论文

针对采用含钒铁水生产无取向电工钢存在的铁水脱硫率低、转炉冶炼过程回硫量大、成品硫含量偏高的问题,通过对含钒钛铁水脱硫,减少转炉冶炼过程回硫以及RH脱硫技术等方面的研究,大幅度降低了电工钢成品硫含量。生产表明钢中w(S)=0.001 9%～0.006 9%,平均为0.004 2%;w(S)≤0.008%的比例达到了100%,且w(S)≤0.005%的比例也达到了91.43%。 In cognizance of the problems of low desulphurization rate for hot metal,large sulfur-recovery in converter as well as high sulfur content in products in producing non-orientation electrical steel with vanadium-content hot metal countermeasures have been carried out.Sulfur content in non-orientation electrical steel is decreased obviously by way of study on technologies of desulphurization for hot metal with vanadium & titanium,sulfur-recovery control in converter and desulphurization in RH ... 

对碳-锰-硅钢进行不同配分温度的Q&P(Quenching and Partitioning)处理,测试了热处理后不同钢的力学性能和残余奥氏体含量,并用扫描电子显微镜和透射电镜观察其显微组织,分析了配分温度对显微组织和力学性能的影响。结果表明:试验钢显微组织基本由低碳板条状马氏体、块状铁素体和条状残余奥氏体组成;随配分温度的升高,试验钢的抗拉强度呈下降趋势,伸长率与奥氏体含量的变化趋势相同,但变化规律不确定;提高锰含量能稳定残余奥氏体,从而提高试验钢的伸长率,并使伸长率对配分温度不敏感。 The C-Mn-Si steel was quenched and partitioned at different partitioning temperatures,the mechanical properties and residual austenite contents were investigated,the microstructure was observed by SEM and TEM,and the effect of partitioning temperature on microstructure and mechanical properties was analyzed.The results show that the microstructure of the tested steel consisted of lath martensite with low carbon,nubby ferrite and banded residual austenite.The tensile strength of the tested steel ... 

介绍了攀钢冶炼电工钢过程硫含量变化以及过程回硫、增硫情况,采取针对性措施,如:提高铁水装入量、转炉采用石英砂代替复合造渣剂造渣、RH脱硫等,降低钢中硫含量。结果表明:采取相应措施后,电工钢炼成率大幅提高,成品w[S]≤0.008%的比例由改进前的62%提高到92.4%,取得了明显的冶金效果。 The resulfurization and the change of sulphur content in production of electrical steel is analyzed.The targeted measures have been taken,such as increase the loaded quantity of liquid iron,quartz sand replaces the composite slagging agent in the converter and RH desulfurization to decrease the sulphur content of the steel.The result shows,after the measures have been taken,the finished product ratio of electrical steel increase a lot.The ratio of sulfur content of finished product no more than ... 

提出一种基于粒子群优化算法实现的硅钢涂层厚度近红外光谱检测新方法。首先,采用近红外光谱仪采集获得了硅钢表面绝缘涂层的近红外光谱,然后,采用离散粒子群算法筛选出近红外光谱数据的最佳波长变量并组成新的光谱数据,最后,建立涂层厚度的核偏最小二乘定量分析模型。实验显示,所建定量分析模型对检验样本分析的绝对误差范围为-0.12～0.19μm,最大相对误差为14.31%,完全符合现场检验需要。研究表明,离散粒子群算法可以有效地筛选出携带更多有用信息的波长变量,提高定量分析模型的分析准确度和速度,是一种有效的近红外光谱波长筛选方法,同时,近红外光谱法也是一种有效的硅钢绝缘涂层厚度检测方法。 A novel thickness measurement NIR spectrometry for surface insulation coating of silicon steel based on discrete binary particle swarm optimization(DBPSO) algorithm is presented.First,we used NIR spectrometer to collect the NIR spectra of insulation coating of silicon steel,and then,DBPSO algorithm was used to select the optimal wavelength variates and composed a new spectra set.Last,the authors created the thickness quantitative analysis model using kernel partial least square algorithm.The exp... 

【作者】 姚昌国； ...

简述了无取向硅钢环保涂层发展背景,分析了硅钢环保涂层的特点及国内、外研究进展,提出了硅钢保涂层下一步的发展方向。 The back ground of environmental protection coating of non-oriented silicon steel was described in this paper.The characteristics and study progress in domestic and foreign of environmental protection coating of non-oriented silicon steel were analysised.The next development direction of environmental protection coating of non-oriented silicon steel was put forward. 

