硅钢资料

利用电子探针面分析、状态分析及电子背散射衍射相分析技术研究硅钢高温氧化铁皮的显微结构。电子探针面分析可以直观的看出元素的分布状态,初步判断氧化铁皮的结构,而状态分析可以准确表征常规氧化铁皮中铁元素的状态,对于合金元素富集区域则通过电子背散射衍射相分析技术来标定。结果表明,高温氧化铁皮的结构主要有4层,即最外层为厚度约为10μm的Fe2O3相,次外层为Fe3O4相,中间层为FeO相上分布有颗粒状的Fe3O4相,最内层为FeO相和Si元素富集的Fe2SiO4相。其中Fe2SiO4层的分布特征与加热温度密切相关:1 100℃时,Fe2SiO4相呈颗粒状,弥散分布在FeO层;1 200℃时,Fe2SiO4相呈液态,侵入基体和疏松的FeO层,且沿着FeO晶界呈网状分布。 The microstructure of high temperature oxide scale on silicon steel was characterized by electron probe microanalyzer(EPMA)mapping analysis,state analysis and electron backscatter diffraction(EBSD)phase analysis.The element distribution and the initial structure of the oxide scale could be detected by EPMA mapping analysis apparently.And the state of iron in the conventional oxide scales could be determined by state analysis.Meanwhile,the alloy-rich region could be identified by EBSD phase analy... 

本发明涉及电工钢的生产方法，更具体地说，涉及一种预应力生产中低牌号无取向电工钢的方法，包括铁水预处理；预处理后的铁水进行转炉冶炼并吹氩脱氧；吹氩后的钢水送入精炼炉中进行冶炼并加入低碳合金进行合金化；合金化处理的钢水通过薄板坯连铸机铸成板坯并采用薄板胚连铸连轧生产工艺进行轧制获得热轧板；所述热轧板经过酸洗冷轧，随后进行预应力拉伸并退火，采用涂层进行涂镀、烧结后卷取。本发明采用预应力拉伸，改善无取向电工钢退火前钢板内部应力的分布，制备的冷轧无取向电工钢产品的电磁性能P15/50≤5.4W/kg，磁感应强度≥1.72T，板形同板差≤8um。

利用EBSD技术研究了电工钢中长轴平行于轧向的柱状晶样品在热轧和退火过程中组织和取向的演变规律,并与长轴平行于板法向的样品的已有研究结果进行对比。结果表明,无论柱状晶按何种方向排列,只要表面存在剪切力,热轧后都可形成剪切织构,同时中心形成轧制织构,主要包括旋转立方织构和{112}<1-10>。柱状晶造成的影响主要体现在板中心层,长轴平行于轧向排列的样品热轧时形成的粗大旋转立方晶粒要到脱碳退火后才能完全消除,但破坏了正常的不同取向晶粒间的取向差分布及尺寸均匀性,导致二次再结晶不完全及磁性能降低。 The evolution of microstructure and grain orientation in an electrical steel containing columnar grains with its long axis being parallel to the rolling direction of sheet was studied during hot rolling and annealing by EBSD technique.The results are compared with those of samples containing columnar grains being parallel to normal direction of sheet reported in the reference [3].It was shown that,whether the long axis of columnar grains was arranged in RD or ND,shear textures can be formed in t... 

对3层高硅电工钢复合板铸坯进行热轧及温轧变形加工后，采用正火、退火两种热处理方式处理，并观察轧制过程中产生的裂纹，研究不同状态下复合板的磁性能。对不同状态下的试样进行扩散退火处理，研究复合板中裂纹变化及其对磁性能的影响。结果表明：不同热处理工艺下合金内部的裂纹尺寸差异明显，裂纹尺寸对复合板的磁性能影响显著，相对于深裂纹，其他因素的影响较小；温轧变形加工后，复合板内层出现有序组织，但该有序组织在合金存在深裂纹的前提下并不能从本质上提高合金的磁性能；扩散退火工艺可以消除复合板内部的浅裂纹及微裂纹，但不能消除尺寸较大的裂纹，故而不能显著提高存在深裂纹的复合板的磁性能。 After hot rolling and warm rolling deformation processing of casting billet for three-layer high silicon electrical steel composite plate, it was normalized and annealed for heat treatment. Then, the cracks produced during the rolling process were observed, and the magnetic properties of composite plate in different states were also investigated. Furthermore, the samples in different states were subjected to diffusion annealing treatment, and the changes of crack in composite plate and their eff... 

