论文

【机构】 宝山钢铁股份有限公司规划与科技部； ...

基于BOF→RH→CSP生产工艺,研究了RH精炼过程钢中夹杂物类型演变及MgO·Al2O3夹杂物形成规律,同时对MgO·Al2O3夹杂物的形成条件进行了热力学计算,借助CFD数值模拟软件研究了RH精炼过程卷渣行为。研究发现,RH精炼过程20和30 min时,w([MgO])/w([Al2O3])为0.005~0.020,未发现MgO·Al2O3夹杂物;RH出站后夹杂物w([MgO])/w([Al2O3])为0.3~0.5,且RH精炼结束后MgO·Al2O3夹杂物占夹杂物总量的58.4%;另外,RH精炼过程钢液表面速度CFD模拟结果为0.57 m/s,大于临界卷渣速度0.45 m/s,且顶渣成分与夹杂物成分相近,存在卷渣现象。热力学计算表明,钢液与炉渣平衡时钢中w([Al])为0.31%~0.37%,w([Mg])为0.00024%~0.00028%,在MgO·Al2O3生成区域之内。减少RH处理过程卷渣,浇铸过程下渣及控制顶渣和包衬相中MgO质量分数可抑制MgO·Al2O3夹杂物形成。 Based on the practical production of non-oriented silicon steel, the evolution of inclusion type and the formation of MgO·Al2O3inclusion were analyzed in the process of BOF→RH→CSP. The thermodynamic conditions for forming MgO·Al2O3inclusion were discussed and the behavior of slag entrapment of molten steel was also simulated by CFD software during RH refining. The results showed that the value of w([MgO])/w([Al2O3]) was in the range of 0.005-0.020 and no MgO · Al2O3 inclusion was observed at 20 ... 

采用电解法和扫描电镜研究了300 t转炉-RH精炼钙处理对无取向硅钢板（%:≤0.005C、1.2～2.2Si、0.2～0.6Mn、≤0.20P、≤0.005S、0.2～0.6Al、0～0.01Ca）中夹杂物的影响。结果表明,钢中Al含量为0.25%和0.35%时,钢中溶解氧均小于1×10^-4%,钙处理后都会产生CaS夹杂物,尤其是含0.35%Al的钢水;钙处理可以有效减少钢中的夹杂物数量,尤其是0.5μm以下的微细夹杂物数量;钙处理后夹杂物的种类以AlN、CaS为主,同时还含有少量的氧化物夹杂物以及AlN-CaS复合夹杂物,尺寸主要为1.5～5.0μm。 The effect of 300 t converter-RH refining calcium treatment on inclusions in non-oriented silicon steel sheet （%:≤0.005C,1.2～2.2Si,0.2～0.6Mn,≤0.20P,≤0.005S,0.2～0.6A1,0～0.01Ca） has been studied by electrolysis and scanning electron microscope.Results show that with 0.25%and 0.35%Al content in steel,all the dissolved oxygen in liquid is less than 1×10^-4%,and the CaS inclusions are produced after calcium treatment,especial for the liquid containing 0.35%Al;the amount of inclusions in ste... 

通过对辉光放电发射光谱法分析电工钢样品光谱行为的研究,分析其工作参数如:电压、电流、预溅射时间和积分时间对光谱强度和稳定性的影响,并以铁为内标元素,优化了工作参数。确定了直流辉光放电光谱法测定电工钢中碳、硅、锰、磷、硫、铬、镍、铜共8种元素的定量分析方法,并对该方法分析的精密度和准确度进行验证,结果表明,各元素的测定结果与认定值和其他方法测定值一致,测量元素结果RSD值小于2%。 Based on research on analyzing the spectrum behavior of the sample taken from the electrical steel by glow discharge optical emission spectrometry,the effect of its operational parameters such as current,voltage,pre-sputtering time and integrating time on the spectral intensity and spectral stability is analyzed.Taking the Fe as an element applied by internal standard method,these operational parameters are optimized,and therefore the quantitative analysis method for testing eight kinds of eleme... 

