论文

利用场发射电镜及能谱仪研究了取向电工钢薄、厚板坯铸锭中不同区域的析出相差异,确定了MnS、AlN及Fe3C的析出顺序和形貌特征。结果表明AlN以先析出的MnS为形核核心,形成粗大微米级的复合析出相。针状Fe3C既可以在复合析出相表面形成也可以在基体中单独出现,主要受冷却速度的影响。在1250℃保温1～2 h,AlN、Fe3C均可完全回溶,但部分MnS仍不回溶。MnS尺寸随着保温时间延长而增大。导致热轧板中沿轧向分布的粗大MnS,减弱了粒子钉扎力。 Precipitates in thin and thick slabs of electrical silicon steel were investigated by means of field emission SEM and EDS analysis.The precipitation sequence and the morphology of MnS,AlN and Fe3C particles were identified.AlN particles are observed to be nucleated on surface of MnS forming micron-meter-sized complex particles.Acicular Fe3C can precipitate on surface of the complex MnS/AlN particles or directly from matrix depending on cooling rate of the slabs.After holding at 1250 ℃ for 1-2 h,... 

利用热模拟试验机、光学显微镜和X射线衍射仪对Fe-3.2%Si低温取向硅钢热轧工艺参数对组织及织构的影响进行了研究。结果表明,Fe-3.2%Si硅钢在1110℃粗轧、880℃终轧,轧后以10℃/s的速度冷却到550℃卷取,然后空冷到室温,热轧硅钢板沿板厚方向的显微组织不均匀性显著,对后续发展完善的二次再结晶有重要作用。无论是热轧板,常化板还是冷轧板,它们的织构集中分布在γ取向线上,γ取向线的织构除取向密度不同外,织构种类是一致的,这说明γ取向线上织构是有继承性的。从热轧到常化,织构取向密度显著减小,经二次冷轧后,织构密度又显著升高,可见,轧制变形有助于织构的形成并使织构强度升高。 The influence of hot-rolled process parameters on the microstructure and texture of Fe-3.2%Si low temperature hot rolled grain-oriented silicon steel were researched by hot simulation experiment machine,light microscope and X-ray diffractometer.The results show that,Fe-3.2%Si silicon steel is rolled by the technology with a temperature of rough rolling of1110℃,finish rolling of 880℃,coiling with the speed of 10℃ /s,and then cooled to room temperature with air.The microstructure of hot-rolled sil... 

介绍了双蓄热燃烧技术的特点和高温硅钢加热炉的特点,探讨了双蓄热燃烧技术在高温硅钢加热炉中使用的技术难点,分析了双蓄热燃烧技术在高温硅钢加热炉上使用的可能性。 Introduced characteristics of double regenerative combustion technology and high temperature silicon steel reheating furnace,discussed technical difficulties for using double regenerative combustion technology,analyzed the possibility of double regenerative combustion technology applied to high temperature silicon steel reheating furnace. 

无取向硅钢中夹杂物的存在会抑止晶粒生长,使基体的均匀连续性中断,其在钢中的形态、含量及分布情况都不同程度影响着硅钢的性能,尤其是对磁性能起关键的作用。因此,全尺度分布考察夹杂物对无取向硅钢夹杂物的研究极为重要。本实验确定了适用于不同牌号无取向硅钢夹杂物全尺度分布的分析方法:样品制备—小样电解—过滤喷金—根据不同牌号的要求选择合适的放大倍率扫描观测—夹杂物颗粒的分类统计。通过统计的结果,结合电解的失重量可以得到不同尺度的体积分布数据。实验分析了不同牌号和工艺无取向硅钢夹杂物的种类、形貌、大小和尺度分布,并初步考查了夹杂物与磁性能的关系,对无取向硅钢的工艺研究具有一定参考价值。 Inclusions in non-oriented silica steel could inhibit the growth of grain and cause discontinuity of micro-structure.The configuration,content and size distribution of inclusion have different effects on the performance of silica steel,especially significant on the magnetic property.Therefore,it is very useful to completely characterize inclusions with full size distribution in silica steel.In our research,full size analysis method for inclusion in silica steel had been established as follows: s... 

结合工业化生产的无取向硅钢,探讨了氧硫交互作用对钢中夹杂物生成的影响。借助非水溶液电解+扫描电镜法,研究了不同O、S含量下钢中夹杂物的变化规律。结果表明,本实验条件下,提高O含量、降低S含量,会劣化热轧组织再结晶效果。在劣化效果上,O的作用大于S;低Si、无Al硅钢中,应尽可能降低O含量、适当提高S含量,以粗化钢中微细夹杂物,减少尺寸小于1.0μm的夹杂物的数量;O、S含量与钢中夹杂物数量不具有关联性。生产过程中,不仅要严格控制O、S含量,还要严格控制生产工艺,以免生成较多的有害夹杂物。 Based on the industrial production of non-oriented silicon steel,the effects of interaction between oxygen and sulfur on the formation of inclusions were discussed.The change of non-metallic inclusions in steel sheets was investigated by means of electrolysis with non-aqueous solution under different oxygen and sulfur content.Results show that the recrystallization microstructure of hot rolled sheets will be deteriorated with the increase of oxygen content and the decrease of sulfur content.The ... 