本发明提出了一种可修饰取向硅钢表面的无铬无机绝缘涂料及其制备方法，该涂料按照重量份计包括以下组份：磷‑硅溶胶40‑70份、钛改性增稠剂预溶胶25份、抑泡剂0.2‑1份、流平剂0.05‑0.2份和去离子水3.8‑34.75份。该涂料的制备方法为：先制备磷‑硅溶胶和钛改性增稠剂预溶胶；然后向磷‑硅溶胶中加入抑泡剂并搅拌均匀；再加入去离子水并搅拌均匀；再分次缓慢加入钛改性增稠剂预溶胶并搅拌均匀；最后加入流平剂并搅拌均匀。本发明所制备的无铬无机绝缘涂料可修饰取向硅钢表面瑕疵露晶等形貌缺陷；在取向硅钢表面形成的绝缘涂层具有良好的附着力和耐热性；涂料采用的原料均为无污染的环保材料，解决了含铬绝缘涂料带来的环境危害。

以取向电工钢成分为基础,制备了含C或Mn和S的4种实验钢。观察了接近平衡析出状态实验钢经60%冷轧后在600～1000℃范围再结晶退火过程中微观组织演变,统计分析了再结晶体积分数随退火时间的变化规律,进而计算了各实验钢静态再结晶的激活能。观察了高含C实验钢退火初期再结晶晶粒优先出现的部位。结果表明900～1000℃范围内各实验钢铁素体的化学成分相似,因而其再结晶激活能基本一致。在600～800℃范围内铁素体内会有阻碍再结晶进程的三次渗碳体析出,从而使再结晶激活能明显提高。高C含量实验钢中还会有从奥氏体转变而来的粗大珠光体或渗碳体,轧制过程中其附近形成的变形区会促进600～800℃加热时该区域附近率先发生再结晶形核、降低再结晶激活能。固溶的Mn、S元素可微弱提高再结晶激活能,但高Mn、S含量会改变粗渗碳体从奥氏体析出时的形态。 Four experimental steels based on grain oriented electrical steel containing C,or Mn and S were prepared.Microstructure evolution of the steels close to a state of equilibrium precipitation were observed during annealing processes at 600-1000 ℃after 60% cold rolling,the changes of recrystallization volume fraction were analyzed statistically as the annealing was prolonged,and the activation energy for static recrystallization of the steels were calculated.The locations,where the recrystallizatio... 

一种高磁感低铁损取向硅钢生产用表面涂层涂覆装置，包括：加工台，加工台上端固定连接支撑架，支撑架下端一侧固定连接伺服电机，伺服电机输出端固定连接第一齿轮，第一齿轮下端啮合连接第二齿轮，第二齿轮中部固定连接螺纹杆，螺纹杆上螺纹连接移动环，螺纹杆远离第二齿轮一侧转动连接支撑板，支撑板上端固定连接支撑架，移动环下端固定连接伸缩杆，支撑架下端前后部均固定连接连接框，本实用新型的有益效果是：通过设置的伺服电机、第一齿轮、第二齿轮、螺纹杆和移动环等结构，能够实现伸缩板带动硅钢板移动，从而能够完成自动化推料，减少工人劳力支出的同时，也能够避免工作人员手臂靠近涂层辊，从而避免安全事故的发生。