针对本钢薄板坯铸机在生产无取向电工硅钢的过程中存在的铸坯拉断、中包增碳、增氮等问题,进行了连铸工艺优化。通过采用新型无碳中间包覆盖剂、环保中间包干式料及专用结晶器保护渣后,降低了铸坯增碳量;通过控制钢包到中间包的增氮环节,降低钢水增氮;适当增大二冷水量,控制钢水过热度,防止铸坯拉断等生产事故的发生。改进工艺后,精炼后到成品铸坯的平均增碳量能控制在10×10-6以内,平均增氮量能控制在4×10-6以内。 The technology optimization has been adopted for preventing nitrogen increasing and carbon increasing in Benxi thin slab producing non-oriented silicon steel.Measures accordingly were adopted and satisfactory results were achieved. 

研究了常化对CSP流程生产的wSi=1.6%的无取向电工钢组织、织构和成品磁性能的影响。结果表明,经CSP流程生产,且在相同的冷轧及退火制度下,经1 000℃×2min常化处理的wSi=1.6%的无取向电工钢热轧板,其最终退火成品的铁损P15/50比不常化试样下降了10.5%,磁感B50比不常化试样提高了2.5%;常化使wSi=1.6%的无取向电工钢成品的平均晶粒尺寸增大,成品铁损P15/50相应减小;同时,常化使wSi=1.6%的无取向电工钢成品中高斯织构的强度增加,γ纤维织构的强度减弱,这有利于成品磁感B50的提高。 The effect of normalizing on microstructure,texture and magnetic properties of non-oriented electrical steel with wSi=1.6% produced by CSP process was investigated.The results show that,under the same cold rolling and annealing system,the iron loss(P15/50) of annealed samples whose hot bands has been normalized by 1 000 ℃×2 min process decreases by 10.5% and magnetic induction(B50) increases by 2.5% compared with the samples whose hot bands was not normalized.The average grain size of non-orient... 

借助OM、激光共聚焦显微镜、质谱仪和电解萃取等设备和方法，研究了添加微量稀土La（质量分数0.001 1%）的取向硅钢在轧制前采用不同加热保温时间对抑制剂固溶行为的影响。结果表明：当稀土取向硅钢在1 250℃分别保温10、20、30 min后，试验钢晶粒尺寸随保温时间延长有先快后慢的长大趋势；三种抑制剂元素Mn、Cu和Al均发生固溶，保温时间对Mn和Cu两种元素的固溶影响明显，固溶量分别由69.8%和43.7%增加至84.2%和85.2%；随着保温时间的延长，稀土取向硅钢中抑制剂的小尺寸未溶物逐渐减少直至消失，较大尺寸未溶物（300～600 nm）逐渐转变为小尺寸未溶物逐步溶入基体中，数量减少且未溶物的类型由复杂逐渐转变为单一。 In this paper the solid solution behavior of the inhibitor under various holding time in 0.001 1 %La oriented silicon steel during reheating had been investigated by using OM, LM, methods of electrolytic extraction and mass spectrometer. The results showed that grain size of the test steel increased significantly with the holding time prolonging when the rare earth oriented silicon steel was heated to1 250 ℃ and held for 10, 20 min and 30 min respectively, and the growth trend slowed down after ... 

利用OM、EBSD等手段研究了热轧板两段式正火时在700℃保温不同时间(0、10、30、60 min)对含Sb冷轧无取向电工钢磁性能的影响。结果表明,700℃保温10 min处理的样品铁损最小,磁感最高。对成品板的组织分析结果表明,试样的晶粒尺寸随700℃保温时间的延长先增大后减小,保温10 min时晶粒尺寸达到最大;分析成品试样织构发现,有利织构组分随700℃保温时间的延长先增加后减少,保温10 min时有利织构组分所占百分比最高。因此,含Sb冷轧无取向电工钢两段式正火时在700℃保温10 min时磁性能最好。 Effect of two-stage normalization on magnetic property of non-oriented electrical steel containing antimony was investigated by using optical microscope(OM) and electron back-scattered diffraction technology(EBSD).The experimental results show that the iron loss and magnetic permeability of the specimen insulated at 700 ℃ for 10 min are lowest and highest respectively.The grain size of the finish specimens increases first and then decreases with the increase of holding time.Similarly,the advanta... 