以一种新的Fe-Si合金制备工艺为出发点,研究了不同放电等离子体快速烧结工艺(SPS)和Si含量变化对Fe-Si合金材料显微组织与磁性能的影响。结果表明,在烧结温度为1 000℃时制备的Fe-6.5%Si合金(质量分数,下同)的综合磁性能较好,其在50Hz下的铁损为0.549W/kg,最大磁感应强度为0.124 3T,矫顽力245.6 A/m,磁导率0.338mH/m。另外,材料的最大磁感应强度随Si含量的增加显著增长,1 000Hz下,Fe-10.0%Si的最大磁感应强度可达到Fe-6.5%Si合金的5倍左右。 The effects of Si content and SPS technology on microstructure and magnetic properties of Fe-Si alloy material were studied in the paper.It shows that the magnetic properties are the best when the content of Si is 6.5wt% and the sintering temperature is 1 000℃,the iron loss is 0.549W / kg in 50Hz,maximum magnetic induction is 0.124 3T,coercive force is 245.6A / m and permeability is 0.338mH / m。And,the maximum magnetic induction increases significantly with the increase of Si.The maximum magneti... 

通过对辉光放电发射光谱参数的优化,以铁元素为内标来消除基体效应,建立了测定硅钢薄板中微量硼元素的方法。优化的实验参数为:放电电压1200 V,放电电流50 mA,预溅射时间40 s,积分时间10 s。校准曲线硼元素含量范围0.0001%~0.022%,相关系数大于0.999,测量结果与认定值一致,相对标准偏差小于10%。完全能够满足日常分析测试的要求。 A glow discharge optical emission spectrometry(GD-OES) method for determining trace boron element in silicon steel sheets were established through optimization of instrumental parameters and using Fe element as an internal standard to eliminate the matrix effect.The optimized instrumental parameters included discharge voltage,discharge current,pre-sputtering time and integration time,which are 1200 V,50 mA,40 s,and 10 s,respectively.The content of boron element that can be determined from the ca... 

【摘要】 <正>为了确保电工钢的产品质量,在生产线...

研究了硅钢铸坯再加热过程中夹杂物的析出行为。采用非水溶液电解提取+扫描电镜观察方法,观察了试样的显微组织,统计了夹杂物的尺寸、种类、数量、分布。结果表明,均热温度为1 523 K时,水淬试样的夹杂物尺寸绝大部分小于0.5μm,0.5～5.0μm的夹杂物数量很少,没有发现5.0μm以上的夹杂物。此外,均热时间为10、30、60、90、120、240 min时,对应试样中0.05～0.2μm的夹杂物数量分别为4.04×104、4.73×104、3.70×104、3.33×104、3.10×104、1.56×104个/mm3。绝大部分夹杂物以MnS、AlN、CuxS类为主,并以三类夹杂物中的两类复合或三类复合居多。三类复合夹杂物总量占每组试样夹杂物总量的90%或以上。随均热时间延长,典型的夹杂物组成会发生如下变化:MnS+AlN+CuxS MnS+AlN AlN。与此同时,MnS、AlN、CuxS三者复合比例从45.2%(均热10 min)降为9.7%(均热240 min)。 The methods of electrolysis extraction from nonaqueous solution and scanning electron microscope were adopted to study the precipitation behavior of non-metallic inclusions in Si steel slabs during reheating processes.The morphologies,chemical compositions,quantity and size distribution of non-metallic inclusions in these steel samples were analyzed.Results show that,when the soaking temperature is 1 523 K,almost all of the non-metallic inclusions are smaller than 0.5 μm,few are in the range of ... 

介绍了电工钢生产线连退机组的表面处理工艺,特别是电解清洗系统的工作机理、设备构造、生产工艺及各种影响因素。 This paper introduces the technology of surface treatment of continuous annealing unit in electrical steel production line,in particular the working mechanism,structure of equipment,production techniques and various influence factors of the electrolytic cleaning system. 

【作者】 朱一知； 高军军； ...

根据新日铁、JFE及浦项等国外钢铁公司2008年以来在日本专利局、欧洲专利局(EP)及世界知识产权组织(WIPO)申请公开的有关生产Hi-B取向电工钢典型专利技术,概述了近年来国外大型钢铁企业采用低温板坯加热(坯加热温度<1 280℃)技术生产Hi-B取向电工钢主要技术重点,即将调节关键化学成分Al、N、Sn及Sb等与工艺改进相结合。最后介绍了国外大型钢铁企业采用低温板坯加热技术生产Hi-B取向电工钢实例。 The latest developments on technology for manufacturing Hi-B grain oriented electrical steel sheets developed by Nippon Steel Corp.,JFE Steel and POSCO were described according to the patents published by World Intellectual Property Organization,Japan Patent Office and European Patent Office over the recent years.The low temperature slab heating process(particularly slab-heating temperature<1 280 ℃) together with suitably adjusting key chemical elements such as Al,N,Sn and Sb elements was the...