选用Q235和Q345钢,在纯锌浴和含钛量分别为0.05%、0.10%、0.15%、0.20%(质量分数)的合金浴中浸镀0.5、1、3、5、8 min。利用扫描电子显微镜和能谱仪研究了钛对热浸镀锌组织和生长动力学的影响,并提出钛对含硅钢铁锌反应抑制作用的机理。结果表明:钛的加入缩短了Γ的孕育期,促进了合金层中δ的生长和ζ的消失,δ的生长依然受扩散控制,呈抛物线生长规律;Zn-0.05%Ti锌浴可以很好的抑制高硅钢的硅反应性;含硅钢热浸镀锌钛合金浴时,在锌浴中会形成锌铁钛三元T相,该相能吸收ζ晶界处富集的硅,从而抑制了铁锌反应。 Both Q235 and Q345 steels were immersed for 0.5 to 8 min in Zn bath with different amount of Ti,ranging from 0 to 0.20 mass%,for galvanization.The effect of Ti in Zn bath on microstructure and growth kinetics of hot-dip galvanizing coatings on the two steels were investigated by means of SEM and EDS analysis.Base on the experiment,the mechanism of Ti additions in controlling Fe-Zn reaction was proposed.The results show that addition of Ti in the zinc bath decreases the incubation time of Γ phase... 

主要对硅钢退火炉耐材施工进行阐述,对一期工程与二期工程施工经验进行总结,包括设计、施工、耐材生产、人员素质等方面,指出了工程项目所所存在的不足,为同类型炉窑的施工提供借鉴。 This paper describes the construction of silicon steel annealing furnace refractories;and it was summarized the construction experience of phase-Ⅰ and phase-Ⅱ projects,including design,construction,refractory production,the quality of personnel etc,and pointed out the shortcomings of the project,which provided a reference for the construction of the same type of furnaces. 

研究了常化温度、常化时间及常化后冷却速度对Si的质量分数为1.6%的无取向电工钢成品磁性能的影响。结果表明:在850~1 050℃范围内,随着常化温度的升高,成品铁损先减小后增大,成品磁感应强度先增大后减小;当常化温度为1 000℃时,成品平均铁损最低,平均磁感应强度最高;常化时间从3min延长到7min时,成品铁损先减小后增大,成品磁感应强度则呈单调下降趋势;随着常化冷却速度的降低,成品铁损先减小后增大,成品磁感应强度则呈单调增大趋势;对于Si的质量分数为1.6%的无取向电工钢,最佳的常化制度为:在1 000℃进行常化,时间5min,常化后空冷。对热轧板进行常化后,热轧板发生了不同程度的再结晶和晶粒长大。提高常化温度、延长常化时间、降低冷却速度,都能使常化板晶粒粗化,进而粗化成品板晶粒,改善磁性能。通过扫描电镜观察发现,成品板中析出物主要为AlN和MnS的复合析出物,以及少量的单独析出的AlN和MnS,而常化工艺主要是通过粗化析出相,减少细小析出相数量,从而减少对晶界钉扎作用来改善成品磁性能。 The effects of normalizing temperature,normalizing time and cooling rate after normalizing on magnetic properties of non-oriented electrical steel with mass fraction of Si of 1.6% were investigated.The results show that core loss of product decreases first and then increases,while magnetic induction increases first and then decreases with the increase of normalizing temperature from 850 to 1 050℃.Average core loss of product is the lowest and average magnetic induction is the highest when normal... 

【作者】 欧阳帆； 肖侃； ...

借助高温激光共聚焦显微镜,在线观察了不同Mn含量的无取向硅钢中夹杂物的尺寸、类型、数量变化。结果表明,Mn含量(质量分数)为0.77%、0.32%时,试样中的夹杂物数量分别约为1000万个/mm3、1600万个/mm3。Mn含量较高的钢种,会优先析出球形、椭球形MnS夹杂物,其析出数量较少,尺寸相对较大,可以有效抑制AlN、CuxS夹杂物析出;Mn含量较低的钢种,会在试样再加热后冷却过程中,先析出相当数量MnS夹杂物,并作为AlN夹杂物析出核心,形成MnS+AlN复合夹杂物。这种复合夹杂物数量较多,尺寸也较大。 Based on the high temperature confocal microscope, the chage of size, type, and quantity of inclusions in non-oriented silicon steels with different Mn content were observed by in-situ SEM. Results show that the inclusion quantities are 10 million per mm3 and 16 million per mm3,while the mass fractions of Mn are 0.77% and 0.32%, respectively. In the silicon steel with higher Mn content, the spherical and ellipsoidal MnS inclusion will precipitate first, which can retard the precipitation of AlN ... 

利用加热炉模拟、动态再结晶以及热模拟等试验方法以及扫描电镜、金相显微镜等分析观察手段对无取向硅钢边裂的成因进行了探讨。结果表明,长时间加热使得板坯边部晶粒异常长大,晶界氧化并脱碳,轧制过程中边部温度过低,动态再结晶过程变弱,使得板坯边部延伸性能变差,是导致硅钢边裂的主要原因。建议通过适当降低铸坯加热温度、缩短保温时间、提高终轧温度来改善硅钢边裂缺陷。 The behaviors of high temperature oxidation,dynamic recrystallization,and hot ductility,microstructure evolution were investigated on the non-oriented electrical steel sheets to discuss the formation of edge crack.The key causes of cracking was found to be the coarse as-cast microstructure,grain boundary oxidation and decarburization in reheating furnace,as well as reduced temperature at strip edge region during hot rolling process resulting in reduced hot ductility and lack of enough dynamic re...