在50Kg氧化镁坩埚真空感应炉上进行高硅电工钢的脱氧试验。结果表明,通过控制原料的成分、高真空下的碳氧反应和炉衬分解向钢液中的供氧,可使钢液的总氧含量≤15×10-6;在维持高温高真空条件下,当钢液中的反应达到一定程度后,延长精炼时间并不能降低钢液的总氧含量;完成精炼后加入硅钙合金沉淀脱氧可进一步降低钢液的总含氧量,但脱氧效果有限。 The test of high-silicon electric steel deoxidation has been carried out in 50Kg vacuum induction furnace with magnesium oxide crucible.Results show that the total oxygen could be ≤15×10-6in molten steel by controlling material components,carbon-oxygen reaction in high vacuum and oxygen contamination from crucible materials on molten steel;And when the reaction was carried through to a certain extent,total oxygen in molten steel could not be reduced by the extension of refining period in high va... 

研究了冷轧大压下量,950℃退火时间对一种新型含铜无取向电工钢晶粒度和织构的影响。结果表明,大压下量冷轧,随压下量的增加,退火晶粒向γ线聚集,形成强{111}<112>织构。提高冷轧压下率,退火织构{111}<100>,{110}<001>强度减弱,增加退火时间,退火织构{111}<110>,{100}<001>,{110}<001>强度变弱。采用87.5%冷轧压下率和950℃退火60 s,有利织构{100},{110}占有率最大。 The effect of annealing(950 ℃) time with high cold rolling reduction on grain size and texture of a new non-oriented electrical steel containing copper was investigated.The results show that for high cold rolling reduction,most annealed grains are oriented along γ-fibre with increasing cold rolling reduction ratio and strong texture {111}<112> is formed.With increasing the cold rolling reduction ratio,the intensity of annealed texture {111}<110>,{011}<100> decreases.With increa... 

利用OM、TEM与EDS技术,对Fe-3.2%Si低温取向硅钢热轧板进行不同常化冷却工艺处理后的显微组织、析出相及最终产品的磁性能进行分析,并与热轧板的组织和析出相进行对比。结果表明,常化板较热轧板的表层组织均匀,基体中再结晶比例增加,带状组织变窄;常化板中析出物的数量明显比热轧板的多,析出物主要有AlN、MnS及复合析出的(Cu,Mn)S等。在常化温度1120℃、保温3 min的条件下,采用二段式冷却较空冷、淬沸水、淬常温水的冷却工艺,常化板表层显微组织更均匀,沿板厚方向的显微组织的不均匀性显著,取向硅钢的磁性能最高;常化后采用二段式冷却工艺析出的细小析出物数量最多,且弥散分布在基体中,抑制剂的抑制效果最好,对成品获得高磁性最有利。 Microstructure, precipitate and magnetic characteristic of final products with different normalizing cooling processes for Fe-3.2%Si low-temperature hot-rolled grain-oriented silicon steel were analyzed and compared with the hot-rolled plate by optical microscopy(OM), transmission electron microscopy(TEM), and energy dispersive spectrometry(EDS). The results show that, the surface microstructure is uniform, the proportion of recrystallization in matrix increases, and the banding textures are nar... 

以能量平衡和辐射换热理论为基础,通过合理假定,建立了硅钢无氧化加热炉数学模型。采用数值计算的方法,通过自编程序,完成对带钢加热过程温度场的仿真。结果显示:数学模型能够反映带钢在无氧化炉内的加热过程,其升温曲线能够与工艺曲线相吻合;现行炉温分布并非最优,数学模型能够为炉温分布的优化、炉段的设计提供理论依据。 Mathematical model of NOF Section of Continuous Annealing Furnace is established based on energy balance and radiation heat exchange. The temperature field of steel is simulated by mathematical computation. The simulating results show that the mathematical model can reflect the heating process of silicon steel in NOF section, and the heat-up curve is coincide with the processing curve. From the results,it is known that the current furnace temperature gradient is not the best, and the mathematica...