针对宝钢硅钢常化退火过程中产生的退火炉辊印缺陷问题,通过实际生产的大数据与产品质量问题相结合,将数据挖掘、数据分析方法应用到实际,一定程度上解决了现场实际生产中的痛点,为现场生产提供决策支撑,避免了以前通过人工识别判定存在疏漏和无法定量判断的问题,形成了一套具有鲁棒性和可操作性的钢铁生产过程数据分析方法。通过智慧决策系统平台获取实际生产和表检仪数据,基于Pearson相关系数算法进行变量挑选和特征工程,并应用随机森林算法对数据建立分类预测模型,实现了质量问题的溯源和监控,通过数据量化预测了炉辊印缺陷是否可通过轧制消除的质量问题,识别准确率达到96.43%。 In views of the normalizing annealing furnace roll marks problem occurred in the process of normalizing annealing of silicon steel in Baosteel,by combining big data from actual production with product quality problems,data mining and data analysis methods were applied to actual production to solve the pain points and provide decision support,a robust and practical data analysis method for the steel production process has been developed,which avoided the previous problems of omission and non-quan... 

研究了退火温度对3.1%Si无取向硅钢组织和磁性能的影响规律。结果表明:退火温度从940℃提高至1 000℃,平均晶粒尺寸由98μm增加到145μm,铁损P_1.5/50从2.576 W/kg降低至2.408W/kg。随着退火温度的升高,γ不利织构组分强度逐渐降低,{111}〈112〉织构组分强度降低约16%,磁感B₅₀逐渐升高,磁性能水平提高。 The effects of annealing temperature on microstructure and texture and magnetic properties of 3.1%Si non-oriented silicon steel were investigated in this paper.The results showed that,when the annealing temperature increased from 940℃ to 1 000℃,the average grain size of metallographic structure increased from 98μm to 145μm,the iron loss value P_1.5/50 decreased from2.576 W/kg to 2.408 W/kg.And as the annealing temperature increased,the strength of the unfavorable texture componentγgrad... 

研究稀土Ce的添加对含Sn高磁感无取向电工钢磁性能及夹杂物的影响。对比分析了两种成分钢的磁性能以及各过程工艺条件下夹杂物种类和分布情况。结果表明,在含Sn高磁感无取向电工钢中加入稀土元素Ce可以粗化夹杂物,提高成品晶粒的均匀性,有效降低铁损;同时Ce的添加不影响Sn元素提高磁感的效果,磁感保持不变。 Effect of Ce on magnetic properties and inclusion of Sn-bearing high permeability non-oriented electrical steel was investigated. A comparative analysis of the magnetic properties and the types and distributions of inclusion in the two sheets with different composition shows that the addition of Ce to the Sn-bearing high permeability non-oriented electrical steel can coarse the inclusion,improve the homogeneity of the finished grain and effectively decrease the core loss. Also,the addition of Ce... 

公开了一种取向硅钢酸洗圆盘剪的剪切方法，方法中，取向硅钢的钢带经酸洗槽酸洗、漂洗、烘干之后，清除表面的氧化铁皮后进入圆盘剪，根据所述钢带的宽度调整圆盘剪的机架之间的距离，根据钢带厚度h调节圆盘剪的上刀片和下刀片间隙△，以及上刀片和下刀片的边缘重叠量C，使得间隙△为h/0.9，重叠量C为1.05‑0.2*h，钢带通过上刀片和下刀片时，上刀片和下刀片施加剪切力于钢带上构成切断面，切断面占带钢厚度的1/5～1/3，随着咬合深度的增加，切断面的变形量也随之增加，直到切断面从钢带断裂形成撕断面。

采用光学显微镜和X射线衍射仪研究了常化退火处理对无取向硅钢热轧板和成品退火板显微组织和织构的影响。结果表明:常化退火处理消除了热轧板中的变形组织,促使变形晶粒完成再结晶;常化退火处理使高斯织构和立方织构易通过再结晶在变形带内形核和长大,可显著降低成品退火板的{111}和{112}不利织构组分的占有率,提高{100}和{110}有利织构组分的占有率,从而有利于提高无取向硅钢成品板的磁性能。 The effect of normalizing annealing treatment on microstructure and texture of non-oriented silicon steel hot rolled plates and final products were investigated by means of optical microscope and X-ray diffractometer analysis.The results show that the deformed microstructure of the hot rolled plates transformed into recrystallized grain after normalizing annealing treatment.The grains of Goss texture and cubic texture crystallographic orientation were formed and grown by recrystallization in the...