工艺影响,A、B、C企业成品试样的夹杂物尺寸、种类、数量存在差异,这些差异对其磁性能产生显著影响;从夹杂物控制角度而言,A、B、C企业对应成品试样的夹杂物,以MnS、CuxS复合或者AlN、MnS、CuxS复合为主,其中1.0μm以下的夹杂物数量分别为2.34×107个/mm3、2.98×107个/mm3和11.98×107个/mm3,1.0μm以上夹杂物数量均很少,夹杂物的平均尺寸从大到小依次为A企业、B企业、C企业。 According to the production of three benchmarking manufacture enterprises A,B and C of non-oriented silicon steel at home and abroad,the inclusions in finished steel samples with typical grades were investigated by electrolytic extraction from non-aqueous solution and SEM(EDS).Results show that,from the viewpoint of improving the magnetic properties,affected by chemical composition and production technique,the size,type and amount of inclusions in finished steel samples are various,which will af... 

研究了应用电感耦合等离子体质谱法(ICP-MS)测定硅钢中痕量铜和镍的分析方法。采用硝酸分解样品,通过内标校正和基体匹配消除了基体干扰的影响,同时根据测量时存在的质谱干扰情况,选择同位素65Cu和60Ni作为测定元素和通过调节仪器参数使双电荷离子的产率最低,以减少带来的干扰。该方法用于硅钢中痕量铜和镍的测定,所得的结果与ICP-AES法测定结果完全吻合,各元素测定结果的RSD值小于5%,加标回收率为97.3%～100.3%。 A method for the determination trace copper and nickel in silicon steel by inductively coupled plasma mass spectrometry(ICP-MS) was studied.The samples were dissolved in HNO3.The effect of matrix interference was eliminated by internal standard correction and matrix matching.Meanwhile,according to the mass spectral interferences in determination,the isotopes including 65Cu and 60Ni were used as measuring elements.The yield of double-charge ions were minimized by adjusting instrumental parameters... 

利用X-射线衍射织构分析和线形分析技术测定了交叉轧制双取向硅钢在制备工艺各阶段的织构及微结构,进而探讨了立方织构({100}<001>)的形成过程。通过对实验结果的分析可知,二次冷轧和交叉轧制工艺为立方织构提供了内能优势和有利的形变织构,而低温预退火工艺既强化了立方织构的内能优势,又为立方织构的异常长大提供了有利的组织保证,最终在抑制剂(AlN和MnS)的协同作用下,硅钢在二次再结晶退火后形成了强烈的立方织构。 The texture and substructure of the double oriented electrical steels produced by the cross rolling technology during the difference process has been measured by means of the X-ray texture and diffraction peak profile analysis technology,and research the formation mechanism of cube texture,{100}<001>.The results show that the dominances of inner energy and deformation texture were supplied by secondary cold rolling and the cross rolling technology and strengthened by pre-annealing at a low... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

以CaO-CaF2复合渣系为脱硫剂,在RH精炼过程采用真空投入法进行高牌号无取向电工钢深脱硫工业试验,采用KTH模型计算分析了RH炉渣成分对硫容量CS的影响。研究结果表明,炉渣成分控制在w((CaO))/w((SiO2))为5~7,w((CaO))/w((Al2O3))为1.5~1.8,w((Al2O3))为25%~30%,w((FeO+MnO))<5%,脱硫剂加入量为6~8kg/t时,钢中硫质量分数从平均0.003 1%降低到0.001 8%,最高脱硫率达到47.1%,平均脱硫率为41.7%。 The industrial trials on deep desulphurization of high grade non-oriented electrical steel were finished through using CaO-CaF2complex based fluxes in RH process.Using the KTH model,the effect of refining slag composition on the sulfide capacities was analyzed.The results show that the chemical composition of refining slag(mass fraction,%)is w((CaO/SiO2))between 5to 7,w((CaO))/w((Al2O3))beween 1.5to 1.8,w((Al2O3)) between 25%to 30%,w((FeO+MnO))less than 5%,and the desulphurizer addition level of... 

Fe-6.5%Si高硅钢是一种具有高磁导率、低矫顽力和低铁损等优异软磁性能的合金,但是其室温脆性和低的热加工性能严重影响了其在工业领域的应用。综述了Fe-6.5%Si高硅钢的性能,评述了合金的改性法、特殊轧制法、快速凝固法、沉积扩散法、粉末冶金法等制备工艺。 It is well known that 6.5%Si high silicon steel is one kind of soft magnetic materials with higher re-lative permeability,lower coercive force and iron loss than those of conventional industrial silicon steel.However,their room-temperature embrittleness and poor workability limit their practical applications in the industry.The pre-paration technique such as modification treatment on alloy,special rolling,rapid solidification,CVD and powder me-tallurgy is reviewed. 

【机构】 商务部进出口公平贸易局； ...

提出一种基于粒子群优化算法实现的硅钢涂层厚度近红外光谱检测新方法。首先,采用近红外光谱仪采集获得了硅钢表面绝缘涂层的近红外光谱,然后,采用离散粒子群算法筛选出近红外光谱数据的最佳波长变量并组成新的光谱数据,最后,建立涂层厚度的核偏最小二乘定量分析模型。实验显示,所建定量分析模型对检验样本分析的绝对误差范围为-0.12～0.19μm,最大相对误差为14.31%,完全符合现场检验需要。研究表明,离散粒子群算法可以有效地筛选出携带更多有用信息的波长变量,提高定量分析模型的分析准确度和速度,是一种有效的近红外光谱波长筛选方法,同时,近红外光谱法也是一种有效的硅钢绝缘涂层厚度检测方法。 A novel thickness measurement NIR spectrometry for surface insulation coating of silicon steel based on discrete binary particle swarm optimization(DBPSO) algorithm is presented.First,we used NIR spectrometer to collect the NIR spectra of insulation coating of silicon steel,and then,DBPSO algorithm was used to select the optimal wavelength variates and composed a new spectra set.Last,the authors created the thickness quantitative analysis model using kernel partial least square algorithm.The exp... 

取向硅钢因其高磁导率、低矫顽力和大电阻系数等特性，被广泛应用于大中型变压器和大型电动机铁芯的制造。因取向硅钢性能和成分控制严格，生产工艺复杂，故其产品代表了钢铁企业特殊钢生产的最高水平。本文介绍了新钢公司卷板厂1580热连轧线生产取向硅钢过程中出现的窄尺问题，研究了取向硅钢产品的特点，分析了热轧过程中的组织转变，并结合生产实际提出了改进措施。通过对加热炉钢坯加热模式、粗轧轧制策略、精轧轧制工艺、二级模型等方面的优化和改进，取向硅钢窄尺情况明显好转，提高了产品的成材率和市场口碑。 The oriented silicon steel is widely used in the iron core manufacture of large and mediumsized transformers and large motors because of its high permeability, low coercivity and large resistance coefficient. Due to the performance and composition control of oriented silicon steel is strict, the production process is complex,therefore, its products represent the highest level of special steel production in iron and steel enterprises. This paper introduces the problem of narrow gauge in the produ... 

采用硅钢自动测量装置及X射线衍射仪检测出样品在实验前后的磁性能参数和织构强度.结果表明:较低的电压、9 Hz、较长的处理时间以及退火温度为650℃有利于增高铁损降低比例;较低的电压、较高的频率以及退火温度为650℃有利于增加磁感应强度增高比例.最佳的提高磁性能的实验参数是:频率为9 Hz,电压为500 V,处理时间为6 min,退火温度为650℃.通过织构分析可以验证:取向硅钢磁感应强度的变化取决于{110}<001>晶粒取向度值,而{110}<001>取向度值可看成是一个反映总体平均偏离角大小情况的综合值. An automatic measurement system for silicon steel and an X-ray diffraction meter were used for measuring the magnetic property parameters and texture of ex-processed samples and processed samples.It is shown that under the condition of a lower voltage,9Hz,a longer processed time and an annealing temperature of 650℃,the decrease rate of iron loss can be increased;a lower voltage,a higher frequency and an annealing temperature of 650℃ are in favor of improving the increase rate of magnetic inducti... 

本文中简要介绍了武汉钢铁有限公司采用薄板坯连铸连轧CSP(compact strip production, CSP)工艺生产中低牌号无取向硅钢的实践情况.CSP工艺生产的硅钢具有成品磁性均匀、板形好的优势，但是在利用该技术生产中低牌号无取向硅钢时，常存在成品板表面瓦楞状缺陷严重、连铸生产效率低等问题.通过优化炼钢成分、热轧等相关工艺，可消除热轧板厚度方向中心的粗大形变组织，从源头上避免了粗大{100}<011>纤维组织的出现，消除了瓦楞状缺陷；通过提升冶炼效率和控制钢中夹杂物总量，可优化隧道炉的加热温度与在炉时间，大幅度提升了连铸生产效率，实现了中低牌号无取向硅钢的批量稳定制造，使CSP产线成为中低牌号无取向硅钢热轧板原料的主要供给生产线.如何进一步提升钢水纯洁度、提高连铸生产效率、降低生产成本，以及挖掘该产线生产薄带钢的技术优点，是未来工作的重点. This paper briefly introduces the practice of producing medium and low grade non oriented silicon steel(NGO) with CSP(compact strip production, CSP)technology in Wuhan Iron and Steel Co., Ltd.. This technology has the inherent advantages of uniform magnetic properties and good shape for silicon steel finished strip. However, in the actual production process, there are serious corrugated defects on the surface of silicon steel finished strip, and production efficiency of continuous casting is low...